Impact of different dopants on the switching properties of ferroelectric hafniumoxide

The wake-up behavior of ferroelectric thin film capacitors based on doped hafnium oxide dielectrics in TiN-based metal-insulator-metal structures is reported. After field cycling a remanent polarization up to 40 µC/cm2 and a high coercive field of about 1 MV/cm was observed. Doping of HfO2 by differ...

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Veröffentlicht in:Japanese Journal of Applied Physics 2014-08, Vol.53 (8S1), p.8-1-08LE02-5
Hauptverfasser: Schroeder, Uwe, Yurchuk, Ekaterina, Müller, Johannes, Martin, Dominik, Schenk, Tony, Polakowski, Patrick, Adelmann, Christoph, Popovici, Mihaela I., Kalinin, Sergei V., Mikolajick, Thomas
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container_end_page 1-08LE02-5
container_issue 8S1
container_start_page 8
container_title Japanese Journal of Applied Physics
container_volume 53
creator Schroeder, Uwe
Yurchuk, Ekaterina
Müller, Johannes
Martin, Dominik
Schenk, Tony
Polakowski, Patrick
Adelmann, Christoph
Popovici, Mihaela I.
Kalinin, Sergei V.
Mikolajick, Thomas
description The wake-up behavior of ferroelectric thin film capacitors based on doped hafnium oxide dielectrics in TiN-based metal-insulator-metal structures is reported. After field cycling a remanent polarization up to 40 µC/cm2 and a high coercive field of about 1 MV/cm was observed. Doping of HfO2 by different dopants with a crystal radius ranging from 54 pm (Si) to 132 pm (Sr) was evaluated. In all cases, an improved polarization-voltage hysteresis after wake-up cycling is visible. For smaller dopant atoms like Si and Al stronger pinching of the polarization hysteresis appeared with increasing dopant concentration and proved to be stable during cycling.
doi_str_mv 10.7567/JJAP.53.08LE02
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source IOP Publishing Journals; Institute of Physics (IOP) Journals - HEAL-Link
subjects Cycles
Dopants
Ferroelectric materials
Ferroelectricity
Hafnium oxide
Hysteresis
Polarization
Silicon
Thin films
title Impact of different dopants on the switching properties of ferroelectric hafniumoxide
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