Effect of sample pretreatment on the fractionation of arsenic in anoxic soils

Using by sequential extraction procedures to obtain the chemical forms of arsenic in soils can provide useful information for the assessment of arsenic mobility and bioavailability in soils. However, sample pretreatments before the extraction probably have some effects on the fractionation of arseni...

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Veröffentlicht in:Environmental science and pollution research international 2015-06, Vol.22 (11), p.8367-8374
Hauptverfasser: Huang, Guanxing, Chen, Zongyu, Sun, Jichao, Liu, Fan, Wang, Jia, Zhang, Ying
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container_issue 11
container_start_page 8367
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creator Huang, Guanxing
Chen, Zongyu
Sun, Jichao
Liu, Fan
Wang, Jia
Zhang, Ying
description Using by sequential extraction procedures to obtain the chemical forms of arsenic in soils can provide useful information for the assessment of arsenic mobility and bioavailability in soils. However, sample pretreatments before the extraction probably have some effects on the fractionation of arsenic in soils. Impact of sample pretreatments (freeze-drying, oven-drying, air-drying, and the fresh soil) on the fractionation of arsenic in anoxic soils was investigated in this study. The results show that there are some differences for arsenic fractions in soils between by drying pretreatments and by the fresh soil, indicating that the redistribution among arsenic fractions in anoxic soils occurs after drying pretreatments. The redistribution of arsenic fractions in anoxic soils is ascribed to the oxidation of organic matter and sulfides, the crystallization of iron (hydr)oxides, the ageing process, and the diffusion of arsenic into micropores. The freeze-drying is the best drying method to minimize the effect on the fractionation of arsenic in anoxic soils, while air-drying is the worst one. Drying pretreatments are not recommended for the fractionation of arsenic in anoxic soils with high concentration of iron.
doi_str_mv 10.1007/s11356-014-3958-5
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subjects Aquatic Pollution
Arsenic
Arsenic - analysis
Arsenic - chemistry
Arsenic removal
Atmospheric Protection/Air Quality Control/Air Pollution
Bioavailability
Chemical Fractionation
Crystallization
Desiccation - methods
Earth and Environmental Science
Ecotoxicology
Environment
Environmental Chemistry
Environmental Health
Environmental impact
Environmental science
Extraction processes
Fractionation
Freeze drying
Iron - chemistry
Methods
Organic matter
Oxides - chemistry
Research Article
Sediments
Soil contamination
Soil Pollutants - analysis
Soil Pollutants - chemistry
Soils
Studies
Waste Water Technology
Water Management
Water Pollution Control
title Effect of sample pretreatment on the fractionation of arsenic in anoxic soils
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