DNA recognition by rhodium(III) polyamine intercalators: considerations of hydrogen bonding and van der Waals interactions

A series of 9,10-phenanthrenequinone diimine (phi) complexes of rhodium have been prepared so as to systematically explore contributions of hydrogen bonding and van der Waals interactions to DNA site specificity. The novel, synthetic complexes Lambda - and Delta -[Rh(en) sub(2)phi] super(3+) (2), as...

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Veröffentlicht in:	Journal of the American Chemical Society 1993-05, Vol.115 (10), p.3877-3882
Hauptverfasser:	Krotz, Achim H, Kuo, Louis Y, Shields, Thomas P, Barton, Jacqueline K
Format:	Artikel
Sprache:	eng
Schlagworte:	Analytical, structural and metabolic biochemistry Biological and medical sciences Dna, deoxyribonucleoproteins Fundamental and applied biological sciences. Psychology Nucleic acids
Online-Zugang:	Volltext
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