“Sweet-in-Green” Systems Based on Sugars and Ionic Liquids: New Solubility Data and Thermodynamic Analysis
Ionic liquids have been considered as “green” replacements for volatile organic compounds in modern and clean industrial processes since the beginning of the 1990s. It has been shown recently that when combined with renewable feedstocks derived from biomass (like carbohydrates) they form systems att...
Gespeichert in:
Veröffentlicht in: | Industrial & engineering chemistry research 2013-12, Vol.52 (51), p.18482-18491 |
---|---|
Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 18491 |
---|---|
container_issue | 51 |
container_start_page | 18482 |
container_title | Industrial & engineering chemistry research |
container_volume | 52 |
creator | Paduszyński, Kamil Okuniewski, Marcin Domańska, Urszula |
description | Ionic liquids have been considered as “green” replacements for volatile organic compounds in modern and clean industrial processes since the beginning of the 1990s. It has been shown recently that when combined with renewable feedstocks derived from biomass (like carbohydrates) they form systems attractive for sustainable chemical engineering and technology. Promising features of such systems have induced research activity in various areas of pure and applied chemistry. In particular, new experimental data on different thermodynamic properties of biomaterials dissolved in ionic liquids are required. In this paper we present both experimental and theoretical thermodynamic studies of binary mixtures composed of sugars and two low-viscous ionic liquids based on 1-butyl-3-methylimidazolium cation and dicyanamide or trifluoroacetate anion. Solubility of d-(+)-glucose, d-(−)-fructose, and sucrose in the ionic liquids was determined as a function of temperature. The results indicate that both ionic liquids under consideration can be successfully applied as alternative solvents for sugars. Additionally, thermal characterization of pure sugars was performed with differential scanning calorimetry. The obtained solid–liquid equilibrium phase diagrams were analyzed in terms of perturbed-chain statistical associating fluid theory (PC-SAFT). It was shown that the PC-SAFT model is capable of representing phase behavior of the studied systems quantitatively. |
doi_str_mv | 10.1021/ie4033186 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1692371603</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1692371603</sourcerecordid><originalsourceid>FETCH-LOGICAL-a362t-3fab6662d39814b73545f5562e99dc17997e1d02bd67c4be374c9217c1ade4123</originalsourceid><addsrcrecordid>eNqF0MtKw0AUxvFBFKzVhW8wG0EX0bkncaf1CkUX1XWYZE51JJd2TkLJzgfRl_NJjFZcCa4OHH58iz8h-5wdcyb4iQfFpOSJ2SAjrgWLNFN6k4xYkiSRThK9TXYQXxhjWis1IvXH69tsBdBGvo6uA8DweKezHluokJ5bBEebms66JxuQ2trR26b2BZ36ZecdntI7WNFZU3a5L33b0wvb2m_28Ayhalxf22rgZ7Ute_S4S7bmtkTY-7lj8nh1-TC5iab317eTs2lkpRFtJOc2N8YIJ9OEqzyWWum51kZAmrqCx2kaA3dM5M7EhcpBxqpIBY8Lbh0oLuSYHK53F6FZdoBtVnksoCxtDU2HGTepkDE3Q6t_qdaacal1MtCjNS1Cgxhgni2Cr2zoM86yr_zZb_7BHqytLTB7abowFMA_3CfKhoPd</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1555013558</pqid></control><display><type>article</type><title>“Sweet-in-Green” Systems Based on Sugars and Ionic Liquids: New Solubility Data and Thermodynamic Analysis</title><source>American Chemical Society Publications</source><creator>Paduszyński, Kamil ; Okuniewski, Marcin ; Domańska, Urszula</creator><creatorcontrib>Paduszyński, Kamil ; Okuniewski, Marcin ; Domańska, Urszula</creatorcontrib><description>Ionic liquids have been considered as “green” replacements for volatile organic compounds in modern and clean industrial processes since the beginning of the 1990s. It has been shown recently that when combined with renewable feedstocks derived from biomass (like carbohydrates) they form systems attractive for sustainable chemical engineering and technology. Promising features of such systems have induced research activity in various areas of pure and applied chemistry. In particular, new experimental data on different thermodynamic properties of biomaterials dissolved in ionic liquids are required. In this paper we present both experimental and theoretical thermodynamic studies of binary mixtures composed of sugars and two low-viscous ionic liquids based on 1-butyl-3-methylimidazolium cation and dicyanamide or trifluoroacetate anion. Solubility of d-(+)-glucose, d-(−)-fructose, and sucrose in the ionic liquids was determined as a function of temperature. The results indicate that both ionic liquids under consideration can be successfully applied as alternative solvents for sugars. Additionally, thermal characterization of pure sugars was performed with differential scanning calorimetry. The obtained solid–liquid equilibrium phase diagrams were analyzed in terms of perturbed-chain statistical associating fluid theory (PC-SAFT). It was shown that the PC-SAFT model is capable of representing phase behavior of the studied systems quantitatively.</description><identifier>ISSN: 0888-5885</identifier><identifier>EISSN: 1520-5045</identifier><identifier>DOI: 10.1021/ie4033186</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>Biomass ; Cations ; Dissolution ; Ionic liquids ; Solubility ; Sugars ; Thermal properties ; Thermodynamics</subject><ispartof>Industrial & engineering chemistry research, 2013-12, Vol.52 (51), p.18482-18491</ispartof><rights>Copyright © 2013 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a362t-3fab6662d39814b73545f5562e99dc17997e1d02bd67c4be374c9217c1ade4123</citedby><cites>FETCH-LOGICAL-a362t-3fab6662d39814b73545f5562e99dc17997e1d02bd67c4be374c9217c1ade4123</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ie4033186$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ie4033186$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2751,27055,27903,27904,56717,56767</link.rule.ids></links><search><creatorcontrib>Paduszyński, Kamil</creatorcontrib><creatorcontrib>Okuniewski, Marcin</creatorcontrib><creatorcontrib>Domańska, Urszula</creatorcontrib><title>“Sweet-in-Green” Systems Based on Sugars and Ionic Liquids: New Solubility Data and Thermodynamic Analysis</title><title>Industrial & engineering chemistry research</title><addtitle>Ind. Eng. Chem. Res</addtitle><description>Ionic liquids have been considered as “green” replacements for volatile organic compounds in modern and clean industrial processes since the beginning of the 1990s. It has been shown recently that when combined with renewable feedstocks derived from biomass (like carbohydrates) they form systems attractive for sustainable chemical engineering and technology. Promising features of such systems have induced research activity in various areas of pure and applied chemistry. In particular, new experimental data on different thermodynamic properties of biomaterials dissolved in ionic liquids are required. In this paper we present both experimental and theoretical thermodynamic studies of binary mixtures composed of sugars and two low-viscous ionic liquids based on 1-butyl-3-methylimidazolium cation and dicyanamide or trifluoroacetate anion. Solubility of d-(+)-glucose, d-(−)-fructose, and sucrose in the ionic liquids was determined as a function of temperature. The results indicate that both ionic liquids under consideration can be successfully applied as alternative solvents for sugars. Additionally, thermal characterization of pure sugars was performed with differential scanning calorimetry. The obtained solid–liquid equilibrium phase diagrams were analyzed in terms of perturbed-chain statistical associating fluid theory (PC-SAFT). It was shown that the PC-SAFT model is capable of representing phase behavior of the studied systems quantitatively.</description><subject>Biomass</subject><subject>Cations</subject><subject>Dissolution</subject><subject>Ionic liquids</subject><subject>Solubility</subject><subject>Sugars</subject><subject>Thermal properties</subject><subject>Thermodynamics</subject><issn>0888-5885</issn><issn>1520-5045</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqF0MtKw0AUxvFBFKzVhW8wG0EX0bkncaf1CkUX1XWYZE51JJd2TkLJzgfRl_NJjFZcCa4OHH58iz8h-5wdcyb4iQfFpOSJ2SAjrgWLNFN6k4xYkiSRThK9TXYQXxhjWis1IvXH69tsBdBGvo6uA8DweKezHluokJ5bBEebms66JxuQ2trR26b2BZ36ZecdntI7WNFZU3a5L33b0wvb2m_28Ayhalxf22rgZ7Ute_S4S7bmtkTY-7lj8nh1-TC5iab317eTs2lkpRFtJOc2N8YIJ9OEqzyWWum51kZAmrqCx2kaA3dM5M7EhcpBxqpIBY8Lbh0oLuSYHK53F6FZdoBtVnksoCxtDU2HGTepkDE3Q6t_qdaacal1MtCjNS1Cgxhgni2Cr2zoM86yr_zZb_7BHqytLTB7abowFMA_3CfKhoPd</recordid><startdate>20131226</startdate><enddate>20131226</enddate><creator>Paduszyński, Kamil</creator><creator>Okuniewski, Marcin</creator><creator>Domańska, Urszula</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>7U6</scope><scope>C1K</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20131226</creationdate><title>“Sweet-in-Green” Systems Based on Sugars and Ionic Liquids: New Solubility Data and Thermodynamic Analysis</title><author>Paduszyński, Kamil ; Okuniewski, Marcin ; Domańska, Urszula</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a362t-3fab6662d39814b73545f5562e99dc17997e1d02bd67c4be374c9217c1ade4123</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Biomass</topic><topic>Cations</topic><topic>Dissolution</topic><topic>Ionic liquids</topic><topic>Solubility</topic><topic>Sugars</topic><topic>Thermal properties</topic><topic>Thermodynamics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Paduszyński, Kamil</creatorcontrib><creatorcontrib>Okuniewski, Marcin</creatorcontrib><creatorcontrib>Domańska, Urszula</creatorcontrib><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Industrial & engineering chemistry research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Paduszyński, Kamil</au><au>Okuniewski, Marcin</au><au>Domańska, Urszula</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>“Sweet-in-Green” Systems Based on Sugars and Ionic Liquids: New Solubility Data and Thermodynamic Analysis</atitle><jtitle>Industrial & engineering chemistry research</jtitle><addtitle>Ind. Eng. Chem. Res</addtitle><date>2013-12-26</date><risdate>2013</risdate><volume>52</volume><issue>51</issue><spage>18482</spage><epage>18491</epage><pages>18482-18491</pages><issn>0888-5885</issn><eissn>1520-5045</eissn><abstract>Ionic liquids have been considered as “green” replacements for volatile organic compounds in modern and clean industrial processes since the beginning of the 1990s. It has been shown recently that when combined with renewable feedstocks derived from biomass (like carbohydrates) they form systems attractive for sustainable chemical engineering and technology. Promising features of such systems have induced research activity in various areas of pure and applied chemistry. In particular, new experimental data on different thermodynamic properties of biomaterials dissolved in ionic liquids are required. In this paper we present both experimental and theoretical thermodynamic studies of binary mixtures composed of sugars and two low-viscous ionic liquids based on 1-butyl-3-methylimidazolium cation and dicyanamide or trifluoroacetate anion. Solubility of d-(+)-glucose, d-(−)-fructose, and sucrose in the ionic liquids was determined as a function of temperature. The results indicate that both ionic liquids under consideration can be successfully applied as alternative solvents for sugars. Additionally, thermal characterization of pure sugars was performed with differential scanning calorimetry. The obtained solid–liquid equilibrium phase diagrams were analyzed in terms of perturbed-chain statistical associating fluid theory (PC-SAFT). It was shown that the PC-SAFT model is capable of representing phase behavior of the studied systems quantitatively.</abstract><pub>American Chemical Society</pub><doi>10.1021/ie4033186</doi><tpages>10</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0888-5885 |
ispartof | Industrial & engineering chemistry research, 2013-12, Vol.52 (51), p.18482-18491 |
issn | 0888-5885 1520-5045 |
language | eng |
recordid | cdi_proquest_miscellaneous_1692371603 |
source | American Chemical Society Publications |
subjects | Biomass Cations Dissolution Ionic liquids Solubility Sugars Thermal properties Thermodynamics |
title | “Sweet-in-Green” Systems Based on Sugars and Ionic Liquids: New Solubility Data and Thermodynamic Analysis |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-22T16%3A47%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=%E2%80%9CSweet-in-Green%E2%80%9D%20Systems%20Based%20on%20Sugars%20and%20Ionic%20Liquids:%20New%20Solubility%20Data%20and%20Thermodynamic%20Analysis&rft.jtitle=Industrial%20&%20engineering%20chemistry%20research&rft.au=Paduszyn%CC%81ski,%20Kamil&rft.date=2013-12-26&rft.volume=52&rft.issue=51&rft.spage=18482&rft.epage=18491&rft.pages=18482-18491&rft.issn=0888-5885&rft.eissn=1520-5045&rft_id=info:doi/10.1021/ie4033186&rft_dat=%3Cproquest_cross%3E1692371603%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1555013558&rft_id=info:pmid/&rfr_iscdi=true |