Understanding the Aldo-Enediolate Tautomerism of Glycolaldehyde in Basic Aqueous Solutions

The biochemically important interconversion process between aldoses and ketoses is assumed to take place via 1,2‐enediol or 1,2‐enediolate intermediates, but such intermediates have never been isolated. The current work was undertaken in an attempt to detect the presence of the 1,2‐enediol structure...

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Veröffentlicht in:	Chemphyschem 2015-07, Vol.16 (10), p.2226-2236
Hauptverfasser:	Azofra, Luis Miguel, Quesada-Moreno, María Mar, Alkorta, Ibon, Avilés-Moreno, Juan Ramón, Elguero, José, López-González, Juan Jesús
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetaldehyde - analogs & derivatives Acetaldehyde - chemistry Aqueous solutions hydrogen bonds quantum chemical calculations Quantum Theory Raman spectroscopy Solutions solvents Spectrum analysis Spectrum Analysis, Raman tautomerism Water - chemistry
Online-Zugang:	Volltext
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