Giant Negative Area Compressibility Tunable in a Soft Porous Framework Material

A soft porous material [Zn­(L)2(OH)2] n ·Guest (where L is 4-(1H-naphtho­[2,3-d]­imidazol-1-yl)­benzoate, and Guest is water or methanol) exhibits the strongest ever observed negative area compressibility (NAC), an extremely rare property, as at hydrostatic pressure most materials shrink in all dire...

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Veröffentlicht in:	Journal of the American Chemical Society 2015-07, Vol.137 (29), p.9296-9301
Hauptverfasser:	Cai, Weizhao, Gładysiak, Andrzej, Anioła, Michalina, Smith, Vincent J, Barbour, Leonard J, Katrusiak, Andrzej
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzoates - chemistry Hydrostatic Pressure Mechanical Phenomena Methanol - chemistry Models, Molecular Molecular Conformation Organometallic Compounds - chemistry Porosity Stress, Mechanical Water - chemistry Zinc - chemistry
Online-Zugang:	Volltext
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