Synergistic Gold and Iron Dual Catalysis: Preferred Radical Addition toward Vinyl–Gold Intermediate over Alkene

A dual catalytic approach enlisting gold and iron synergy is described. This method offers readily access to substituted heterocycle aldehydes via oxygen radical addition to vinyl–gold intermediates under Fe catalyst assistance. This system shows good functional group compatibility for the generatio...

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Veröffentlicht in:	Journal of the American Chemical Society 2015-07, Vol.137 (28), p.8912-8915
Hauptverfasser:	Peng, Haihui, Akhmedov, Novruz G, Liang, Yu-Feng, Jiao, Ning, Shi, Xiaodong
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes - chemical synthesis Aldehydes - chemistry Alkenes - chemical synthesis Alkenes - chemistry Catalysis Cyclization Gold - chemistry Heterocyclic Compounds - chemical synthesis Heterocyclic Compounds - chemistry Iron - chemistry Oxazoles - chemical synthesis Oxazoles - chemistry Reactive Oxygen Species - chemical synthesis Reactive Oxygen Species - chemistry Stereoisomerism Vinyl Compounds - chemical synthesis Vinyl Compounds - chemistry
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