Enhanced light scattering and photovoltaic performance for dye-sensitized solar cells by embedding submicron SiO2/TiO2 core/shell particles in photoanode

The introduction of light scattering in the photoanodes of dye-sensitized solar cells is one of the most effective approaches to enhance their photovoltaic performance. In this work, we prepared submicron SiO2/TiO2 core/shell particles and embedded these particles in the nanostructured TiO2 photoano...

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Veröffentlicht in:Ceramics international 2013-07, Vol.39 (5), p.5407-5413
Hauptverfasser: Wang, Yuanzhe, Chen, Enlong, Lai, Hongmei, Lu, Bin, Hu, Zhijuan, Qin, Xiaomei, Shi, Wangzhou, Du, Guoping
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container_end_page 5413
container_issue 5
container_start_page 5407
container_title Ceramics international
container_volume 39
creator Wang, Yuanzhe
Chen, Enlong
Lai, Hongmei
Lu, Bin
Hu, Zhijuan
Qin, Xiaomei
Shi, Wangzhou
Du, Guoping
description The introduction of light scattering in the photoanodes of dye-sensitized solar cells is one of the most effective approaches to enhance their photovoltaic performance. In this work, we prepared submicron SiO2/TiO2 core/shell particles and embedded these particles in the nanostructured TiO2 photoanodes for light to scatter in the dye-sensitized solar cells. Due to the large difference in the refractive index between the SiO2 core and the TiO2 shell, the embedded submicron SiO2/TiO2 core/shell particles showed strong light scattering effect. Light absorbance of the dyed photoanode with the embedded SiO2/TiO2 particles for light scattering was found to be three times stronger than the one without light scattering particles over a wide wavelength range. The power conversion efficiency of dye-sensitized solar cells was increased by about 50% after the introduction of light scattering SiO2/TiO2 core/shell particles in the photoanode. This work will provide a base for further enhancement in the photovoltaic performance of dye-sensitized solar cells by optimizing the submicron SiO2/TiO2 core/shell particles and the photoanodes.
doi_str_mv 10.1016/j.ceramint.2012.12.048
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subjects Core/shell particle
Dye-sensitized solar cell
Dyes
Energy conversion efficiency
Light scattering
Nanostructure
Photovoltaic cells
Shells
Silicon dioxide
Solar cells
Titanium dioxide
title Enhanced light scattering and photovoltaic performance for dye-sensitized solar cells by embedding submicron SiO2/TiO2 core/shell particles in photoanode
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