Corrosion of alumina and mullite hot gas filter candles in gasification environment

Reliable fuel gas cleaning is required to meet environmental regulations as well as to prevent corrosion and erosion of downstream components. The aggressive process environment in biomass-gasification power generation systems or in biofuels production systems causes corrosion in the ceramic hot gas...

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Veröffentlicht in:Journal of the European Ceramic Society 2013-12, Vol.33 (15-16), p.3301-3312
Hauptverfasser: Schaafhausen, Sarah, Yazhenskikh, Elena, Walch, Astrid, Heidenreich, Steffen, Müller, Michael
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container_end_page 3312
container_issue 15-16
container_start_page 3301
container_title Journal of the European Ceramic Society
container_volume 33
creator Schaafhausen, Sarah
Yazhenskikh, Elena
Walch, Astrid
Heidenreich, Steffen
Müller, Michael
description Reliable fuel gas cleaning is required to meet environmental regulations as well as to prevent corrosion and erosion of downstream components. The aggressive process environment in biomass-gasification power generation systems or in biofuels production systems causes corrosion in the ceramic hot gas filter candles used to clean the fuel gas. Therefore, in order to improve the reliability and durability of filters, the influence of steam, ash, hydrogen sulfide, and alkaline metals on the corrosion processes was studied for alumina and mullite filter candles fabricated by Pall Schumacher. Exposure to these contaminants effects the chemical composition of the binder phases resulting in exchange of alkaline metals and alkaline earth metals. Analyses by energy dispersive X-ray spectroscopy demonstrate the negative effect of silicon containing binder phases. These effects are discussed and it is shown that the usage of silicon-free binder phases in hot gas filter candles for gasification processes is promising.
doi_str_mv 10.1016/j.jeurceramsoc.2013.05.024
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subjects Alkaline metal
Alumina
Aluminum oxide
Ashes
Binders
Candles
Corrosion
Gasification
Hot gas filter
Mullite
Phases
title Corrosion of alumina and mullite hot gas filter candles in gasification environment
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