On the sol-gel fabrication and characterization of undoped and cerium-doped Sr sub(4)Al sub(14)O sub(25 )

An aqueous sol-gel synthesis route has been used for the preparation of undoped and cerium-doped strontium aluminate phase Sr sub(4)Al sub(14)O sub(25 ). This study revealed required conditions for obtaining single phase compound, which are 1300 [degrees]C annealing temperature and addition of 2.5%...

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Veröffentlicht in:Journal of alloys and compounds 2014-11, Vol.614, p.44-48
Hauptverfasser: Misevicius, Martynas, Kilmanas, Martynas, Culunlu, Serdar, Sakirzanovas, Simas, Morkan, Ayse Uztetik, Beganskiene, Aldona, Kareiva, Aivaras
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container_end_page 48
container_issue
container_start_page 44
container_title Journal of alloys and compounds
container_volume 614
creator Misevicius, Martynas
Kilmanas, Martynas
Culunlu, Serdar
Sakirzanovas, Simas
Morkan, Ayse Uztetik
Beganskiene, Aldona
Kareiva, Aivaras
description An aqueous sol-gel synthesis route has been used for the preparation of undoped and cerium-doped strontium aluminate phase Sr sub(4)Al sub(14)O sub(25 ). This study revealed required conditions for obtaining single phase compound, which are 1300 [degrees]C annealing temperature and addition of 2.5% of boric acid as a fluxing agent. The fact that boric acid is involved in the process of formation of strontium aluminate was confirmed by thermogravimetric measurements. A series of cerium-doped samples has been prepared and their excitation and emission spectra has been measured, which showed peaks at 330 nm and 385 nm, respectively.
doi_str_mv 10.1016/j.jallcom.2014.06.037
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subjects Alloys
Aluminates
Annealing
Boric acids
Reagents
Sol gel process
Strontium
Synthesis
title On the sol-gel fabrication and characterization of undoped and cerium-doped Sr sub(4)Al sub(14)O sub(25 )
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