Electrochemical characteristics of iron oxide nanowires during lithium-promoted conversion reaction
Iron oxide nanowires are synthesized and characterized as negative electrode for lithium ion battery. The lithium-conversion reaction of the material is studied by electrochemical techniques as well as by XRD and SEM. Lithium cells based on the electrode material evidence a reversible capacity of ab...
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| Veröffentlicht in: | Journal of power sources 2014-06, Vol.256, p.133-136 |
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| container_title | Journal of power sources |
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| creator | Hong, Inchul Angelucci, Marco Verrelli, Roberta Betti, Maria Grazia Panero, Stefania Croce, Fausto Mariani, Carlo Scrosati, Bruno Hassoun, Jusef |
| description | Iron oxide nanowires are synthesized and characterized as negative electrode for lithium ion battery. The lithium-conversion reaction of the material is studied by electrochemical techniques as well as by XRD and SEM. Lithium cells based on the electrode material evidence a reversible capacity of about 800 mAh g−1 and a multiple-step electrochemical process leading to the formation of amorphous compound. Furthermore, SEM analysis of the compound formed by direct lithium atoms deposition on the iron oxide nanowires clearly evidences the change of the electrode morphology upon formation of a lithiated phase. We believe that the data here reported may shed light on the properties of the iron oxide nanowires as high capacity anode for lithium ion battery.
•Iron oxide nanowires are characterizated as anode material for lithium-ion battery.•The anode has specific capacity of 800 mAh g−1 evolving at 0.9 V vs. Li.•Morphological and structural variation during lithium-conversion process is studied.•The material has low cost and environment compatibility. |
| doi_str_mv | 10.1016/j.jpowsour.2014.01.052 |
| format | Article |
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•Iron oxide nanowires are characterizated as anode material for lithium-ion battery.•The anode has specific capacity of 800 mAh g−1 evolving at 0.9 V vs. Li.•Morphological and structural variation during lithium-conversion process is studied.•The material has low cost and environment compatibility.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2014.01.052</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Amorphous materials ; Anode ; Applied sciences ; Conversion ; Deposition ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrodes ; Exact sciences and technology ; Iron oxides ; Iron-oxide ; Lithium batteries ; Lithium-ion-battery ; Materials ; Nanowires ; Scanning electron microscopy</subject><ispartof>Journal of power sources, 2014-06, Vol.256, p.133-136</ispartof><rights>2014 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c449t-1899d3622b1de109d4ed6f01f0935fb94db2dd2cec6077ff5aa6470a6536348c3</citedby><cites>FETCH-LOGICAL-c449t-1899d3622b1de109d4ed6f01f0935fb94db2dd2cec6077ff5aa6470a6536348c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0378775314000755$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28250657$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Hong, Inchul</creatorcontrib><creatorcontrib>Angelucci, Marco</creatorcontrib><creatorcontrib>Verrelli, Roberta</creatorcontrib><creatorcontrib>Betti, Maria Grazia</creatorcontrib><creatorcontrib>Panero, Stefania</creatorcontrib><creatorcontrib>Croce, Fausto</creatorcontrib><creatorcontrib>Mariani, Carlo</creatorcontrib><creatorcontrib>Scrosati, Bruno</creatorcontrib><creatorcontrib>Hassoun, Jusef</creatorcontrib><title>Electrochemical characteristics of iron oxide nanowires during lithium-promoted conversion reaction</title><title>Journal of power sources</title><description>Iron oxide nanowires are synthesized and characterized as negative electrode for lithium ion battery. The lithium-conversion reaction of the material is studied by electrochemical techniques as well as by XRD and SEM. Lithium cells based on the electrode material evidence a reversible capacity of about 800 mAh g−1 and a multiple-step electrochemical process leading to the formation of amorphous compound. Furthermore, SEM analysis of the compound formed by direct lithium atoms deposition on the iron oxide nanowires clearly evidences the change of the electrode morphology upon formation of a lithiated phase. We believe that the data here reported may shed light on the properties of the iron oxide nanowires as high capacity anode for lithium ion battery.
•Iron oxide nanowires are characterizated as anode material for lithium-ion battery.•The anode has specific capacity of 800 mAh g−1 evolving at 0.9 V vs. Li.•Morphological and structural variation during lithium-conversion process is studied.•The material has low cost and environment compatibility.</description><subject>Amorphous materials</subject><subject>Anode</subject><subject>Applied sciences</subject><subject>Conversion</subject><subject>Deposition</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrodes</subject><subject>Exact sciences and technology</subject><subject>Iron oxides</subject><subject>Iron-oxide</subject><subject>Lithium batteries</subject><subject>Lithium-ion-battery</subject><subject>Materials</subject><subject>Nanowires</subject><subject>Scanning electron microscopy</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFkUFv1DAQhS0EEkvhL6BckLgkjJ3Yjm-gqgWkSlzgbHnHY9arJF7spIV_j1dbuPY0c_jem9F7jL3l0HHg6sOxO57SQ0lb7gTwoQPegRTP2I6Pum-FlvI520Gvx1Zr2b9kr0o5AgDnGnYMbybCNSc80BzRTQ0eXHa4Uo5ljViaFJqY09Kk39FTs7glPcRMpfFbjsvPZorrIW5ze8ppTiv5BtNyT7nEKslUjerymr0Ibir05nFesR-3N9-vv7R33z5_vf501-IwmLXlozG-V0LsuScOxg_kVQAewPQy7M3g98J7gYQKtA5BOqcGDU7JXvXDiP0Ve3_xrc_82qisdo4FaZrcQmkrliutzThKo55GZaWG0egzqi4o5lRKpmBPOc4u_7Ec7LkAe7T_CrDnAixwWwuownePN1ypyYbsFozlv1qMQoKSunIfLxzVbO4jZVsw0oLka9C4Wp_iU6f-AsGRohw</recordid><startdate>20140615</startdate><enddate>20140615</enddate><creator>Hong, Inchul</creator><creator>Angelucci, Marco</creator><creator>Verrelli, Roberta</creator><creator>Betti, Maria Grazia</creator><creator>Panero, Stefania</creator><creator>Croce, Fausto</creator><creator>Mariani, Carlo</creator><creator>Scrosati, Bruno</creator><creator>Hassoun, Jusef</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20140615</creationdate><title>Electrochemical characteristics of iron oxide nanowires during lithium-promoted conversion reaction</title><author>Hong, Inchul ; Angelucci, Marco ; Verrelli, Roberta ; Betti, Maria Grazia ; Panero, Stefania ; Croce, Fausto ; Mariani, Carlo ; Scrosati, Bruno ; Hassoun, Jusef</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c449t-1899d3622b1de109d4ed6f01f0935fb94db2dd2cec6077ff5aa6470a6536348c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Amorphous materials</topic><topic>Anode</topic><topic>Applied sciences</topic><topic>Conversion</topic><topic>Deposition</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrodes</topic><topic>Exact sciences and technology</topic><topic>Iron oxides</topic><topic>Iron-oxide</topic><topic>Lithium batteries</topic><topic>Lithium-ion-battery</topic><topic>Materials</topic><topic>Nanowires</topic><topic>Scanning electron microscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hong, Inchul</creatorcontrib><creatorcontrib>Angelucci, Marco</creatorcontrib><creatorcontrib>Verrelli, Roberta</creatorcontrib><creatorcontrib>Betti, Maria Grazia</creatorcontrib><creatorcontrib>Panero, Stefania</creatorcontrib><creatorcontrib>Croce, Fausto</creatorcontrib><creatorcontrib>Mariani, Carlo</creatorcontrib><creatorcontrib>Scrosati, Bruno</creatorcontrib><creatorcontrib>Hassoun, Jusef</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hong, Inchul</au><au>Angelucci, Marco</au><au>Verrelli, Roberta</au><au>Betti, Maria Grazia</au><au>Panero, Stefania</au><au>Croce, Fausto</au><au>Mariani, Carlo</au><au>Scrosati, Bruno</au><au>Hassoun, Jusef</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical characteristics of iron oxide nanowires during lithium-promoted conversion reaction</atitle><jtitle>Journal of power sources</jtitle><date>2014-06-15</date><risdate>2014</risdate><volume>256</volume><spage>133</spage><epage>136</epage><pages>133-136</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>Iron oxide nanowires are synthesized and characterized as negative electrode for lithium ion battery. The lithium-conversion reaction of the material is studied by electrochemical techniques as well as by XRD and SEM. Lithium cells based on the electrode material evidence a reversible capacity of about 800 mAh g−1 and a multiple-step electrochemical process leading to the formation of amorphous compound. Furthermore, SEM analysis of the compound formed by direct lithium atoms deposition on the iron oxide nanowires clearly evidences the change of the electrode morphology upon formation of a lithiated phase. We believe that the data here reported may shed light on the properties of the iron oxide nanowires as high capacity anode for lithium ion battery.
•Iron oxide nanowires are characterizated as anode material for lithium-ion battery.•The anode has specific capacity of 800 mAh g−1 evolving at 0.9 V vs. Li.•Morphological and structural variation during lithium-conversion process is studied.•The material has low cost and environment compatibility.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2014.01.052</doi><tpages>4</tpages></addata></record> |
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| subjects | Amorphous materials Anode Applied sciences Conversion Deposition Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrodes Exact sciences and technology Iron oxides Iron-oxide Lithium batteries Lithium-ion-battery Materials Nanowires Scanning electron microscopy |
| title | Electrochemical characteristics of iron oxide nanowires during lithium-promoted conversion reaction |
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