Preparation of titanium carbide nanowires for application in electromagnetic wave absorption

The TiC nanowires with high specific surface areas were prepared by a chloride-assisted carbothermal reduction. The 30wt% loaded sample shows strong EM wave absorption capability in X-band, due to the good impedance match degree and destructive interference at the air–material interface. TiC nanowir...

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Veröffentlicht in:Journal of alloys and compounds 2014-05, Vol.596, p.132-139
Hauptverfasser: Yuan, Xiaoyan, Cheng, Laifei, Kong, Luo, Yin, Xiaowei, Zhang, Litong
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container_end_page 139
container_issue
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container_title Journal of alloys and compounds
container_volume 596
creator Yuan, Xiaoyan
Cheng, Laifei
Kong, Luo
Yin, Xiaowei
Zhang, Litong
description The TiC nanowires with high specific surface areas were prepared by a chloride-assisted carbothermal reduction. The 30wt% loaded sample shows strong EM wave absorption capability in X-band, due to the good impedance match degree and destructive interference at the air–material interface. TiC nanowires show a potential as a new-type of stealth materials. •TiC nanowires with high surface areas were prepared by a carbothermal reduction.•The TiC nanowire/paraffin sample had good electromagnetic loss abilities in X-band.•The matching thickness was determined by the quarter-wavelength law and impedance match. TiC nanowires were synthesized by chloride-assisted carbothermal reaction, using sucrose, TiO2 and NaCl as precursors and Ni(NO3)2·6H2O as a catalyst. The TiC nanowires have specific surface areas of 186.7m2g−1 with a diameter of 200–400nm and length of dozens micrometers. The hybrids of TiC nanowires/paraffin exhibited distinct electromagnetic wave absorbing ability in X-band (8.2–12.4GHz). The optimal reflection loss (RL) of −51dB at 11.8GHz and the bandwidth of 3.0GHz (RL
doi_str_mv 10.1016/j.jallcom.2014.01.022
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The 30wt% loaded sample shows strong EM wave absorption capability in X-band, due to the good impedance match degree and destructive interference at the air–material interface. TiC nanowires show a potential as a new-type of stealth materials. •TiC nanowires with high surface areas were prepared by a carbothermal reduction.•The TiC nanowire/paraffin sample had good electromagnetic loss abilities in X-band.•The matching thickness was determined by the quarter-wavelength law and impedance match. TiC nanowires were synthesized by chloride-assisted carbothermal reaction, using sucrose, TiO2 and NaCl as precursors and Ni(NO3)2·6H2O as a catalyst. The TiC nanowires have specific surface areas of 186.7m2g−1 with a diameter of 200–400nm and length of dozens micrometers. The hybrids of TiC nanowires/paraffin exhibited distinct electromagnetic wave absorbing ability in X-band (8.2–12.4GHz). The optimal reflection loss (RL) of −51dB at 11.8GHz and the bandwidth of 3.0GHz (RL&lt;−10dB) was achieved when the thickness is 1.7mm. 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The optimal reflection loss (RL) of −51dB at 11.8GHz and the bandwidth of 3.0GHz (RL&lt;−10dB) was achieved when the thickness is 1.7mm. 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The optimal reflection loss (RL) of −51dB at 11.8GHz and the bandwidth of 3.0GHz (RL&lt;−10dB) was achieved when the thickness is 1.7mm. The optimal reflection loss and matching thickness were determined by the impedance match and quarter-wavelength law.</abstract><cop>Kidlington</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2014.01.022</doi><tpages>8</tpages></addata></record>
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subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Electromagnetic wave absorption
Electromagnetic waves
Exact sciences and technology
Microstructure
Microwave and radio-frequency interactions (excluding resonances)
Nanowires
Noise levels
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optimization
Other interactions of matter with particles and radiation
Physics
Reflection
Specific surface
TiC nanowires
Titanium carbide
Titanium dioxide
title Preparation of titanium carbide nanowires for application in electromagnetic wave absorption
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