Properties of poly(vinyl chloride) incorporated with a novel soybean oil based secondary plasticizer containing a flame retardant group
ABSTRACT A novel bio‐based plasticizer containing flame retardant groups based on soybean oil (SOPE) was synthesized from epoxidized soybean oil (ESO) and diethyl phosphate through a ring‐opening reaction. PVC blends plasticized with ESO and SOPE were prepared, respectively. Properties including rhe...
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| Veröffentlicht in: | Journal of applied polymer science 2015-07, Vol.132 (25), p.np-n/a |
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| creator | Jia, Puyou Zhang, Meng Liu, Chengguo Hu, Lihong Zhou, Yong-Hong |
| description | ABSTRACT
A novel bio‐based plasticizer containing flame retardant groups based on soybean oil (SOPE) was synthesized from epoxidized soybean oil (ESO) and diethyl phosphate through a ring‐opening reaction. PVC blends plasticized with ESO and SOPE were prepared, respectively. Properties including rheological behavior, thermal stability, flame retardant performance, mechanical properties of PVC plasticized with ESO and SOPE were carefully studied. The results showed that the plasticized PVC blends indicated better compatibility, thermal, and mechanical properties. As a novel bio‐based plasticizer containing flame retardant groups, the TGA data indicated that the thermal degradation temperature of PVC blends plasticized with SOPE could reach to 275.5°C. LOI tests and SEM indicated that the LOI value of PVC blends could increase from 24.2 to 33.6%, the flame retardant performance of SOPE was put into effect by promoting polymer carbonization and forming a consolidated and thick flame retardant coating quickly, which is effective to prohibit the heat flux and air incursion. The enhancement in flame retardancy will expand the application range of PVC materials plasticized with SOPE. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42111. |
| doi_str_mv | 10.1002/app.42111 |
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A novel bio‐based plasticizer containing flame retardant groups based on soybean oil (SOPE) was synthesized from epoxidized soybean oil (ESO) and diethyl phosphate through a ring‐opening reaction. PVC blends plasticized with ESO and SOPE were prepared, respectively. Properties including rheological behavior, thermal stability, flame retardant performance, mechanical properties of PVC plasticized with ESO and SOPE were carefully studied. The results showed that the plasticized PVC blends indicated better compatibility, thermal, and mechanical properties. As a novel bio‐based plasticizer containing flame retardant groups, the TGA data indicated that the thermal degradation temperature of PVC blends plasticized with SOPE could reach to 275.5°C. LOI tests and SEM indicated that the LOI value of PVC blends could increase from 24.2 to 33.6%, the flame retardant performance of SOPE was put into effect by promoting polymer carbonization and forming a consolidated and thick flame retardant coating quickly, which is effective to prohibit the heat flux and air incursion. The enhancement in flame retardancy will expand the application range of PVC materials plasticized with SOPE. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42111.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.42111</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Blackwell Publishing Ltd</publisher><subject>blends ; Chlorides ; flame retardance ; Flame retardants ; Materials science ; Mechanical properties ; Phosphates ; Plasticizers ; poly(vinyl chloride) ; Polymer blends ; Polymers ; Polyvinyl chlorides ; Soya bean oil ; synthesis and processing ; Thermal degradation ; thermogravimetric analysis</subject><ispartof>Journal of applied polymer science, 2015-07, Vol.132 (25), p.np-n/a</ispartof><rights>2015 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4091-a8409f7fe7940bfb5558230cc6f2b9d5ecf87e4e408db911a6293199903ceed43</citedby><cites>FETCH-LOGICAL-c4091-a8409f7fe7940bfb5558230cc6f2b9d5ecf87e4e408db911a6293199903ceed43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.42111$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.42111$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Jia, Puyou</creatorcontrib><creatorcontrib>Zhang, Meng</creatorcontrib><creatorcontrib>Liu, Chengguo</creatorcontrib><creatorcontrib>Hu, Lihong</creatorcontrib><creatorcontrib>Zhou, Yong-Hong</creatorcontrib><title>Properties of poly(vinyl chloride) incorporated with a novel soybean oil based secondary plasticizer containing a flame retardant group</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>ABSTRACT
A novel bio‐based plasticizer containing flame retardant groups based on soybean oil (SOPE) was synthesized from epoxidized soybean oil (ESO) and diethyl phosphate through a ring‐opening reaction. PVC blends plasticized with ESO and SOPE were prepared, respectively. Properties including rheological behavior, thermal stability, flame retardant performance, mechanical properties of PVC plasticized with ESO and SOPE were carefully studied. The results showed that the plasticized PVC blends indicated better compatibility, thermal, and mechanical properties. As a novel bio‐based plasticizer containing flame retardant groups, the TGA data indicated that the thermal degradation temperature of PVC blends plasticized with SOPE could reach to 275.5°C. LOI tests and SEM indicated that the LOI value of PVC blends could increase from 24.2 to 33.6%, the flame retardant performance of SOPE was put into effect by promoting polymer carbonization and forming a consolidated and thick flame retardant coating quickly, which is effective to prohibit the heat flux and air incursion. The enhancement in flame retardancy will expand the application range of PVC materials plasticized with SOPE. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42111.</description><subject>blends</subject><subject>Chlorides</subject><subject>flame retardance</subject><subject>Flame retardants</subject><subject>Materials science</subject><subject>Mechanical properties</subject><subject>Phosphates</subject><subject>Plasticizers</subject><subject>poly(vinyl chloride)</subject><subject>Polymer blends</subject><subject>Polymers</subject><subject>Polyvinyl chlorides</subject><subject>Soya bean oil</subject><subject>synthesis and processing</subject><subject>Thermal degradation</subject><subject>thermogravimetric analysis</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp1kU9LHTEUxYNY8Kld-A0CbnQxmsz_LK1tVZB2KJZ2FzKZG43NS2KSpx2_gF_b2KddFLo6cO_vXA73ILRHyRElpDwW3h_VJaV0Ay0oYV1Rt2W_iRZ5R4uesWYLbcd4SwilDWkX6GkIzkNIGiJ2Cntn5oN7bWeD5Y1xQU9wiLWVLngXRIIJP-h0gwW27h4Mjm4eQVjstMGjiHkdQTo7iTBjb0RMWupHCDjPktBW2-tsVUYsAQdIIkzCJnwd3MrvondKmAjvX3UHff_86er0vLj8enZxenJZyJowWog-i-oUdKwmoxqbpunLikjZqnJkUwNS9R3UUJN-Ghmloi1ZRRljpJIAU13toIP1XR_c3Qpi4ksdJRgjLLhV5LTtm66ru6rL6P4_6K1bBZvTZartaf5mRTJ1uKZkcDEGUNwHvcwP4JTwl0p4roT_qSSzx2v2QRuY_w_yk2F4cxRrh44Jfv91iPCLtzljw398OePDt58fB3L1gZ9XzwRPnrs</recordid><startdate>20150705</startdate><enddate>20150705</enddate><creator>Jia, Puyou</creator><creator>Zhang, Meng</creator><creator>Liu, Chengguo</creator><creator>Hu, Lihong</creator><creator>Zhou, Yong-Hong</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20150705</creationdate><title>Properties of poly(vinyl chloride) incorporated with a novel soybean oil based secondary plasticizer containing a flame retardant group</title><author>Jia, Puyou ; Zhang, Meng ; Liu, Chengguo ; Hu, Lihong ; Zhou, Yong-Hong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4091-a8409f7fe7940bfb5558230cc6f2b9d5ecf87e4e408db911a6293199903ceed43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>blends</topic><topic>Chlorides</topic><topic>flame retardance</topic><topic>Flame retardants</topic><topic>Materials science</topic><topic>Mechanical properties</topic><topic>Phosphates</topic><topic>Plasticizers</topic><topic>poly(vinyl chloride)</topic><topic>Polymer blends</topic><topic>Polymers</topic><topic>Polyvinyl chlorides</topic><topic>Soya bean oil</topic><topic>synthesis and processing</topic><topic>Thermal degradation</topic><topic>thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jia, Puyou</creatorcontrib><creatorcontrib>Zhang, Meng</creatorcontrib><creatorcontrib>Liu, Chengguo</creatorcontrib><creatorcontrib>Hu, Lihong</creatorcontrib><creatorcontrib>Zhou, Yong-Hong</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jia, Puyou</au><au>Zhang, Meng</au><au>Liu, Chengguo</au><au>Hu, Lihong</au><au>Zhou, Yong-Hong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Properties of poly(vinyl chloride) incorporated with a novel soybean oil based secondary plasticizer containing a flame retardant group</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2015-07-05</date><risdate>2015</risdate><volume>132</volume><issue>25</issue><spage>np</spage><epage>n/a</epage><pages>np-n/a</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>ABSTRACT
A novel bio‐based plasticizer containing flame retardant groups based on soybean oil (SOPE) was synthesized from epoxidized soybean oil (ESO) and diethyl phosphate through a ring‐opening reaction. PVC blends plasticized with ESO and SOPE were prepared, respectively. Properties including rheological behavior, thermal stability, flame retardant performance, mechanical properties of PVC plasticized with ESO and SOPE were carefully studied. The results showed that the plasticized PVC blends indicated better compatibility, thermal, and mechanical properties. As a novel bio‐based plasticizer containing flame retardant groups, the TGA data indicated that the thermal degradation temperature of PVC blends plasticized with SOPE could reach to 275.5°C. LOI tests and SEM indicated that the LOI value of PVC blends could increase from 24.2 to 33.6%, the flame retardant performance of SOPE was put into effect by promoting polymer carbonization and forming a consolidated and thick flame retardant coating quickly, which is effective to prohibit the heat flux and air incursion. The enhancement in flame retardancy will expand the application range of PVC materials plasticized with SOPE. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42111.</abstract><cop>Hoboken</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.42111</doi><tpages>9</tpages></addata></record> |
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| subjects | blends Chlorides flame retardance Flame retardants Materials science Mechanical properties Phosphates Plasticizers poly(vinyl chloride) Polymer blends Polymers Polyvinyl chlorides Soya bean oil synthesis and processing Thermal degradation thermogravimetric analysis |
| title | Properties of poly(vinyl chloride) incorporated with a novel soybean oil based secondary plasticizer containing a flame retardant group |
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