Stearic-capric acid eutectic/activated-attapulgiate composite as form-stable phase change material for thermal energy storage

The aim of this research was to prepare a novel form-stable PCMs (FSPCM) for latent heat thermal energy storage (LHTES) in low temperature, by incorporating eutectic mixture of stearic-capric acid (S-C) into activated-attapulgite (a-ATP) which acted as supporting material in the composite. The a-ATP...

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Veröffentlicht in:Energy conversion and management 2014-05, Vol.81, p.306-311
Hauptverfasser: Song, Shaokun, Dong, Lijie, Chen, Shun, Xie, Haian, Xiong, Chuanxi
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container_title Energy conversion and management
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creator Song, Shaokun
Dong, Lijie
Chen, Shun
Xie, Haian
Xiong, Chuanxi
description The aim of this research was to prepare a novel form-stable PCMs (FSPCM) for latent heat thermal energy storage (LHTES) in low temperature, by incorporating eutectic mixture of stearic-capric acid (S-C) into activated-attapulgite (a-ATP) which acted as supporting material in the composite. The a-ATP is open-ended tubular capillary with large specific surface area, which is beneficial for the adsorption of PCMs. The maximum mass fraction of stearic-capric binary fatty acid loaded in a-ATP is determined as high as 50 wt% without melted S-C seepage from the composite. The phase change temperatures and latent heats of FSPCM are measured to be 21.8 [degrees]C and 72.6 J/g for melting process, and 20.3 [degrees]C and 71.9 J/g for freezing process, respectively, indicating it has suitable phase change temperature and high latent heat storage capacity. Moreover, the S-C/a-ATP FSPCM shows good thermal and chemical reliability after 1000 times thermal cycling test, which is identified by differential scanning calorimetry (DSC) and Fourier transformation infrared (FTIR). Therefore, the S-C/a-ATP FSPCM is an effective LHTES building material to reduce energy consumption.
doi_str_mv 10.1016/j.enconman.2014.02.045
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The a-ATP is open-ended tubular capillary with large specific surface area, which is beneficial for the adsorption of PCMs. The maximum mass fraction of stearic-capric binary fatty acid loaded in a-ATP is determined as high as 50 wt% without melted S-C seepage from the composite. The phase change temperatures and latent heats of FSPCM are measured to be 21.8 [degrees]C and 72.6 J/g for melting process, and 20.3 [degrees]C and 71.9 J/g for freezing process, respectively, indicating it has suitable phase change temperature and high latent heat storage capacity. Moreover, the S-C/a-ATP FSPCM shows good thermal and chemical reliability after 1000 times thermal cycling test, which is identified by differential scanning calorimetry (DSC) and Fourier transformation infrared (FTIR). 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The a-ATP is open-ended tubular capillary with large specific surface area, which is beneficial for the adsorption of PCMs. The maximum mass fraction of stearic-capric binary fatty acid loaded in a-ATP is determined as high as 50 wt% without melted S-C seepage from the composite. The phase change temperatures and latent heats of FSPCM are measured to be 21.8 [degrees]C and 72.6 J/g for melting process, and 20.3 [degrees]C and 71.9 J/g for freezing process, respectively, indicating it has suitable phase change temperature and high latent heat storage capacity. Moreover, the S-C/a-ATP FSPCM shows good thermal and chemical reliability after 1000 times thermal cycling test, which is identified by differential scanning calorimetry (DSC) and Fourier transformation infrared (FTIR). 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subjects Applied sciences
Differential scanning calorimetry
Energy
Energy. Thermal use of fuels
Eutectic composition
Eutectic temperature
Exact sciences and technology
Fatty acids
Latent heat
Phase change
Specific surface
Thermal energy
Transport and storage of energy
title Stearic-capric acid eutectic/activated-attapulgiate composite as form-stable phase change material for thermal energy storage
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