Double junction photoelectrochemical solar cells based on Cu2ZnSnS4/Cu2ZnSnSe4 thin film as composite photocathode
•A new structure photocathode with CZTS/CZTSe double-layer film was fabricated via a blade coating process.•The film was to convert DSSC into double junction solar cell by the replacement of the Pt film with CZTS/CZTSe film.•CZTS and CZTSe nanoparticles were synthesized by a low-cost solvothermal pr...
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| Veröffentlicht in: | Applied surface science 2014-02, Vol.292, p.55-62 |
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| creator | Zhu, L. Qiang, Y.H. Zhao, Y.L. Gu, X.Q. |
| description | •A new structure photocathode with CZTS/CZTSe double-layer film was fabricated via a blade coating process.•The film was to convert DSSC into double junction solar cell by the replacement of the Pt film with CZTS/CZTSe film.•CZTS and CZTSe nanoparticles were synthesized by a low-cost solvothermal process to high-efficiency solar cells.•The prepared cell achieves efficiency as high as 8.83% which is similar to conventional Pt-based DSSC (8.49%).
A solvothermal method was used to synthesize Cu2ZnSnS4 (CZTS) and Cu2ZnSnSe4 (CZTSe) nanoparticles. CZTS/CZTSe bilayer films have been fabricated via a layer-by-layer blade coating process on the fluorine dope tin oxide (FTO) substrates. We converted conventional dye-sensitized solar cells (DSSCs) into double junction photoelectrochemical solar cells with the replacement of the Pt-coated counter electrode with the as-prepared films as composite photocathodes. Compared with conventional DSSCs, the cells show an increased short circuit current and power conversion efficiency. |
| doi_str_mv | 10.1016/j.apsusc.2013.11.063 |
| format | Article |
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A solvothermal method was used to synthesize Cu2ZnSnS4 (CZTS) and Cu2ZnSnSe4 (CZTSe) nanoparticles. CZTS/CZTSe bilayer films have been fabricated via a layer-by-layer blade coating process on the fluorine dope tin oxide (FTO) substrates. We converted conventional dye-sensitized solar cells (DSSCs) into double junction photoelectrochemical solar cells with the replacement of the Pt-coated counter electrode with the as-prepared films as composite photocathodes. Compared with conventional DSSCs, the cells show an increased short circuit current and power conversion efficiency.</description><identifier>ISSN: 0169-4332</identifier><identifier>EISSN: 1873-5584</identifier><identifier>DOI: 10.1016/j.apsusc.2013.11.063</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Cross-disciplinary physics: materials science; rheology ; Cu2ZnSnS4 ; Cu2ZnSnSe4 ; CZT ; Dye-sensitized solar cells ; Electrodes ; Energy conversion efficiency ; Exact sciences and technology ; Nanoparticles ; Photocathode ; Photocathodes ; Photoelectrochemical solar cells ; Photovoltaic cells ; Physics ; Solar cells ; Solvothermal ; Thin films ; Tin oxides</subject><ispartof>Applied surface science, 2014-02, Vol.292, p.55-62</ispartof><rights>2013 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c340t-b72b8148feb4c708e86aea7e5e51801ae5f34db09f67affa1cbcee4a991259093</citedby><cites>FETCH-LOGICAL-c340t-b72b8148feb4c708e86aea7e5e51801ae5f34db09f67affa1cbcee4a991259093</cites><orcidid>0000-0002-1546-9931</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.apsusc.2013.11.063$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,777,781,3537,27905,27906,45976</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28607484$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhu, L.</creatorcontrib><creatorcontrib>Qiang, Y.H.</creatorcontrib><creatorcontrib>Zhao, Y.L.</creatorcontrib><creatorcontrib>Gu, X.Q.</creatorcontrib><title>Double junction photoelectrochemical solar cells based on Cu2ZnSnS4/Cu2ZnSnSe4 thin film as composite photocathode</title><title>Applied surface science</title><description>•A new structure photocathode with CZTS/CZTSe double-layer film was fabricated via a blade coating process.•The film was to convert DSSC into double junction solar cell by the replacement of the Pt film with CZTS/CZTSe film.•CZTS and CZTSe nanoparticles were synthesized by a low-cost solvothermal process to high-efficiency solar cells.•The prepared cell achieves efficiency as high as 8.83% which is similar to conventional Pt-based DSSC (8.49%).
A solvothermal method was used to synthesize Cu2ZnSnS4 (CZTS) and Cu2ZnSnSe4 (CZTSe) nanoparticles. CZTS/CZTSe bilayer films have been fabricated via a layer-by-layer blade coating process on the fluorine dope tin oxide (FTO) substrates. We converted conventional dye-sensitized solar cells (DSSCs) into double junction photoelectrochemical solar cells with the replacement of the Pt-coated counter electrode with the as-prepared films as composite photocathodes. Compared with conventional DSSCs, the cells show an increased short circuit current and power conversion efficiency.</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Cu2ZnSnS4</subject><subject>Cu2ZnSnSe4</subject><subject>CZT</subject><subject>Dye-sensitized solar cells</subject><subject>Electrodes</subject><subject>Energy conversion efficiency</subject><subject>Exact sciences and technology</subject><subject>Nanoparticles</subject><subject>Photocathode</subject><subject>Photocathodes</subject><subject>Photoelectrochemical solar cells</subject><subject>Photovoltaic cells</subject><subject>Physics</subject><subject>Solar cells</subject><subject>Solvothermal</subject><subject>Thin films</subject><subject>Tin oxides</subject><issn>0169-4332</issn><issn>1873-5584</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kEGL1TAQx4Mo-Hz6DTzkInhpN9OkbXoR5Lm6woKH1YuXkKYTXh5tUzOt4Lc3j64e9zQD85sZ_j_G3oIoQUBzcyntQhu5shIgS4BSNPIZO4BuZVHXWj1nh4x1hZKyesleEV2EgCpPDyx9ils_Ir9ss1tDnPlyjmvEEd2aojvjFJwdOcXRJu5wHIn3lnDgmTxt1c_5YX5QN_86VHw9h5n7ME7cEndxWiKFFferzq7nOOBr9sLbkfDNYz2yH59vv5_uivtvX76ePt4XTiqxFn1b9RqU9tgr1wqNurFoW6yxBi3AYu2lGnrR-aa13ltwvUNUtuugqjvRySN7v99dUvy1Ia1mCnTNYGeMGxlodK1BymzlyNSOuhSJEnqzpDDZ9MeAMFfF5mJ2xeaq2ACYrDivvXv8YClr8snOLtD_3Uo3olVaZe7DzmGO-ztgMuQCzg6HkLJoM8Tw9KO_Z0CVuA</recordid><startdate>20140215</startdate><enddate>20140215</enddate><creator>Zhu, L.</creator><creator>Qiang, Y.H.</creator><creator>Zhao, Y.L.</creator><creator>Gu, X.Q.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-1546-9931</orcidid></search><sort><creationdate>20140215</creationdate><title>Double junction photoelectrochemical solar cells based on Cu2ZnSnS4/Cu2ZnSnSe4 thin film as composite photocathode</title><author>Zhu, L. ; Qiang, Y.H. ; Zhao, Y.L. ; Gu, X.Q.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c340t-b72b8148feb4c708e86aea7e5e51801ae5f34db09f67affa1cbcee4a991259093</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Cu2ZnSnS4</topic><topic>Cu2ZnSnSe4</topic><topic>CZT</topic><topic>Dye-sensitized solar cells</topic><topic>Electrodes</topic><topic>Energy conversion efficiency</topic><topic>Exact sciences and technology</topic><topic>Nanoparticles</topic><topic>Photocathode</topic><topic>Photocathodes</topic><topic>Photoelectrochemical solar cells</topic><topic>Photovoltaic cells</topic><topic>Physics</topic><topic>Solar cells</topic><topic>Solvothermal</topic><topic>Thin films</topic><topic>Tin oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhu, L.</creatorcontrib><creatorcontrib>Qiang, Y.H.</creatorcontrib><creatorcontrib>Zhao, Y.L.</creatorcontrib><creatorcontrib>Gu, X.Q.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied surface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhu, L.</au><au>Qiang, Y.H.</au><au>Zhao, Y.L.</au><au>Gu, X.Q.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Double junction photoelectrochemical solar cells based on Cu2ZnSnS4/Cu2ZnSnSe4 thin film as composite photocathode</atitle><jtitle>Applied surface science</jtitle><date>2014-02-15</date><risdate>2014</risdate><volume>292</volume><spage>55</spage><epage>62</epage><pages>55-62</pages><issn>0169-4332</issn><eissn>1873-5584</eissn><abstract>•A new structure photocathode with CZTS/CZTSe double-layer film was fabricated via a blade coating process.•The film was to convert DSSC into double junction solar cell by the replacement of the Pt film with CZTS/CZTSe film.•CZTS and CZTSe nanoparticles were synthesized by a low-cost solvothermal process to high-efficiency solar cells.•The prepared cell achieves efficiency as high as 8.83% which is similar to conventional Pt-based DSSC (8.49%).
A solvothermal method was used to synthesize Cu2ZnSnS4 (CZTS) and Cu2ZnSnSe4 (CZTSe) nanoparticles. CZTS/CZTSe bilayer films have been fabricated via a layer-by-layer blade coating process on the fluorine dope tin oxide (FTO) substrates. We converted conventional dye-sensitized solar cells (DSSCs) into double junction photoelectrochemical solar cells with the replacement of the Pt-coated counter electrode with the as-prepared films as composite photocathodes. Compared with conventional DSSCs, the cells show an increased short circuit current and power conversion efficiency.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.apsusc.2013.11.063</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-1546-9931</orcidid></addata></record> |
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| subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Cu2ZnSnS4 Cu2ZnSnSe4 CZT Dye-sensitized solar cells Electrodes Energy conversion efficiency Exact sciences and technology Nanoparticles Photocathode Photocathodes Photoelectrochemical solar cells Photovoltaic cells Physics Solar cells Solvothermal Thin films Tin oxides |
| title | Double junction photoelectrochemical solar cells based on Cu2ZnSnS4/Cu2ZnSnSe4 thin film as composite photocathode |
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