DMSO/I2 mediated C-C bond cleavage of α-ketoaldehydes followed by C-O bond formation: a metal-free approach for one-pot esterification

A novel and efficient I2/DMSO mediated metal-free strategy is presented for the direct C-C bond cleavage of aryl-/heteroaryl- or aliphatic α-ketoaldehydes by C2-decarbonylation and C1-carbonyl oxidation to give the corresponding carboxylic acids followed by esterification in one pot, offering excell...

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Veröffentlicht in:	Organic & biomolecular chemistry 2015-08, Vol.13 (29), p.7973-7978
Hauptverfasser:	Venkateswarlu, Vunnam, Aravinda Kumar, K A, Gupta, Sorav, Singh, Deepika, Vishwakarma, Ram A, Sawant, Sanghapal D
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes - chemistry Benzoic Acid - chemistry Carboxylic Acids - chemistry Chemistry, Organic - methods Dimethyl Sulfoxide - chemistry Esterification Esters - chemistry Iodine - chemistry Ketones - chemistry Metals - chemistry Oxidation-Reduction Solvents
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