Effects of CaTiO3 addition on microstructures and electrical properties of Na0.52K0.48NbO3 lead-free piezoelectric ceramics
In this article, various amounts of CaTiO3 (CT) were added into (Na0.52K0.48)NbO3 (NKN) ceramics using conventional oxide-mixing method for improving NKN's properties. The experimental results show that the (1−x)(Na0.52K0.48)NbO3–xCaTiO3 (x=0∼0.07) solid solution system can be successfully synt...
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Veröffentlicht in: | Ceramics international 2013-05, Vol.39, p.S125-S128 |
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description | In this article, various amounts of CaTiO3 (CT) were added into (Na0.52K0.48)NbO3 (NKN) ceramics using conventional oxide-mixing method for improving NKN's properties. The experimental results show that the (1−x)(Na0.52K0.48)NbO3–xCaTiO3 (x=0∼0.07) solid solution system can be successfully synthesized. Addition of CaTiO3 not only effectively prevents materials from deliquescence, but also improves the density and the electrical properties of the ceramics. The dielectric constant–temperature (εr−T) curves exhibit that the temperatures of the Curie point (Tc) and the phase transition from tetragonal to orthorhombic (TO−T) are decreasing monotonously as the amount of CT addition is increased. A morphotropic phase boundary (MPB) can be found in the (1−x)NKN−xCT solid solution system as the doping amount of x=0.03, and the 0.97NKN–0.03CT ceramics, with a high bulk density, 98% theoretical density, and an appropriate grain size of about 1∼2μm, present a superior domain switching ability and the optimum properties: d33=117pC/N, kp=0.39, Pr=21μC/cm2, and Tc=333°C. |
doi_str_mv | 10.1016/j.ceramint.2012.10.047 |
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The experimental results show that the (1−x)(Na0.52K0.48)NbO3–xCaTiO3 (x=0∼0.07) solid solution system can be successfully synthesized. Addition of CaTiO3 not only effectively prevents materials from deliquescence, but also improves the density and the electrical properties of the ceramics. The dielectric constant–temperature (εr−T) curves exhibit that the temperatures of the Curie point (Tc) and the phase transition from tetragonal to orthorhombic (TO−T) are decreasing monotonously as the amount of CT addition is increased. A morphotropic phase boundary (MPB) can be found in the (1−x)NKN−xCT solid solution system as the doping amount of x=0.03, and the 0.97NKN–0.03CT ceramics, with a high bulk density, 98% theoretical density, and an appropriate grain size of about 1∼2μm, present a superior domain switching ability and the optimum properties: d33=117pC/N, kp=0.39, Pr=21μC/cm2, and Tc=333°C.</description><identifier>ISSN: 0272-8842</identifier><identifier>EISSN: 1873-3956</identifier><identifier>DOI: 10.1016/j.ceramint.2012.10.047</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>A. Sintering ; B. Microstructure-final ; C. Piezoelectric properties ; Ceramics ; Curie temperature ; D. 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The experimental results show that the (1−x)(Na0.52K0.48)NbO3–xCaTiO3 (x=0∼0.07) solid solution system can be successfully synthesized. Addition of CaTiO3 not only effectively prevents materials from deliquescence, but also improves the density and the electrical properties of the ceramics. The dielectric constant–temperature (εr−T) curves exhibit that the temperatures of the Curie point (Tc) and the phase transition from tetragonal to orthorhombic (TO−T) are decreasing monotonously as the amount of CT addition is increased. A morphotropic phase boundary (MPB) can be found in the (1−x)NKN−xCT solid solution system as the doping amount of x=0.03, and the 0.97NKN–0.03CT ceramics, with a high bulk density, 98% theoretical density, and an appropriate grain size of about 1∼2μm, present a superior domain switching ability and the optimum properties: d33=117pC/N, kp=0.39, Pr=21μC/cm2, and Tc=333°C.</description><subject>A. Sintering</subject><subject>B. Microstructure-final</subject><subject>C. Piezoelectric properties</subject><subject>Ceramics</subject><subject>Curie temperature</subject><subject>D. Niobates</subject><subject>Density</subject><subject>Electrical properties</subject><subject>Grain size</subject><subject>Phase boundaries</subject><subject>Solid solutions</subject><subject>Theoretical density</subject><issn>0272-8842</issn><issn>1873-3956</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkUtLxDAUhYMoOD7-gmTppjW5aZt0pwy-UHQz-5AmN5Ch045JR1D_vKmjayEQuJzvcO85hFxwVnLGm6t1aTGaTRimEhiHPCxZJQ_IgispCtHWzSFZMJBQKFXBMTlJac0y2FZsQb5uvUc7JTp6ujSr8CqocS5MYRxofptg45imuLPTLmKiZnAU-wzEYE1Pt3HcYpwC_vAvhpU1PLGyUi9dNurRuMJHRLoN-Dn-cXS_rk1n5MibPuH5739KVne3q-VD8fx6_7i8eS6skGoqkBnBK6mASwnYStbVquEAYGrwjXSNaBE8cuO5Ua7qwDVcqq7ugFUCQJySy71t3vZth2nSm5As9r0ZcNwlnZMAoUTL2P_SSrRStgpmabOXzgGliF5vY9iY-KE503Mveq3_etFzL_M895LB6z2I-eT3gFEnG3Cw6ELMAWk3hv8svgHMtpjQ</recordid><startdate>201305</startdate><enddate>201305</enddate><creator>Chen, Cheng-Sao</creator><creator>Chou, Chen-Chia</creator><creator>Lin, Yung-Shun</creator><creator>Chen, Pin-Yi</creator><creator>Chen, Haydn</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>201305</creationdate><title>Effects of CaTiO3 addition on microstructures and electrical properties of Na0.52K0.48NbO3 lead-free piezoelectric ceramics</title><author>Chen, Cheng-Sao ; Chou, Chen-Chia ; Lin, Yung-Shun ; Chen, Pin-Yi ; Chen, Haydn</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c378t-e0a3147821772e970b5861222a52f67d639e2fe1af1a8d4b2d6178b5b2043223</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>A. Sintering</topic><topic>B. Microstructure-final</topic><topic>C. Piezoelectric properties</topic><topic>Ceramics</topic><topic>Curie temperature</topic><topic>D. Niobates</topic><topic>Density</topic><topic>Electrical properties</topic><topic>Grain size</topic><topic>Phase boundaries</topic><topic>Solid solutions</topic><topic>Theoretical density</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Cheng-Sao</creatorcontrib><creatorcontrib>Chou, Chen-Chia</creatorcontrib><creatorcontrib>Lin, Yung-Shun</creatorcontrib><creatorcontrib>Chen, Pin-Yi</creatorcontrib><creatorcontrib>Chen, Haydn</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Ceramics international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Cheng-Sao</au><au>Chou, Chen-Chia</au><au>Lin, Yung-Shun</au><au>Chen, Pin-Yi</au><au>Chen, Haydn</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of CaTiO3 addition on microstructures and electrical properties of Na0.52K0.48NbO3 lead-free piezoelectric ceramics</atitle><jtitle>Ceramics international</jtitle><date>2013-05</date><risdate>2013</risdate><volume>39</volume><spage>S125</spage><epage>S128</epage><pages>S125-S128</pages><issn>0272-8842</issn><eissn>1873-3956</eissn><abstract>In this article, various amounts of CaTiO3 (CT) were added into (Na0.52K0.48)NbO3 (NKN) ceramics using conventional oxide-mixing method for improving NKN's properties. The experimental results show that the (1−x)(Na0.52K0.48)NbO3–xCaTiO3 (x=0∼0.07) solid solution system can be successfully synthesized. Addition of CaTiO3 not only effectively prevents materials from deliquescence, but also improves the density and the electrical properties of the ceramics. The dielectric constant–temperature (εr−T) curves exhibit that the temperatures of the Curie point (Tc) and the phase transition from tetragonal to orthorhombic (TO−T) are decreasing monotonously as the amount of CT addition is increased. A morphotropic phase boundary (MPB) can be found in the (1−x)NKN−xCT solid solution system as the doping amount of x=0.03, and the 0.97NKN–0.03CT ceramics, with a high bulk density, 98% theoretical density, and an appropriate grain size of about 1∼2μm, present a superior domain switching ability and the optimum properties: d33=117pC/N, kp=0.39, Pr=21μC/cm2, and Tc=333°C.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.ceramint.2012.10.047</doi></addata></record> |
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subjects | A. Sintering B. Microstructure-final C. Piezoelectric properties Ceramics Curie temperature D. Niobates Density Electrical properties Grain size Phase boundaries Solid solutions Theoretical density |
title | Effects of CaTiO3 addition on microstructures and electrical properties of Na0.52K0.48NbO3 lead-free piezoelectric ceramics |
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