Integration of a semi-rigid proline ligand and 4,4'-bipyridine in the synthesis of homochiral metal-organic frameworks with helices
A pair of 3-D homochiral metal-organic frameworks (HMOFs) based on a mixed semi-rigid 5-(2-carboxypyrrolidine-1-carbonyl)isophthalate (PIA) ligand and rigid 4,4'-bipyridine (bipy), [Co3((R)-PIA)2(bipy)3]·6H2O (1-D) and [Co3((S)-PIA)2(bipy)3]·6H2O (1-L) are synthesized and structurally character...
Gespeichert in:
| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2015-06, Vol.44 (24), p.11052-11056 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 11056 |
|---|---|
| container_issue | 24 |
| container_start_page | 11052 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 44 |
| creator | Xu, Zhong-Xuan Kang, Yao Han, Min-Le Li, Dong-Sheng Zhang, Jian |
| description | A pair of 3-D homochiral metal-organic frameworks (HMOFs) based on a mixed semi-rigid 5-(2-carboxypyrrolidine-1-carbonyl)isophthalate (PIA) ligand and rigid 4,4'-bipyridine (bipy), [Co3((R)-PIA)2(bipy)3]·6H2O (1-D) and [Co3((S)-PIA)2(bipy)3]·6H2O (1-L) are synthesized and structurally characterized. They are enantiomers and exhibit three-dimensional open frameworks. In each structure, the PIA ligands link the Co centers into homochiral frameworks with large open channels that are occupied by the bipy ligands. Interesting helical chains built from the connectivity between PIA ligands and Co centers are presented. Antiferromagnetic coupling is observed in 1-D. These results demonstrated that the mixed ligand approach is successful for the construction of HMOFs. |
| doi_str_mv | 10.1039/c5dt01151e |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1687997804</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1687997804</sourcerecordid><originalsourceid>FETCH-LOGICAL-c287t-233898c12b9e7dde589fba710fece4232747923ca456695a821103e3c83b88143</originalsourceid><addsrcrecordid>eNo9kEtLxDAUhYMovjf-AMlOEat5NE2ylHF8gOBG1yVNb6fRthmTDMOs_eO2vhaXc-F-98A5CJ1QckUJ19dW1IlQKihsoX2aS5lpxvPt_50Ve-ggxjdCGCOC7aI9JrTOGRf76PNxSLAIJjk_YN9ggyP0Lgtu4Wq8DL5zA-DOLcxQ42nyy_wsq9xyE1w9ndyAUws4boZRoouTR-t7b1sXTId7SKbLfBj_ncVNMD2sfXiPeO1Si1vonIV4hHYa00U4_tVD9Ho3f5k9ZE_P94-zm6fMMiVTxjhXWlnKKg2yrkEo3VRGUtKAhTENk7kcg1uTi6LQwihGx3qAW8UrpWjOD9H5j--Y62MFMZW9ixa6zgzgV7GkhZJaS0Um9OIHtcHHGKApl8H1JmxKSsqp9HImbl--S5-P8Omv76rqof5H_1rmXx_nfVI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1687997804</pqid></control><display><type>article</type><title>Integration of a semi-rigid proline ligand and 4,4'-bipyridine in the synthesis of homochiral metal-organic frameworks with helices</title><source>MEDLINE</source><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Xu, Zhong-Xuan ; Kang, Yao ; Han, Min-Le ; Li, Dong-Sheng ; Zhang, Jian</creator><creatorcontrib>Xu, Zhong-Xuan ; Kang, Yao ; Han, Min-Le ; Li, Dong-Sheng ; Zhang, Jian</creatorcontrib><description>A pair of 3-D homochiral metal-organic frameworks (HMOFs) based on a mixed semi-rigid 5-(2-carboxypyrrolidine-1-carbonyl)isophthalate (PIA) ligand and rigid 4,4'-bipyridine (bipy), [Co3((R)-PIA)2(bipy)3]·6H2O (1-D) and [Co3((S)-PIA)2(bipy)3]·6H2O (1-L) are synthesized and structurally characterized. They are enantiomers and exhibit three-dimensional open frameworks. In each structure, the PIA ligands link the Co centers into homochiral frameworks with large open channels that are occupied by the bipy ligands. Interesting helical chains built from the connectivity between PIA ligands and Co centers are presented. Antiferromagnetic coupling is observed in 1-D. These results demonstrated that the mixed ligand approach is successful for the construction of HMOFs.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c5dt01151e</identifier><identifier>PMID: 25994235</identifier><language>eng</language><publisher>England</publisher><subject>Cobalt - chemistry ; Crystallography, X-Ray ; Ligands ; Models, Molecular ; Molecular Conformation ; Organometallic Compounds - chemical synthesis ; Organometallic Compounds - chemistry ; Phthalic Acids - chemical synthesis ; Phthalic Acids - chemistry ; Proline - chemistry ; Pyridines - chemical synthesis ; Pyridines - chemistry ; Pyrrolidines - chemical synthesis ; Pyrrolidines - chemistry ; Stereoisomerism</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2015-06, Vol.44 (24), p.11052-11056</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c287t-233898c12b9e7dde589fba710fece4232747923ca456695a821103e3c83b88143</citedby><cites>FETCH-LOGICAL-c287t-233898c12b9e7dde589fba710fece4232747923ca456695a821103e3c83b88143</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25994235$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Xu, Zhong-Xuan</creatorcontrib><creatorcontrib>Kang, Yao</creatorcontrib><creatorcontrib>Han, Min-Le</creatorcontrib><creatorcontrib>Li, Dong-Sheng</creatorcontrib><creatorcontrib>Zhang, Jian</creatorcontrib><title>Integration of a semi-rigid proline ligand and 4,4'-bipyridine in the synthesis of homochiral metal-organic frameworks with helices</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>A pair of 3-D homochiral metal-organic frameworks (HMOFs) based on a mixed semi-rigid 5-(2-carboxypyrrolidine-1-carbonyl)isophthalate (PIA) ligand and rigid 4,4'-bipyridine (bipy), [Co3((R)-PIA)2(bipy)3]·6H2O (1-D) and [Co3((S)-PIA)2(bipy)3]·6H2O (1-L) are synthesized and structurally characterized. They are enantiomers and exhibit three-dimensional open frameworks. In each structure, the PIA ligands link the Co centers into homochiral frameworks with large open channels that are occupied by the bipy ligands. Interesting helical chains built from the connectivity between PIA ligands and Co centers are presented. Antiferromagnetic coupling is observed in 1-D. These results demonstrated that the mixed ligand approach is successful for the construction of HMOFs.</description><subject>Cobalt - chemistry</subject><subject>Crystallography, X-Ray</subject><subject>Ligands</subject><subject>Models, Molecular</subject><subject>Molecular Conformation</subject><subject>Organometallic Compounds - chemical synthesis</subject><subject>Organometallic Compounds - chemistry</subject><subject>Phthalic Acids - chemical synthesis</subject><subject>Phthalic Acids - chemistry</subject><subject>Proline - chemistry</subject><subject>Pyridines - chemical synthesis</subject><subject>Pyridines - chemistry</subject><subject>Pyrrolidines - chemical synthesis</subject><subject>Pyrrolidines - chemistry</subject><subject>Stereoisomerism</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNo9kEtLxDAUhYMovjf-AMlOEat5NE2ylHF8gOBG1yVNb6fRthmTDMOs_eO2vhaXc-F-98A5CJ1QckUJ19dW1IlQKihsoX2aS5lpxvPt_50Ve-ggxjdCGCOC7aI9JrTOGRf76PNxSLAIJjk_YN9ggyP0Lgtu4Wq8DL5zA-DOLcxQ42nyy_wsq9xyE1w9ndyAUws4boZRoouTR-t7b1sXTId7SKbLfBj_ncVNMD2sfXiPeO1Si1vonIV4hHYa00U4_tVD9Ho3f5k9ZE_P94-zm6fMMiVTxjhXWlnKKg2yrkEo3VRGUtKAhTENk7kcg1uTi6LQwihGx3qAW8UrpWjOD9H5j--Y62MFMZW9ixa6zgzgV7GkhZJaS0Um9OIHtcHHGKApl8H1JmxKSsqp9HImbl--S5-P8Omv76rqof5H_1rmXx_nfVI</recordid><startdate>20150628</startdate><enddate>20150628</enddate><creator>Xu, Zhong-Xuan</creator><creator>Kang, Yao</creator><creator>Han, Min-Le</creator><creator>Li, Dong-Sheng</creator><creator>Zhang, Jian</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20150628</creationdate><title>Integration of a semi-rigid proline ligand and 4,4'-bipyridine in the synthesis of homochiral metal-organic frameworks with helices</title><author>Xu, Zhong-Xuan ; Kang, Yao ; Han, Min-Le ; Li, Dong-Sheng ; Zhang, Jian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c287t-233898c12b9e7dde589fba710fece4232747923ca456695a821103e3c83b88143</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Cobalt - chemistry</topic><topic>Crystallography, X-Ray</topic><topic>Ligands</topic><topic>Models, Molecular</topic><topic>Molecular Conformation</topic><topic>Organometallic Compounds - chemical synthesis</topic><topic>Organometallic Compounds - chemistry</topic><topic>Phthalic Acids - chemical synthesis</topic><topic>Phthalic Acids - chemistry</topic><topic>Proline - chemistry</topic><topic>Pyridines - chemical synthesis</topic><topic>Pyridines - chemistry</topic><topic>Pyrrolidines - chemical synthesis</topic><topic>Pyrrolidines - chemistry</topic><topic>Stereoisomerism</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Zhong-Xuan</creatorcontrib><creatorcontrib>Kang, Yao</creatorcontrib><creatorcontrib>Han, Min-Le</creatorcontrib><creatorcontrib>Li, Dong-Sheng</creatorcontrib><creatorcontrib>Zhang, Jian</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Zhong-Xuan</au><au>Kang, Yao</au><au>Han, Min-Le</au><au>Li, Dong-Sheng</au><au>Zhang, Jian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Integration of a semi-rigid proline ligand and 4,4'-bipyridine in the synthesis of homochiral metal-organic frameworks with helices</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2015-06-28</date><risdate>2015</risdate><volume>44</volume><issue>24</issue><spage>11052</spage><epage>11056</epage><pages>11052-11056</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A pair of 3-D homochiral metal-organic frameworks (HMOFs) based on a mixed semi-rigid 5-(2-carboxypyrrolidine-1-carbonyl)isophthalate (PIA) ligand and rigid 4,4'-bipyridine (bipy), [Co3((R)-PIA)2(bipy)3]·6H2O (1-D) and [Co3((S)-PIA)2(bipy)3]·6H2O (1-L) are synthesized and structurally characterized. They are enantiomers and exhibit three-dimensional open frameworks. In each structure, the PIA ligands link the Co centers into homochiral frameworks with large open channels that are occupied by the bipy ligands. Interesting helical chains built from the connectivity between PIA ligands and Co centers are presented. Antiferromagnetic coupling is observed in 1-D. These results demonstrated that the mixed ligand approach is successful for the construction of HMOFs.</abstract><cop>England</cop><pmid>25994235</pmid><doi>10.1039/c5dt01151e</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2015-06, Vol.44 (24), p.11052-11056 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1687997804 |
| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Cobalt - chemistry Crystallography, X-Ray Ligands Models, Molecular Molecular Conformation Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Phthalic Acids - chemical synthesis Phthalic Acids - chemistry Proline - chemistry Pyridines - chemical synthesis Pyridines - chemistry Pyrrolidines - chemical synthesis Pyrrolidines - chemistry Stereoisomerism |
| title | Integration of a semi-rigid proline ligand and 4,4'-bipyridine in the synthesis of homochiral metal-organic frameworks with helices |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-18T07%3A04%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Integration%20of%20a%20semi-rigid%20proline%20ligand%20and%204,4'-bipyridine%20in%20the%20synthesis%20of%20homochiral%20metal-organic%20frameworks%20with%20helices&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Xu,%20Zhong-Xuan&rft.date=2015-06-28&rft.volume=44&rft.issue=24&rft.spage=11052&rft.epage=11056&rft.pages=11052-11056&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/c5dt01151e&rft_dat=%3Cproquest_cross%3E1687997804%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1687997804&rft_id=info:pmid/25994235&rfr_iscdi=true |