Effect of Ag content on the microstructure, tribological and corrosion properties of amorphous carbon coatings on 316L SS

The mechanical durability and stability of a-C:Ag nanocomposite coatings deposited on 316L stainless steel substrates were investigated with respect to Ag content. The coatings were prepared using graphite and Ag targets. The coatings were characterized by Raman spectroscopy, X-ray photoelectron spe...

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Veröffentlicht in:Surface & coatings technology 2014-02, Vol.240, p.128-136
Hauptverfasser: Dhandapani, Vishnu shankar, Thangavel, Elangovan, Arumugam, Madhankumar, Shin, Kwang Seon, Veeraraghavan, Veeravazhuthi, Yau, Su Yee, Kim, Changlae, Kim, Dae-Eun
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container_end_page 136
container_issue
container_start_page 128
container_title Surface & coatings technology
container_volume 240
creator Dhandapani, Vishnu shankar
Thangavel, Elangovan
Arumugam, Madhankumar
Shin, Kwang Seon
Veeraraghavan, Veeravazhuthi
Yau, Su Yee
Kim, Changlae
Kim, Dae-Eun
description The mechanical durability and stability of a-C:Ag nanocomposite coatings deposited on 316L stainless steel substrates were investigated with respect to Ag content. The coatings were prepared using graphite and Ag targets. The coatings were characterized by Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and transmission electron microscopy (TEM). XPS and Raman spectroscopy confirmed the formation of sp2 clusters in the a-C coating with 4.46at.% Ag content. Surface roughness was found to be reduced by increasing the Ag content in a-C coatings as confirmed by AFM analysis. TEM analysis also showed the presence of nanostructured Ag in the a-C matrix. The tribological and corrosion properties of these coatings were also investigated. Hardness and Young's modulus were found to decrease with increase in Ag content. The experimental results revealed that the friction coefficient could be significantly reduced due to inclusion of Ag in the composite coating. In particular, the coating with an Ag content of 4.46at.% showed the best tribological behavior. Inclusion of Ag also improved the corrosion resistance of the composite coating. It was concluded that Ag content in a-C:Ag nanocomposite coating has a significant effect on the tribological and corrosion properties of the coating. Experimental results revealed that optimum Ag content (4.46at.%) in a-C:Ag nanocomposite coatings may be effectively utilized to protect 316L stainless steel substrates. •a-C:Ag coatings were prepared on 316L stainless steel by using RF sputtering method.•Silver strongly influences the wear behavior of a-C:Ag coatings.•The corrosion resistance of coatings is enhanced by silver content.•4.46at.% Ag content resulted to superior durability and stability properties of a-C:Ag coating.
doi_str_mv 10.1016/j.surfcoat.2013.12.025
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The coatings were prepared using graphite and Ag targets. The coatings were characterized by Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and transmission electron microscopy (TEM). XPS and Raman spectroscopy confirmed the formation of sp2 clusters in the a-C coating with 4.46at.% Ag content. Surface roughness was found to be reduced by increasing the Ag content in a-C coatings as confirmed by AFM analysis. TEM analysis also showed the presence of nanostructured Ag in the a-C matrix. The tribological and corrosion properties of these coatings were also investigated. Hardness and Young's modulus were found to decrease with increase in Ag content. The experimental results revealed that the friction coefficient could be significantly reduced due to inclusion of Ag in the composite coating. In particular, the coating with an Ag content of 4.46at.% showed the best tribological behavior. 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subjects 316L SS
AFM
Amorphous carbon
Applied sciences
Atomic force microscopy
Austenitic stainless steels
Coatings
Corrosion
Corrosion environments
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Heat resistant steels
Inclusions
Materials science
Metals. Metallurgy
Nanostructure
Physics
Production techniques
RF sputtering
Silver
Surface treatment
Surface treatments
Tribological property
Tribology
X-ray photoelectron spectroscopy
title Effect of Ag content on the microstructure, tribological and corrosion properties of amorphous carbon coatings on 316L SS
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