Research on Chemical Composition Changing of Heteroatom Compounds during Asphalt Aging Process

It’s easy to cause asphalt aging in the production, storage, transportation and construction sectors; the polar compounds of asphalt in the aging process were studied by using negative-ion electrospray ionization (ESI) Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry (MS).Test re...

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Veröffentlicht in:Applied Mechanics and Materials 2015-03, Vol.744-746 (Advances in Civil Engineering and Transportation IV), p.1456-1462
Hauptverfasser: Zhang, Hai Yan, He, Min, Zhang, Yan Jun, Liang, Jun Lin, Xiong, Jian Ping, Chen, Yan Ju, Cao, Dong Wei
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container_end_page 1462
container_issue Advances in Civil Engineering and Transportation IV
container_start_page 1456
container_title Applied Mechanics and Materials
container_volume 744-746
creator Zhang, Hai Yan
He, Min
Zhang, Yan Jun
Liang, Jun Lin
Xiong, Jian Ping
Chen, Yan Ju
Cao, Dong Wei
description It’s easy to cause asphalt aging in the production, storage, transportation and construction sectors; the polar compounds of asphalt in the aging process were studied by using negative-ion electrospray ionization (ESI) Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry (MS).Test results showed that, with the deepening of aging process, molecular weight of asphalt samples was increasing. Ox class compounds had the biggest content change; Content of Nx class compounds were basically stable; Content changing range of class NxOy compounds was affected by types of compounds. Aging degree of heteroatom compounds was affected by molecular condensation degree, and oxidation rate of low DBE compounds was higher than that of high DBE compounds. The result is of value to analysis of asphalt production and asphalt recycling.
doi_str_mv 10.4028/www.scientific.net/AMM.744-746.1456
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subjects Asphalt
Cyclotron resonance
Fourier transforms
Ionization
Mass spectrometry
Molecular weight
Recycling
Transportation
title Research on Chemical Composition Changing of Heteroatom Compounds during Asphalt Aging Process
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