Synthesis of the diazonium (perfluoroalkyl) benzenesulfonimide monomer from Nafion monomer for proton exchange membrane fuel cells
One diazonium (perfluoroalkyl) benzenesulfonimide monomer, perfluoro-3, 6-dioxa-4-methyl-7-octene benzenesulfonyl imide, has been synthesized from Nafion monomer for the first time. With trifluorovinyl ether and diazonium precursors, the partially-fluorinated diazonium PFSI monomer can be polymerize...
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| Veröffentlicht in: | Journal of power sources 2014, Vol.248, p.1177-1180 |
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| container_title | Journal of power sources |
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| creator | HUA MEI D'ANDREA, Dan NGUYEN, Tuyet-Trinh NWORIE, Chima |
| description | One diazonium (perfluoroalkyl) benzenesulfonimide monomer, perfluoro-3, 6-dioxa-4-methyl-7-octene benzenesulfonyl imide, has been synthesized from Nafion monomer for the first time. With trifluorovinyl ether and diazonium precursors, the partially-fluorinated diazonium PFSI monomer can be polymerized and will provide chemically bonding with carbon electrode in proton exchange membrane fuel cells. A systematic study of the synthesis and characterization of this diazonium PFSI monomer has been conducted by varying reaction conditions. The optimized synthesis method has been established in the lab. |
| doi_str_mv | 10.1016/j.jpowsour.2013.10.024 |
| format | Article |
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With trifluorovinyl ether and diazonium precursors, the partially-fluorinated diazonium PFSI monomer can be polymerized and will provide chemically bonding with carbon electrode in proton exchange membrane fuel cells. A systematic study of the synthesis and characterization of this diazonium PFSI monomer has been conducted by varying reaction conditions. The optimized synthesis method has been established in the lab.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2013.10.024</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier</publisher><subject>Applied sciences ; Carbon ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrodes ; Energy ; Energy. 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With trifluorovinyl ether and diazonium precursors, the partially-fluorinated diazonium PFSI monomer can be polymerized and will provide chemically bonding with carbon electrode in proton exchange membrane fuel cells. A systematic study of the synthesis and characterization of this diazonium PFSI monomer has been conducted by varying reaction conditions. The optimized synthesis method has been established in the lab.</description><subject>Applied sciences</subject><subject>Carbon</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrodes</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</subject><subject>Exact sciences and technology</subject><subject>Fuel cells</subject><subject>Membranes</subject><subject>Monomers</subject><subject>Perfluoroalkyls</subject><subject>Synthesis</subject><subject>Trifluorovinyl ether</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqNkT1PwzAURS0EEqXwF5AXpDKk-PkjdkdU8SUhGIA5chKbpjhxsRtBGfnluGqBESZbR-fZV-8idAxkDATys_l4vvBv0fdhTAmwBMeE8h00ACVZRqUQu2hAmFSZlILto4MY54QQAEkG6PNh1S1nJjYRe4vTDdeN_vBd07d4tDDBut4Hr93Lyp3i0nQfpjOxdzYZbVMb3PrOtyZgG3yL77RtfPfLfMCL4JcJmfdqprvn5Ju2DLoz2PbG4co4Fw_RntUumqPtOURPlxeP0-vs9v7qZnp-m1WcwjLThJS1hgoUg5yzSS244lDTnEvGpVSq5rmlJVV5VRoG1koha1BArBA6UTZEo827KdNrb-KyaJu4TpDi-D4WkEuV9iJy8bcqBBA2UVL9Q2WpJTGRNKn5Rq2CjzEYWyxC0-qwKoAU6yqLefFdZbGucs1TlWnwZPuHjpV2Ni2wauLPNFVUAJ9Q9gUGPqNq</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>HUA MEI</creator><creator>D'ANDREA, Dan</creator><creator>NGUYEN, Tuyet-Trinh</creator><creator>NWORIE, Chima</creator><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>KR7</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-3892-1927</orcidid></search><sort><creationdate>2014</creationdate><title>Synthesis of the diazonium (perfluoroalkyl) benzenesulfonimide monomer from Nafion monomer for proton exchange membrane fuel cells</title><author>HUA MEI ; D'ANDREA, Dan ; NGUYEN, Tuyet-Trinh ; NWORIE, Chima</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c421t-a00bda1c18316439d54841d2647347788d46f2b286cbe31ff757d1810f55a2863</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Applied sciences</topic><topic>Carbon</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrodes</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</topic><topic>Exact sciences and technology</topic><topic>Fuel cells</topic><topic>Membranes</topic><topic>Monomers</topic><topic>Perfluoroalkyls</topic><topic>Synthesis</topic><topic>Trifluorovinyl ether</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>HUA MEI</creatorcontrib><creatorcontrib>D'ANDREA, Dan</creatorcontrib><creatorcontrib>NGUYEN, Tuyet-Trinh</creatorcontrib><creatorcontrib>NWORIE, Chima</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>HUA MEI</au><au>D'ANDREA, Dan</au><au>NGUYEN, Tuyet-Trinh</au><au>NWORIE, Chima</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of the diazonium (perfluoroalkyl) benzenesulfonimide monomer from Nafion monomer for proton exchange membrane fuel cells</atitle><jtitle>Journal of power sources</jtitle><date>2014</date><risdate>2014</risdate><volume>248</volume><spage>1177</spage><epage>1180</epage><pages>1177-1180</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>One diazonium (perfluoroalkyl) benzenesulfonimide monomer, perfluoro-3, 6-dioxa-4-methyl-7-octene benzenesulfonyl imide, has been synthesized from Nafion monomer for the first time. With trifluorovinyl ether and diazonium precursors, the partially-fluorinated diazonium PFSI monomer can be polymerized and will provide chemically bonding with carbon electrode in proton exchange membrane fuel cells. A systematic study of the synthesis and characterization of this diazonium PFSI monomer has been conducted by varying reaction conditions. The optimized synthesis method has been established in the lab.</abstract><cop>Amsterdam</cop><pub>Elsevier</pub><doi>10.1016/j.jpowsour.2013.10.024</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-3892-1927</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0378-7753 |
| ispartof | Journal of power sources, 2014, Vol.248, p.1177-1180 |
| issn | 0378-7753 1873-2755 |
| language | eng |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Applied sciences Carbon Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrodes Energy Energy. Thermal use of fuels Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc Exact sciences and technology Fuel cells Membranes Monomers Perfluoroalkyls Synthesis Trifluorovinyl ether |
| title | Synthesis of the diazonium (perfluoroalkyl) benzenesulfonimide monomer from Nafion monomer for proton exchange membrane fuel cells |
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