A 3-D metal–organic framework with a rutile topology network, right- or left- handed helical chains and tunable UV-to-visible photoluminescence

A 3-D metal–organic framework with a rutile topology network, right- or left- handed helical chains and tunable UV-to-visible photoluminescence

A rutile topological 3-D metal organic framework (MOF) has been obtained by reacting CdSO 4 ·8/3H 2 O with HL (HL = 6-aminonicotinic acid) under solvothermal conditions. Unique right- or left- handed helices can be found in the architecture of the MOF. The framework can exhibit tunable UV-to-visible...

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Veröffentlicht in:RSC advances 2015-01, Vol.5 (53), p.42616-42620
Hauptverfasser: Zhou, Wei-Wei, Zhao, Wang, Wang, Feng-Wu, Fang, Wen-Yan, Liu, Dao-Fu, Wei, Yi-Jun, Xu, Mai, Zhao, Xing, Liang, Xian
Format: Artikel
Sprache:eng
Schlagworte:
Fluorescence
Helical
Helices
Metal-organic frameworks
Networks
Photoluminescence
Rutile
Three dimensional
Topology
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Zusammenfassung:A rutile topological 3-D metal organic framework (MOF) has been obtained by reacting CdSO 4 ·8/3H 2 O with HL (HL = 6-aminonicotinic acid) under solvothermal conditions. Unique right- or left- handed helices can be found in the architecture of the MOF. The framework can exhibit tunable UV-to-visible fluorescence by variation of the excitation light.
ISSN:2046-2069
2046-2069
DOI:10.1039/C5RA06940H