Resolution of quaternary mixtures of cadaverine, histamine, putrescine and tyramine by the square wave voltammetry and partial least squares method

This work presents the simultaneous determination of cadaverine, histamine, putrescine and tyramine by square wave voltammetry using a boron-doped diamond electrode. A multivariate calibration method based on partial least square regressions has allowed the resolution of the very high overlapped vol...

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Veröffentlicht in:Talanta (Oxford) 2015-10, Vol.143, p.97-100
Hauptverfasser: Henao-Escobar, W., Domínguez-Renedo, O., Alonso-Lomillo, M.A., Arcos-Martínez, M.J.
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container_start_page 97
container_title Talanta (Oxford)
container_volume 143
creator Henao-Escobar, W.
Domínguez-Renedo, O.
Alonso-Lomillo, M.A.
Arcos-Martínez, M.J.
description This work presents the simultaneous determination of cadaverine, histamine, putrescine and tyramine by square wave voltammetry using a boron-doped diamond electrode. A multivariate calibration method based on partial least square regressions has allowed the resolution of the very high overlapped voltammetric signals obtained for the analyzed biogenic amines. Prediction errors lower than 9% have been obtained when concentration of quaternary mixtures were calculated. The developed procedure has been applied in the analysis of ham samples, which results are in good agreement with those obtained using the standard HPLC method. [Display omitted] •Voltammetric determination of Cad, His, Put and Tyr using a boron-doped diamond electrode.•PLS regressions allow the simultaneous determination of four biogenic amines.•Successful simultaneous determination of Cad, His, Put and Tyr in complex real samples.
doi_str_mv 10.1016/j.talanta.2015.05.047
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A multivariate calibration method based on partial least square regressions has allowed the resolution of the very high overlapped voltammetric signals obtained for the analyzed biogenic amines. Prediction errors lower than 9% have been obtained when concentration of quaternary mixtures were calculated. The developed procedure has been applied in the analysis of ham samples, which results are in good agreement with those obtained using the standard HPLC method. [Display omitted] •Voltammetric determination of Cad, His, Put and Tyr using a boron-doped diamond electrode.•PLS regressions allow the simultaneous determination of four biogenic amines.•Successful simultaneous determination of Cad, His, Put and Tyr in complex real samples.</abstract><cop>Netherlands</cop><pub>Elsevier B.V</pub><pmid>26078134</pmid><doi>10.1016/j.talanta.2015.05.047</doi><tpages>4</tpages></addata></record>
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subjects Biogenic Amines - analysis
Boron - chemistry
Boron-doped diamond electrode
Cadaverine
Cadaverine - analysis
Calibration
Diamond - chemistry
Electrochemistry - instrumentation
Electrochemistry - methods
Electrodes
Food Contamination - analysis
Histamine
Histamine - analysis
Least-Squares Analysis
Meat Products - analysis
Partial least squares
Putrescine
Putrescine - analysis
Time Factors
Tyramine
Tyramine - analysis
title Resolution of quaternary mixtures of cadaverine, histamine, putrescine and tyramine by the square wave voltammetry and partial least squares method
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