Acceleration Effects of Phosphine Ligands on the Rhodium-Catalyzed Dehydrogenative Silylation and Germylation of Unactivated C(sp3)–H Bonds

The current work describes the marked rate of acceleration caused by phosphine ligands on the rhodium-catalyzed dehydrogenative silylation and germylation of unactivated C­(sp3)–H bonds. The reactivity was affected by the steric and electronic nature of the phosphine ligands. The use of the bulky an...

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Veröffentlicht in:	Journal of organic chemistry 2015-06, Vol.80 (11), p.5407-5414
Hauptverfasser:	Murai, Masahito, Takeshima, Hirotaka, Morita, Haruka, Kuninobu, Yoichiro, Takai, Kazuhiko
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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