Efficient Reaction Based Colorimetric Probe for Sensitive Detection, Quantification, and On-Site Analysis of Nitrite Ions in Natural Water Resources
We have developed a novel aza-BODIPY probe for the sensitive colorimetric detection of the nitrite ions in the aqueous medium by a simple and direct method. This probe selectively recognizes the nitrite ions through a distinct visual color change from bright blue to intense green with a sensitivity...
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Veröffentlicht in: | Analytical chemistry (Washington) 2013-11, Vol.85 (21), p.10008-10012 |
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creator | Adarsh, Nagappanpillai Shanmugasundaram, Madhesh Ramaiah, Danaboyina |
description | We have developed a novel aza-BODIPY probe for the sensitive colorimetric detection of the nitrite ions in the aqueous medium by a simple and direct method. This probe selectively recognizes the nitrite ions through a distinct visual color change from bright blue to intense green with a sensitivity of 20 ppb. Uniquely, this probe can be coated on a glass surface to fabricate a simple solid-state dipstick device that can be used for the visual detection of the nitrite ions in the presence of other competing anions in distilled as well as natural water resources like a sea, lake, and river. Furthermore, this probe can be used for the sensitive detection of the nitrate ions when coupled to a reduction step. Our results demonstrate that this probe not only can be used for the on-site analysis and quantification but also can replace the conventional spot test carried out for the nitrite ions in the laboratory practical experiments. |
doi_str_mv | 10.1021/ac4031303 |
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This probe selectively recognizes the nitrite ions through a distinct visual color change from bright blue to intense green with a sensitivity of 20 ppb. Uniquely, this probe can be coated on a glass surface to fabricate a simple solid-state dipstick device that can be used for the visual detection of the nitrite ions in the presence of other competing anions in distilled as well as natural water resources like a sea, lake, and river. Furthermore, this probe can be used for the sensitive detection of the nitrate ions when coupled to a reduction step. 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Chem</addtitle><description>We have developed a novel aza-BODIPY probe for the sensitive colorimetric detection of the nitrite ions in the aqueous medium by a simple and direct method. This probe selectively recognizes the nitrite ions through a distinct visual color change from bright blue to intense green with a sensitivity of 20 ppb. Uniquely, this probe can be coated on a glass surface to fabricate a simple solid-state dipstick device that can be used for the visual detection of the nitrite ions in the presence of other competing anions in distilled as well as natural water resources like a sea, lake, and river. Furthermore, this probe can be used for the sensitive detection of the nitrate ions when coupled to a reduction step. Our results demonstrate that this probe not only can be used for the on-site analysis and quantification but also can replace the conventional spot test carried out for the nitrite ions in the laboratory practical experiments.</description><subject>Analytical chemistry</subject><subject>Color</subject><subject>Colorimetry</subject><subject>Experiments</subject><subject>Ions</subject><subject>Lakes</subject><subject>Limit of Detection</subject><subject>Molecular Probes</subject><subject>Nitrates</subject><subject>Nitrates - analysis</subject><subject>Nitrites</subject><subject>Spots</subject><subject>Visual</subject><subject>Water - chemistry</subject><subject>Water resources</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkV1rFDEUQIModrv64B-QgAgVHL35msk-1rVqobRqCz4Od7J3IGU2qUlG6P_wB5u6tYg-9CkknJyEexh7JuCNACneotOghAL1gC2EkdC01sqHbAEAqpEdwB7bz_kSQAgQ7WO2J7XQGiws2M-jcfTOUyj8K6ErPgb-DjNt-DpOMfktleQd_5ziQHyMiZ9TyL74H8TfU6HfF17zLzOG4qsId3sMG34WmnNfiB8GnK6zzzyO_NRXWz07jiFzH_gpljnhxL9hoVQ_kOOcHOUn7NGIU6ant-uSXXw4ulh_ak7OPh6vD08a1LAqjTGayCmEQaOzKFqlB7cx4AYnrRXCrZy21qIUqMmOThnaSDXSAAgdKrVkBzvtVYrfZ8ql3_rsaJowUJxzL9qVVKoTrb0fNVJrqYQx96Nar2Sntekq-uIf9LIOoM7rhjJWtVrVsEv2ake5FHNONPZXtQum615Af9O_v-tf2ee3xnnY0uaO_BO8Ai93ALr812v_iX4BnfC10A</recordid><startdate>20131105</startdate><enddate>20131105</enddate><creator>Adarsh, Nagappanpillai</creator><creator>Shanmugasundaram, Madhesh</creator><creator>Ramaiah, Danaboyina</creator><general>American Chemical Society</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7TM</scope><scope>7U5</scope><scope>7U7</scope><scope>7U9</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H94</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope><scope>7QH</scope><scope>7UA</scope><scope>F1W</scope><scope>H97</scope><scope>L.G</scope></search><sort><creationdate>20131105</creationdate><title>Efficient Reaction Based Colorimetric Probe for Sensitive Detection, Quantification, and On-Site Analysis of Nitrite Ions in Natural Water Resources</title><author>Adarsh, Nagappanpillai ; Shanmugasundaram, Madhesh ; Ramaiah, Danaboyina</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a409t-554eec3a0b4ac8a1634bcd50cbc28811c9c4888a21a4e8fc35ed23feb0a07a33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Analytical chemistry</topic><topic>Color</topic><topic>Colorimetry</topic><topic>Experiments</topic><topic>Ions</topic><topic>Lakes</topic><topic>Limit of Detection</topic><topic>Molecular Probes</topic><topic>Nitrates</topic><topic>Nitrates - analysis</topic><topic>Nitrites</topic><topic>Spots</topic><topic>Visual</topic><topic>Water - chemistry</topic><topic>Water resources</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Adarsh, Nagappanpillai</creatorcontrib><creatorcontrib>Shanmugasundaram, Madhesh</creatorcontrib><creatorcontrib>Ramaiah, Danaboyina</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><collection>Aqualine</collection><collection>Water Resources Abstracts</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>Analytical chemistry (Washington)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Adarsh, Nagappanpillai</au><au>Shanmugasundaram, Madhesh</au><au>Ramaiah, Danaboyina</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Efficient Reaction Based Colorimetric Probe for Sensitive Detection, Quantification, and On-Site Analysis of Nitrite Ions in Natural Water Resources</atitle><jtitle>Analytical chemistry (Washington)</jtitle><addtitle>Anal. 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subjects | Analytical chemistry Color Colorimetry Experiments Ions Lakes Limit of Detection Molecular Probes Nitrates Nitrates - analysis Nitrites Spots Visual Water - chemistry Water resources |
title | Efficient Reaction Based Colorimetric Probe for Sensitive Detection, Quantification, and On-Site Analysis of Nitrite Ions in Natural Water Resources |
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