Synthesis of polysaccharide derivatives bearing bromobenzoate pendants for use as chiral auxiliaries

Cellulose and amylose derivatives bearing bromobenzoate pendants were synthesized as chiral auxiliaries to create optically active biaryl compounds through Suzuki–Miyaura cross-coupling with naphthalen-1-ylboronic acids. The regioselectively substituted polysaccharide derivatives bearing 2-bromobenz...

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