Surface modification of MAl2O4:Eu2+,Dy3+ (M=Sr, Ca, Ba) phosphors to enhance water resistance by combustion method

[Display omitted] •A facile combustion method has been developed to modify phosphors.•MAl2B2O7 layer was formed on the surface of aluminate phosphors.•Little influence occurred on the luminescence property.•Water resistance of the phosphors was enhanced greatly. A facile combustion method was introd...

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Veröffentlicht in:Applied surface science 2013-10, Vol.282, p.315-319
Hauptverfasser: Deng, Suqing, Xue, Zhiping, Yang, Qu, Liu, Yingliang, Lei, Bingfu, Xiao, Yong, Zheng, Mingtao
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container_end_page 319
container_issue
container_start_page 315
container_title Applied surface science
container_volume 282
creator Deng, Suqing
Xue, Zhiping
Yang, Qu
Liu, Yingliang
Lei, Bingfu
Xiao, Yong
Zheng, Mingtao
description [Display omitted] •A facile combustion method has been developed to modify phosphors.•MAl2B2O7 layer was formed on the surface of aluminate phosphors.•Little influence occurred on the luminescence property.•Water resistance of the phosphors was enhanced greatly. A facile combustion method was introduced into surface modification of MAl2O4:Eu2+,Dy3+ (M=Sr, Ca, Ba) phosphors to improve their water resistance. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), pH measurements and photoluminescence (PL) spectrophotometry were used to characterize the phosphors before and after modification, respectively. Experimental results showed that compact layer of MAl2B2O7 (M=Sr, Ca, Ba) substance was formed on the surface of aluminate phosphors by direct chemical reaction between aluminate and boracic acid. MAl2B2O7 (M=Sr, Ca, Ba) substance is chemically stable in water and could improve water resistance of aluminate phosphors effectively with little influence of luminescence property. It was considered that the versatility of combustion method for surface modification of aluminate phosphors has been confirmed.
doi_str_mv 10.1016/j.apsusc.2013.05.125
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A facile combustion method was introduced into surface modification of MAl2O4:Eu2+,Dy3+ (M=Sr, Ca, Ba) phosphors to improve their water resistance. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), pH measurements and photoluminescence (PL) spectrophotometry were used to characterize the phosphors before and after modification, respectively. Experimental results showed that compact layer of MAl2B2O7 (M=Sr, Ca, Ba) substance was formed on the surface of aluminate phosphors by direct chemical reaction between aluminate and boracic acid. MAl2B2O7 (M=Sr, Ca, Ba) substance is chemically stable in water and could improve water resistance of aluminate phosphors effectively with little influence of luminescence property. 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A facile combustion method was introduced into surface modification of MAl2O4:Eu2+,Dy3+ (M=Sr, Ca, Ba) phosphors to improve their water resistance. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), pH measurements and photoluminescence (PL) spectrophotometry were used to characterize the phosphors before and after modification, respectively. Experimental results showed that compact layer of MAl2B2O7 (M=Sr, Ca, Ba) substance was formed on the surface of aluminate phosphors by direct chemical reaction between aluminate and boracic acid. MAl2B2O7 (M=Sr, Ca, Ba) substance is chemically stable in water and could improve water resistance of aluminate phosphors effectively with little influence of luminescence property. 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subjects Aluminate phosphors
Aluminates
Combustion
Combustion method
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Luminescence
Phosphors
Physics
Scanning electron microscopy
Water resistance
X-ray diffraction
X-ray photoelectron spectroscopy
X-rays
title Surface modification of MAl2O4:Eu2+,Dy3+ (M=Sr, Ca, Ba) phosphors to enhance water resistance by combustion method
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