Hindrance, Donor Ability of Me sub(n)NNChelates and Overall Stability of Pentacoordinate [PtCl sub(2)( eta super(2)- CH sub(2)=CH sub(2))(Me sub(n)NN] Complexes as Observed by eta super(2)-Olefin super(1)J sub(Pt,C) Modulation: An NMR Study

A series of pentacoordinate d super(8) Pt super(II) complexes, of the type [PtCl sub(2)( eta super(2)- CH sub(2)=CH sub(2))(Me sub(n)NN], where Me sub(n)NN= bis-nitrogen ligand, with a variable number of Me groups (i.e., 2,2'-bipyridyl; 1,10-phenanthroline; 6-methyl-2,2'-bipyridyl; 2,9-dim...

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Veröffentlicht in:	European journal of inorganic chemistry 2015-05, Vol.2015 (13), p.2308-2316
Hauptverfasser:	Benedetti, Michele, Antonucci, Daniela, Girelli, Chiara R, Fanizzi, Francesco P
Format:	Artikel
Sprache:	eng
Schlagworte:	Diamines Electron density Ligands Mathematical models Modulation Nuclear magnetic resonance Stability Steric hindrance
Online-Zugang:	Volltext
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