Physisorption of Three Calix[4]arenes on Alkyl-Functionalized Mesoporous Silica for Biomimetic Ligand Development

Calixarene physisorption onto alkyl-functionalized silica support is presented as an alternative to tethering to reduce synthetic complexity. Three versions of calix[4]arene were synthesized with differing upper rim functional groups: aromatic amine, tert-butyl, and unfunctionalized. Calixarene mole...

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Veröffentlicht in:	Industrial & engineering chemistry research 2013-11, Vol.52 (47), p.16755-16765
Hauptverfasser:	Desch, Rebecca J, Daniel, Breanna, Frierson, Ashley, Miyahara, Leland, Turner, Benjamin T, Kim, Jungseung, Fantini, Jordan L, Guliants, Vadim V, Thiel, Stephen W, Pinto, Neville G
Format:	Artikel
Sprache:	eng
Schlagworte:	Calixarenes Entropy Evaporation Heat of adsorption Mathematical analysis Myoglobin Silicon dioxide Solvents
Online-Zugang:	Volltext
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