Solvent Effects on the Encapsulation of Divalent Ions by Benzo-18-Crown‑6 and Benzo-15-Crown‑5

We measure UV photodissociation (UVPD) spectra of cold benzo-15-crown-5 (B15C5) and benzo-18-crown-6 (B18C6) complexes with divalent ions (M2+ = Ca2+, Sr2+, Ba2+, and Mn2+), solvated with an H2O or a CH3OH molecule: M2+·B15C5·H2O, M2+·B15C5·CH3OH, M2+·B18C6·H2O, and M2+·B18C6·CH3OH. All the species...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2015-07, Vol.119 (29), p.8097-8105
Hauptverfasser:	Inokuchi, Yoshiya, Ebata, Takayuki, Rizzo, Thomas R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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