In situ X-ray diffraction studies of Pr sub(2-x) NiO sub(4+ delta ) crystal structure relaxation caused by oxygen loss

Fine powders of Pr sub(2-x)NiO sub(4+ delta ) (PNO) oxides (x = 0 / 0.3) synthesized by Pechini route were uniaxially pressed into pellets and sintered at 1300 [degrees]C under air. Chemical diffusion coefficients (D sub(chem).) and surface exchange constants (k sub(chem).) were estimated by analysi...

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Veröffentlicht in:Solid state ionics 2014-09, Vol.262, p.918-922
Hauptverfasser: Sadykov, V, Okhlupin, Yu, Yeremeev, N, Vinokurov, Z, Shmakov, A, Belyaev, V, Uvarov, N, Mertens, J
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Sprache:eng
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