Isolation of a germanium(II) cation and a germylene iron carbonyl complex utilizing an imidazolin-2-iminato ligand

Isolation of a germanium(II) cation and a germylene iron carbonyl complex utilizing an imidazolin-2-iminato ligand

The novel amino(imino)germylene 1 was prepared by the conversion of HNIPr (NIPr = bis(2,6-diisopropylphenyl)imidazolin-2-imino) with 1 equiv. of Ge[N(SiMe3)2]2. Germylene 1 reacts with B(C6F5)3 to afford the borate salt 2(+)[MeB(C6F5)3](-) in a methyl-abstraction and ring-closing reaction. The conve...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2015-06, Vol.44 (24), p.10952-10956
Hauptverfasser: Ochiai, Tatsumi, Franz, Daniel, Wu, Xiao-Nan, Inoue, Shigeyoshi
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container_issue 24
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Ochiai, Tatsumi
Franz, Daniel
Wu, Xiao-Nan
Inoue, Shigeyoshi
description The novel amino(imino)germylene 1 was prepared by the conversion of HNIPr (NIPr = bis(2,6-diisopropylphenyl)imidazolin-2-imino) with 1 equiv. of Ge[N(SiMe3)2]2. Germylene 1 reacts with B(C6F5)3 to afford the borate salt 2(+)[MeB(C6F5)3](-) in a methyl-abstraction and ring-closing reaction. The conversion of 2 with Fe2(CO)9 furnishes the germylene iron carbonyl complex 3 with a trigonal planar-coordinate germanium atom.
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title Isolation of a germanium(II) cation and a germylene iron carbonyl complex utilizing an imidazolin-2-iminato ligand
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