Highly Filled Polystyrene/Laponite Hybrid Nanoparticles Prepared Using the Ad-miniemulsion Polymerisation Technique
The preparation of highly filled polystyrene/Laponite (PS/Lap) hybrid nanoparticles by the ad‐miniemulsion polymerisation technique, using conventional free‐radical polymerisation, is described. Laponite (Lap) is first modified with a polymerisable cationic surfactant. Then, using a second surfactan...
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| Veröffentlicht in: | Macromolecular chemistry and physics 2013-01, Vol.214 (1), p.62-75 |
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| creator | Zengeni, Eddson Hartmann, Patrice C. Pasch, Harald |
| description | The preparation of highly filled polystyrene/Laponite (PS/Lap) hybrid nanoparticles by the ad‐miniemulsion polymerisation technique, using conventional free‐radical polymerisation, is described. Laponite (Lap) is first modified with a polymerisable cationic surfactant. Then, using a second surfactant dispersions are prepared under sonication. A stable hybrid miniemulsion is obtained after mixing and co‐sonicating both miniemulsions. The polymerisation is conducted using an oil‐soluble initiator to obtain hybrid nanoparticles. PS/Lap hybrid nanoparticles are effectively prepared with clay contents as high as 50 wt%. TEM reveals that the highly filled hybrid latexes (≥30 wt%) exhibit encapsulated morphology with homogeneously distributed clay platelets.
The use of the ad‐miniemulsion polymerisation technique to prepare highly filled polystyrene/Laponite hybrid latexes with up to 50 wt% clay content is described. The latex and film morphology of these hybrids latexes have been examined. The extent of clay exfoliation and physical properties of the nanocomposites has been evaluated in relation to clay content. |
| doi_str_mv | 10.1002/macp.201200330 |
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The use of the ad‐miniemulsion polymerisation technique to prepare highly filled polystyrene/Laponite hybrid latexes with up to 50 wt% clay content is described. The latex and film morphology of these hybrids latexes have been examined. The extent of clay exfoliation and physical properties of the nanocomposites has been evaluated in relation to clay content.</description><identifier>ISSN: 1022-1352</identifier><identifier>EISSN: 1521-3935</identifier><identifier>DOI: 10.1002/macp.201200330</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>ad-miniemulsion polymerisation ; Applied sciences ; Clay (material) ; clay encapsulation ; Composites ; Exact sciences and technology ; Forms of application and semi-finished materials ; highly filled nanocomposites ; hybrid nanoparticles ; Latex ; Morphology ; Nanocomposites ; Nanoparticles ; Polymer industry, paints, wood ; Polymerization ; Polystyrene resins ; Surfactants ; Technology of polymers ; water-based latexes</subject><ispartof>Macromolecular chemistry and physics, 2013-01, Vol.214 (1), p.62-75</ispartof><rights>Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3900-5b67135cd0e7c164c284b5860000314180c5f4d31371acca2058f518107af2f63</citedby><cites>FETCH-LOGICAL-c3900-5b67135cd0e7c164c284b5860000314180c5f4d31371acca2058f518107af2f63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmacp.201200330$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmacp.201200330$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26780447$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Zengeni, Eddson</creatorcontrib><creatorcontrib>Hartmann, Patrice C.</creatorcontrib><creatorcontrib>Pasch, Harald</creatorcontrib><title>Highly Filled Polystyrene/Laponite Hybrid Nanoparticles Prepared Using the Ad-miniemulsion Polymerisation Technique</title><title>Macromolecular chemistry and physics</title><addtitle>Macromol. Chem. Phys</addtitle><description>The preparation of highly filled polystyrene/Laponite (PS/Lap) hybrid nanoparticles by the ad‐miniemulsion polymerisation technique, using conventional free‐radical polymerisation, is described. Laponite (Lap) is first modified with a polymerisable cationic surfactant. Then, using a second surfactant dispersions are prepared under sonication. A stable hybrid miniemulsion is obtained after mixing and co‐sonicating both miniemulsions. The polymerisation is conducted using an oil‐soluble initiator to obtain hybrid nanoparticles. PS/Lap hybrid nanoparticles are effectively prepared with clay contents as high as 50 wt%. TEM reveals that the highly filled hybrid latexes (≥30 wt%) exhibit encapsulated morphology with homogeneously distributed clay platelets.
The use of the ad‐miniemulsion polymerisation technique to prepare highly filled polystyrene/Laponite hybrid latexes with up to 50 wt% clay content is described. The latex and film morphology of these hybrids latexes have been examined. The extent of clay exfoliation and physical properties of the nanocomposites has been evaluated in relation to clay content.</description><subject>ad-miniemulsion polymerisation</subject><subject>Applied sciences</subject><subject>Clay (material)</subject><subject>clay encapsulation</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>highly filled nanocomposites</subject><subject>hybrid nanoparticles</subject><subject>Latex</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Polymer industry, paints, wood</subject><subject>Polymerization</subject><subject>Polystyrene resins</subject><subject>Surfactants</subject><subject>Technology of polymers</subject><subject>water-based latexes</subject><issn>1022-1352</issn><issn>1521-3935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkDFv2zAQhYWgBZqmWTtrKdBFzpEUSWk03Dou4KQGksAjQVOnmClFqaSMVv--dB0Y3TrdHfC-dw8vyz4SmBEAetNpM8woEArAGFxkl4RTUrCa8TdpB0oLwjh9l72P8QUAKqjlZRZX9nnvpnxpncMm3_RuiuMU0OPNWg-9tyPmq2kXbJPfa98POozWOIz5JmA6EvIUrX_Oxz3m86borLfYHVy0vf9r1mGwUY_H8xHN3tufB_yQvW21i3j9Oq-yp-XXx8WqWH-__baYrwvDaoCC74RMiU0DKA0RpaFVueOVSNmBkZJUYHhbNowwSbQxmgKvWk4qAlK3tBXsKvt88h1Cn97GUXU2GnROe-wPUREhZS1EKSFJZyepCX2MAVs1BNvpMCkC6tiuOrarzu0m4NOrt45GuzZob2w8U1TICspSJl190v2yDqf_uKq7-WLz74_ixNo44u8zq8MPJSSTXG3vb9Vmu334Ui3v1Jb9AW9Sm1U</recordid><startdate>20130111</startdate><enddate>20130111</enddate><creator>Zengeni, Eddson</creator><creator>Hartmann, Patrice C.</creator><creator>Pasch, Harald</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20130111</creationdate><title>Highly Filled Polystyrene/Laponite Hybrid Nanoparticles Prepared Using the Ad-miniemulsion Polymerisation Technique</title><author>Zengeni, Eddson ; Hartmann, Patrice C. ; Pasch, Harald</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3900-5b67135cd0e7c164c284b5860000314180c5f4d31371acca2058f518107af2f63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>ad-miniemulsion polymerisation</topic><topic>Applied sciences</topic><topic>Clay (material)</topic><topic>clay encapsulation</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>highly filled nanocomposites</topic><topic>hybrid nanoparticles</topic><topic>Latex</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Polymer industry, paints, wood</topic><topic>Polymerization</topic><topic>Polystyrene resins</topic><topic>Surfactants</topic><topic>Technology of polymers</topic><topic>water-based latexes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zengeni, Eddson</creatorcontrib><creatorcontrib>Hartmann, Patrice C.</creatorcontrib><creatorcontrib>Pasch, Harald</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Macromolecular chemistry and physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zengeni, Eddson</au><au>Hartmann, Patrice C.</au><au>Pasch, Harald</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly Filled Polystyrene/Laponite Hybrid Nanoparticles Prepared Using the Ad-miniemulsion Polymerisation Technique</atitle><jtitle>Macromolecular chemistry and physics</jtitle><addtitle>Macromol. Chem. Phys</addtitle><date>2013-01-11</date><risdate>2013</risdate><volume>214</volume><issue>1</issue><spage>62</spage><epage>75</epage><pages>62-75</pages><issn>1022-1352</issn><eissn>1521-3935</eissn><abstract>The preparation of highly filled polystyrene/Laponite (PS/Lap) hybrid nanoparticles by the ad‐miniemulsion polymerisation technique, using conventional free‐radical polymerisation, is described. Laponite (Lap) is first modified with a polymerisable cationic surfactant. Then, using a second surfactant dispersions are prepared under sonication. A stable hybrid miniemulsion is obtained after mixing and co‐sonicating both miniemulsions. The polymerisation is conducted using an oil‐soluble initiator to obtain hybrid nanoparticles. PS/Lap hybrid nanoparticles are effectively prepared with clay contents as high as 50 wt%. TEM reveals that the highly filled hybrid latexes (≥30 wt%) exhibit encapsulated morphology with homogeneously distributed clay platelets.
The use of the ad‐miniemulsion polymerisation technique to prepare highly filled polystyrene/Laponite hybrid latexes with up to 50 wt% clay content is described. The latex and film morphology of these hybrids latexes have been examined. The extent of clay exfoliation and physical properties of the nanocomposites has been evaluated in relation to clay content.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/macp.201200330</doi><tpages>14</tpages></addata></record> |
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| subjects | ad-miniemulsion polymerisation Applied sciences Clay (material) clay encapsulation Composites Exact sciences and technology Forms of application and semi-finished materials highly filled nanocomposites hybrid nanoparticles Latex Morphology Nanocomposites Nanoparticles Polymer industry, paints, wood Polymerization Polystyrene resins Surfactants Technology of polymers water-based latexes |
| title | Highly Filled Polystyrene/Laponite Hybrid Nanoparticles Prepared Using the Ad-miniemulsion Polymerisation Technique |
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