Quantum chemical analysis for the formation of glycine in the interstellar medium
Glycine （C2H5NO2） was the first amino acid to be detected in space by the stardust space probe in Comet Wild2, and is used by living organisms to make proteins. We discuss three different reaction paths for the formation of glycine in interstellar space from some simpler molecules detected in the in...
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| Veröffentlicht in: | Research in astronomy and astrophysics 2013-08, Vol.13 (8), p.912-920 |
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| container_title | Research in astronomy and astrophysics |
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| creator | Singh, Amresh Misra, Alka Tandon, Poonam |
| description | Glycine （C2H5NO2） was the first amino acid to be detected in space by the stardust space probe in Comet Wild2, and is used by living organisms to make proteins. We discuss three different reaction paths for the formation of glycine in interstellar space from some simpler molecules detected in the interstellar medium. The possibility of the formation of glycine in interstellar space is considered by radicalradical and radical-molecule interaction schemes using quantum chemical calculations with density functional theory at the B3LYP/6-31G （d,p） level. In the chemical pathways we discuss, a few reactions are found to be totally exothermic and barrierless while others are endothermic with a very small reaction barrier, thus giving rise to a high probability of forming glycine in interstellar space. |
| doi_str_mv | 10.1088/1674-4527/13/8/003 |
| format | Article |
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| ispartof | Research in astronomy and astrophysics, 2013-08, Vol.13 (8), p.912-920 |
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| language | eng |
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| source | IOP Publishing Journals; Alma/SFX Local Collection |
| subjects | Amino acids Comets Endothermic reactions Formations Glycine Interstellar matter Interstellar space Quantum chemistry 化学分析 反应路径 密度泛函理论 星际介质 星际空间 甘氨酸 自由基分子 量子化学计算 |
| title | Quantum chemical analysis for the formation of glycine in the interstellar medium |
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