Sintering behaviour of porous ceramic kaolin–corundum composites: Phase evolution and densification

[Display omitted] ► We set out to design controlled mullite–corundum matrixes with appropriate physicochemical properties. ► Corundum from calcined bauxite, constituted by hard particle inclusions acts in the matrix composites as second-phase. ► Main features: the increasing of softening point, the...

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Veröffentlicht in:Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 2011, Vol.528 (29), p.8311-8318
Hauptverfasser: Njiomou Djangang, Chantale, Kamseu, Elie, Kor Ndikontar, Maurice, Lecomte Nana, Gisèle Laure, Soro, Julien, Chinje Melo, Uphie, Elimbi, Antoine, Blanchart, Philippe, Njopwouo, Daniel
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container_end_page 8318
container_issue 29
container_start_page 8311
container_title Materials science & engineering. A, Structural materials : properties, microstructure and processing
container_volume 528
creator Njiomou Djangang, Chantale
Kamseu, Elie
Kor Ndikontar, Maurice
Lecomte Nana, Gisèle Laure
Soro, Julien
Chinje Melo, Uphie
Elimbi, Antoine
Blanchart, Philippe
Njopwouo, Daniel
description [Display omitted] ► We set out to design controlled mullite–corundum matrixes with appropriate physicochemical properties. ► Corundum from calcined bauxite, constituted by hard particle inclusions acts in the matrix composites as second-phase. ► Main features: the increasing of softening point, the absence of vitrification in the temperature range of refractory composites in service and the achievement of a good thermal stability. ► Into the refractory matrix, the such reinforcing second-phase strongly improve the final mechanical properties by deflecting the cracks at the grain boundaries. Kaolinite–corundum (derived from bauxite) associations were assessed as candidate matrices in the field of porous ceramics composites. Particles of corundum were expected to behave as non reactive second phase, deflecting the matrix cracks and increasing the toughness. Porosity and densification were monitored by developing coarse grains (67 wt.% of grains 56 wt.%), the secondary expansion (
doi_str_mv 10.1016/j.msea.2011.07.006
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Kaolinite–corundum (derived from bauxite) associations were assessed as candidate matrices in the field of porous ceramics composites. Particles of corundum were expected to behave as non reactive second phase, deflecting the matrix cracks and increasing the toughness. Porosity and densification were monitored by developing coarse grains (67 wt.% of grains &lt;1 mm and 33 wt.% of grains between 1 and 4 mm) of bauxite-based chamotte with corundum as principal phase. The main features resulting from the use of bauxite-based chamotte were the increase of softening point, the absence of vitrification in the temperature range of refractory composites in service and the achievement of a good thermal stability. For temperatures ranging between 1200 and 1300 °C, flint kaolin matrix did not show any reaction with the red corundum grains. Refractory composites elaborated with more than 30% of corundum exhibited typical final characteristics which satisfied ASTM C155 and ISO 1109 standards for refractory materials, namely: the chemical composition (Al 2O 3 &gt; 56 wt.%), the secondary expansion (&lt;0.1%), the total porosity (∼45 vol.%) and the bulk density (1.9 g/cm 3). 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1873-4936
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source Elsevier ScienceDirect Journals
subjects Ceramics
Chamotte
Clay
Composites
Condensed matter: structure, mechanical and thermal properties
Corundum
Cross-disciplinary physics: materials science
rheology
Deformation and plasticity (including yield, ductility, and superplasticity)
Densification
Exact sciences and technology
Grains
Materials science
Materials synthesis
materials processing
Mechanical and acoustical properties of condensed matter
Mechanical properties
Mechanical properties of solids
Physics
Porosity
Refractories
title Sintering behaviour of porous ceramic kaolin–corundum composites: Phase evolution and densification
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