Effect of barium content on dielectric and energy storage properties of (Pb,La,Ba)(Zr,Sn,Ti)O3 ceramics

The effect of barium content on phase development, dielectric property and energy storage performance of (Pb0.925−xLa0.05Bax) (Zr0.52Sn0.39Ti0.09)O3 (PLBZST) ceramics synthesized by a solid state reaction method was investigated. X-ray diffraction patterns and scanning electron microscopy micrograph...

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Veröffentlicht in:Ceramics international 2015-03, Vol.41 (2), p.3030-3035
Hauptverfasser: Zhang, Qian, Liu, Xiaolin, Zhang, Yong, Song, Xiaozhen, Zhu, Jia, Baturin, Ivan, Chen, Jianfeng
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container_end_page 3035
container_issue 2
container_start_page 3030
container_title Ceramics international
container_volume 41
creator Zhang, Qian
Liu, Xiaolin
Zhang, Yong
Song, Xiaozhen
Zhu, Jia
Baturin, Ivan
Chen, Jianfeng
description The effect of barium content on phase development, dielectric property and energy storage performance of (Pb0.925−xLa0.05Bax) (Zr0.52Sn0.39Ti0.09)O3 (PLBZST) ceramics synthesized by a solid state reaction method was investigated. X-ray diffraction patterns and scanning electron microscopy micrographs illustrated that the pyrochlore phase was effectively suppressed by the introduction of barium in the (Pb0.925La0.05) (Zr0.52Sn0.39Ti0.09)O3 (PLZST) ceramics. The increase in maximum dielectric constant and the decrease in both transition temperature and switching field with increasing barium content were due to the decrease in the stability of antiferroelectric phase. The energy storage performance of the barium doped PLZST ceramics was studied by measurements of polarization hysteresis loops and discharge curves. The increase of barium content led to the increase of the energy storage density at first and then slight decrease. The study of cyclic charge–discharge showed that barium doped PLZST ceramic capacitor can withstand up to 10,000 cycles with about 8% energy density loss.
doi_str_mv 10.1016/j.ceramint.2014.10.139
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X-ray diffraction patterns and scanning electron microscopy micrographs illustrated that the pyrochlore phase was effectively suppressed by the introduction of barium in the (Pb0.925La0.05) (Zr0.52Sn0.39Ti0.09)O3 (PLZST) ceramics. The increase in maximum dielectric constant and the decrease in both transition temperature and switching field with increasing barium content were due to the decrease in the stability of antiferroelectric phase. The energy storage performance of the barium doped PLZST ceramics was studied by measurements of polarization hysteresis loops and discharge curves. The increase of barium content led to the increase of the energy storage density at first and then slight decrease. 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X-ray diffraction patterns and scanning electron microscopy micrographs illustrated that the pyrochlore phase was effectively suppressed by the introduction of barium in the (Pb0.925La0.05) (Zr0.52Sn0.39Ti0.09)O3 (PLZST) ceramics. The increase in maximum dielectric constant and the decrease in both transition temperature and switching field with increasing barium content were due to the decrease in the stability of antiferroelectric phase. The energy storage performance of the barium doped PLZST ceramics was studied by measurements of polarization hysteresis loops and discharge curves. The increase of barium content led to the increase of the energy storage density at first and then slight decrease. The study of cyclic charge–discharge showed that barium doped PLZST ceramic capacitor can withstand up to 10,000 cycles with about 8% energy density loss.</description><subject>Barium doped PLZST ceramics</subject><subject>C. Dielectric properties</subject><subject>C. Fatigue</subject><subject>Capacitors</subject><subject>Ceramics</subject><subject>Density</subject><subject>Dielectric properties</subject><subject>Discharge</subject><subject>E. 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X-ray diffraction patterns and scanning electron microscopy micrographs illustrated that the pyrochlore phase was effectively suppressed by the introduction of barium in the (Pb0.925La0.05) (Zr0.52Sn0.39Ti0.09)O3 (PLZST) ceramics. The increase in maximum dielectric constant and the decrease in both transition temperature and switching field with increasing barium content were due to the decrease in the stability of antiferroelectric phase. The energy storage performance of the barium doped PLZST ceramics was studied by measurements of polarization hysteresis loops and discharge curves. The increase of barium content led to the increase of the energy storage density at first and then slight decrease. The study of cyclic charge–discharge showed that barium doped PLZST ceramic capacitor can withstand up to 10,000 cycles with about 8% energy density loss.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.ceramint.2014.10.139</doi><tpages>6</tpages></addata></record>
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subjects Barium doped PLZST ceramics
C. Dielectric properties
C. Fatigue
Capacitors
Ceramics
Density
Dielectric properties
Discharge
E. Capacitors
Energy density
Energy storage
Phase (cyclic)
Switching
title Effect of barium content on dielectric and energy storage properties of (Pb,La,Ba)(Zr,Sn,Ti)O3 ceramics
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