Recent Advances in Gas Barrier Thin Films via Layer-by-Layer Assembly of Polymers and Platelets
Layer‐by‐layer (LbL) assembly has emerged as the leading non‐vacuum technology for the fabrication of transparent, super gas barrier films. The super gas barrier performance of LbL deposited films has been demonstrated in numerous studies, with a variety of polyelectrolytes, to rival that of metal a...
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| Veröffentlicht in: | Macromolecular rapid communications. 2015-05, Vol.36 (10), p.866-879 |
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| container_title | Macromolecular rapid communications. |
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| creator | Priolo, Morgan A. Holder, Kevin M. Guin, Tyler Grunlan, Jaime C. |
| description | Layer‐by‐layer (LbL) assembly has emerged as the leading non‐vacuum technology for the fabrication of transparent, super gas barrier films. The super gas barrier performance of LbL deposited films has been demonstrated in numerous studies, with a variety of polyelectrolytes, to rival that of metal and metal oxide‐based barrier films. This Feature Article is a mini‐review of LbL‐based multilayer thin films with a ‘nanobrick wall’ microstructure comprising polymeric mortar and nanoplatelet bricks that impart high gas barrier to otherwise permeable polymer substrates. These transparent, water‐based thin films exhibit oxygen transmission rates below 5 × 10‐3 cm3 m‐2 day‐1 atm‐1 and lower permeability than any other barrier material reported. In an effort to put this technology in the proper context, incumbent technologies such as metallized plastics, metal oxides, and flake‐filled polymers are briefly reviewed.
This Feature Article reviews multilayer thin films, deposited layer‐by‐layer to produce a ‘nanobrick wall’ structure that imparts high gas barrier to permeable polymer substrates. These transparent, water‐based thin films exhibit a lower permeability than any other barrier thin film material. |
| doi_str_mv | 10.1002/marc.201500055 |
| format | Article |
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This Feature Article reviews multilayer thin films, deposited layer‐by‐layer to produce a ‘nanobrick wall’ structure that imparts high gas barrier to permeable polymer substrates. 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| subjects | Aluminum Silicates - chemistry Assembly Barriers Blood Platelets - chemistry clays Deposition Diffusion Food Packaging - methods gas barrier Humans layer-by-layer assembly Multilayers Nanostructure Nylons - chemistry Oxygen - chemistry oxygen transmission rate Polyethylene - chemistry Polyethylene Terephthalates - chemistry Polymers Polypropylenes - chemistry Surface Properties Thin films Walls Water - chemistry |
| title | Recent Advances in Gas Barrier Thin Films via Layer-by-Layer Assembly of Polymers and Platelets |
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