A Molecular Ruthenium Electrocatalyst for the Reduction of Carbon Dioxide to CO and Formate

The use of a bulky bipyridine ligand, 6,6′-dimesityl-2,2′-bipyridine (mesbpy), to enable the reduction of carbon dioxide by a Ru-based molecular electrocatalyst is reported. Under catalytic conditions, this compound exhibits turnover frequencies of 1300 s–1 and 95% Faradaic efficiency for the produc...

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Veröffentlicht in:	Journal of the American Chemical Society 2015-07, Vol.137 (26), p.8564-8571
Hauptverfasser:	Machan, Charles W, Sampson, Matthew D, Kubiak, Clifford P
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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