Temperature induced evolution of structure/microstructure parameters and their correlations with electric/magnetic properties of nanocrystalline Nickel ferrite
Nickel ferrite nanoparticles were annealed in order to find dependence of electric/magnetic properties on crystallite size. The following correlations of crystallite size with physical parameters were found: (a) lattice parameter decreases with the increase in size and it reaches value for bulk coun...
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Veröffentlicht in: | Ceramics international 2014-04, Vol.40 (3), p.4521-4527 |
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creator | Vucinic-Vasic, Milica Boskovic, Marko Antic, Aleksandar Stojanovic, Goran Radovanovic, Milan Fabian, Martin Jovalekic, Cedomir Pavlovic, Miodrag B. Antic, Bratislav |
description | Nickel ferrite nanoparticles were annealed in order to find dependence of electric/magnetic properties on crystallite size. The following correlations of crystallite size with physical parameters were found: (a) lattice parameter decreases with the increase in size and it reaches value for bulk counterpart approximately for crystallites bigger than 7nm, (b) ac electrical resistivity at room temperature increases with the increase in crystallite size, (c) for crystallites of ~7nm or smaller electrical resistivity have maximum value at 50°C, (d) the real part of permittivity at selected frequency generally decreases with the increase in crystallite size and (e) magnetization increases with the increase in crystallite size. Deviation of stoichiometry, cation polyvalence, and cation redistribution with annealing are the main factors that influence physical properties of Nickel ferrite nanoparticles. |
doi_str_mv | 10.1016/j.ceramint.2013.08.127 |
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The following correlations of crystallite size with physical parameters were found: (a) lattice parameter decreases with the increase in size and it reaches value for bulk counterpart approximately for crystallites bigger than 7nm, (b) ac electrical resistivity at room temperature increases with the increase in crystallite size, (c) for crystallites of ~7nm or smaller electrical resistivity have maximum value at 50°C, (d) the real part of permittivity at selected frequency generally decreases with the increase in crystallite size and (e) magnetization increases with the increase in crystallite size. Deviation of stoichiometry, cation polyvalence, and cation redistribution with annealing are the main factors that influence physical properties of Nickel ferrite nanoparticles.</description><identifier>ISSN: 0272-8842</identifier><identifier>EISSN: 1873-3956</identifier><identifier>DOI: 10.1016/j.ceramint.2013.08.127</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Annealing ; B. Grain size ; C. Electrical properties ; C. Magnetic properties ; Cations ; Crystallites ; D. 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The following correlations of crystallite size with physical parameters were found: (a) lattice parameter decreases with the increase in size and it reaches value for bulk counterpart approximately for crystallites bigger than 7nm, (b) ac electrical resistivity at room temperature increases with the increase in crystallite size, (c) for crystallites of ~7nm or smaller electrical resistivity have maximum value at 50°C, (d) the real part of permittivity at selected frequency generally decreases with the increase in crystallite size and (e) magnetization increases with the increase in crystallite size. Deviation of stoichiometry, cation polyvalence, and cation redistribution with annealing are the main factors that influence physical properties of Nickel ferrite nanoparticles.</description><subject>Annealing</subject><subject>B. Grain size</subject><subject>C. Electrical properties</subject><subject>C. Magnetic properties</subject><subject>Cations</subject><subject>Crystallites</subject><subject>D. Ferrite</subject><subject>Deviation</subject><subject>Electrical resistivity</subject><subject>Magnetic properties</subject><subject>Nanoparticles</subject><subject>Nickel ferrites</subject><issn>0272-8842</issn><issn>1873-3956</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFkUFvFSEUhYmxic_qXzAs3cw8mGFg2GkatU0a3dQ14TF37H0y8ASmpr-mf1UmT912RYBzzoXzEfKOs5YzLvfH1kGyC4bSdoz3LRtb3qkXZMdH1Te9HuRLsmOd6ppxFN0r8jrnI6tGLdiOPN3Bcqr2siagGKbVwUThIfq1YAw0zjSXtLrter-gS_H_lp5snQoFUqY2TLTcAybqYkrg7WbO9DeWewoeXEno9ov9EaCgo6cU68iCkLf8YEN06TEX6z0GoF_R_QRPZ0gJC7whF7P1Gd7-XS_J98-f7q6um9tvX26uPt42rldjabQUEzsIqZnToHvgUmoplVTswKbBHQ5CCSlGBXruBtV3XDIO0PezUiB1Pbkk78-59XG_VsjFLJgdeG8DxDWbWlcneA1hz0sHwcXAmOJVKs_SrbicYDanhItNj4Yzs8EzR_MPntngGTaaCq8aP5yNUP_8gJBMdgihwsFU6zRTxOci_gByHKsB</recordid><startdate>20140401</startdate><enddate>20140401</enddate><creator>Vucinic-Vasic, Milica</creator><creator>Boskovic, Marko</creator><creator>Antic, Aleksandar</creator><creator>Stojanovic, Goran</creator><creator>Radovanovic, Milan</creator><creator>Fabian, Martin</creator><creator>Jovalekic, Cedomir</creator><creator>Pavlovic, Miodrag B.</creator><creator>Antic, Bratislav</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20140401</creationdate><title>Temperature induced evolution of structure/microstructure parameters and their correlations with electric/magnetic properties of nanocrystalline Nickel ferrite</title><author>Vucinic-Vasic, Milica ; Boskovic, Marko ; Antic, Aleksandar ; Stojanovic, Goran ; Radovanovic, Milan ; Fabian, Martin ; Jovalekic, Cedomir ; Pavlovic, Miodrag B. ; Antic, Bratislav</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c378t-964d0b4690c9e93e1669667670b0d5cbb4746487e9f257321601ee33f77e69573</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Annealing</topic><topic>B. Grain size</topic><topic>C. Electrical properties</topic><topic>C. Magnetic properties</topic><topic>Cations</topic><topic>Crystallites</topic><topic>D. Ferrite</topic><topic>Deviation</topic><topic>Electrical resistivity</topic><topic>Magnetic properties</topic><topic>Nanoparticles</topic><topic>Nickel ferrites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vucinic-Vasic, Milica</creatorcontrib><creatorcontrib>Boskovic, Marko</creatorcontrib><creatorcontrib>Antic, Aleksandar</creatorcontrib><creatorcontrib>Stojanovic, Goran</creatorcontrib><creatorcontrib>Radovanovic, Milan</creatorcontrib><creatorcontrib>Fabian, Martin</creatorcontrib><creatorcontrib>Jovalekic, Cedomir</creatorcontrib><creatorcontrib>Pavlovic, Miodrag B.</creatorcontrib><creatorcontrib>Antic, Bratislav</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Ceramics international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vucinic-Vasic, Milica</au><au>Boskovic, Marko</au><au>Antic, Aleksandar</au><au>Stojanovic, Goran</au><au>Radovanovic, Milan</au><au>Fabian, Martin</au><au>Jovalekic, Cedomir</au><au>Pavlovic, Miodrag B.</au><au>Antic, Bratislav</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Temperature induced evolution of structure/microstructure parameters and their correlations with electric/magnetic properties of nanocrystalline Nickel ferrite</atitle><jtitle>Ceramics international</jtitle><date>2014-04-01</date><risdate>2014</risdate><volume>40</volume><issue>3</issue><spage>4521</spage><epage>4527</epage><pages>4521-4527</pages><issn>0272-8842</issn><eissn>1873-3956</eissn><abstract>Nickel ferrite nanoparticles were annealed in order to find dependence of electric/magnetic properties on crystallite size. The following correlations of crystallite size with physical parameters were found: (a) lattice parameter decreases with the increase in size and it reaches value for bulk counterpart approximately for crystallites bigger than 7nm, (b) ac electrical resistivity at room temperature increases with the increase in crystallite size, (c) for crystallites of ~7nm or smaller electrical resistivity have maximum value at 50°C, (d) the real part of permittivity at selected frequency generally decreases with the increase in crystallite size and (e) magnetization increases with the increase in crystallite size. Deviation of stoichiometry, cation polyvalence, and cation redistribution with annealing are the main factors that influence physical properties of Nickel ferrite nanoparticles.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.ceramint.2013.08.127</doi><tpages>7</tpages></addata></record> |
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subjects | Annealing B. Grain size C. Electrical properties C. Magnetic properties Cations Crystallites D. Ferrite Deviation Electrical resistivity Magnetic properties Nanoparticles Nickel ferrites |
title | Temperature induced evolution of structure/microstructure parameters and their correlations with electric/magnetic properties of nanocrystalline Nickel ferrite |
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