Engineered hydrochar composites for phosphorus removal/recovery: Lanthanum doped hydrochar prepared by hydrothermal carbonization of lanthanum pretreated rice straw
•Lanthanum doped hydrochar was prepared by one-pot hydrothermal carbonization.•The adsorbents was highly effective in P adsorption in a wide range of pH.•The competing anions showed little negative effects on P adsorption on the adsorbent. Engineered hydrochar composites (EHC) were synthesized by hy...
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Veröffentlicht in: | Bioresource technology 2014-06, Vol.161, p.327-332 |
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creator | Dai, Lichun Wu, Bo Tan, Furong He, Mingxiong Wang, Wenguo Qin, Han Tang, Xiaoyu Zhu, Qili Pan, Ke Hu, Qichun |
description | •Lanthanum doped hydrochar was prepared by one-pot hydrothermal carbonization.•The adsorbents was highly effective in P adsorption in a wide range of pH.•The competing anions showed little negative effects on P adsorption on the adsorbent.
Engineered hydrochar composites (EHC) were synthesized by hydrothermal carbonization (HTC) of lanthanum pretreated rice straw. The as-prepared composite with about 30% lanthanum content showed greater P removal potential than La(OH)3, indicating the synergistic effect of hydrochar and lanthanum in P removal. The adsorption results showed that EHC showed great P adsorption capacities (>50mgPg−1) in the pH range of 2.5–10.5, and the presence of competing anions had little negative effects on P adsorption on EHC. The equilibrium time for P adsorption on EHC was considerably reduced under acid condition (12h) compared to alkaline condition (48h). The maximum adsorption capacity was 61.57mgPg−1 according to Langmuir isotherms. These results suggested that EHC was highly effective in P adsorption in a wide range of pH and the presence of competing anions, thus EHC could be a promising adsorbent for phosphorus removal/recovery from wastewater. |
doi_str_mv | 10.1016/j.biortech.2014.03.086 |
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Engineered hydrochar composites (EHC) were synthesized by hydrothermal carbonization (HTC) of lanthanum pretreated rice straw. The as-prepared composite with about 30% lanthanum content showed greater P removal potential than La(OH)3, indicating the synergistic effect of hydrochar and lanthanum in P removal. The adsorption results showed that EHC showed great P adsorption capacities (>50mgPg−1) in the pH range of 2.5–10.5, and the presence of competing anions had little negative effects on P adsorption on EHC. The equilibrium time for P adsorption on EHC was considerably reduced under acid condition (12h) compared to alkaline condition (48h). The maximum adsorption capacity was 61.57mgPg−1 according to Langmuir isotherms. These results suggested that EHC was highly effective in P adsorption in a wide range of pH and the presence of competing anions, thus EHC could be a promising adsorbent for phosphorus removal/recovery from wastewater.</description><identifier>ISSN: 0960-8524</identifier><identifier>EISSN: 1873-2976</identifier><identifier>DOI: 10.1016/j.biortech.2014.03.086</identifier><identifier>PMID: 24727355</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Adsorption ; Anions ; Biological and medical sciences ; Carbonization ; Charcoal - chemistry ; Food industries ; Fundamental and applied biological sciences. Psychology ; Hydrochar composite ; Hydrothermal carbonization ; Kinetics ; Lanthanum ; Lanthanum - chemistry ; Microscopy, Electron, Scanning ; Oryza - chemistry ; Oryza sativa ; Phosphorus - isolation & purification ; Phosphorus recovery ; Phosphorus removal ; Rice ; Spectroscopy, Fourier Transform Infrared ; Straw ; Thermodynamics ; Use and upgrading of agricultural and food by-products. Biotechnology ; Waste water ; X-Ray Diffraction</subject><ispartof>Bioresource technology, 2014-06, Vol.161, p.327-332</ispartof><rights>2014 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2014 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c464t-72405734a627dd13cce5d72794555f343a88891037b69846159412cdc5a255703</citedby><cites>FETCH-LOGICAL-c464t-72405734a627dd13cce5d72794555f343a88891037b69846159412cdc5a255703</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0960852414003915$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28472026$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24727355$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dai, Lichun</creatorcontrib><creatorcontrib>Wu, Bo</creatorcontrib><creatorcontrib>Tan, Furong</creatorcontrib><creatorcontrib>He, Mingxiong</creatorcontrib><creatorcontrib>Wang, Wenguo</creatorcontrib><creatorcontrib>Qin, Han</creatorcontrib><creatorcontrib>Tang, Xiaoyu</creatorcontrib><creatorcontrib>Zhu, Qili</creatorcontrib><creatorcontrib>Pan, Ke</creatorcontrib><creatorcontrib>Hu, Qichun</creatorcontrib><title>Engineered hydrochar composites for phosphorus removal/recovery: Lanthanum doped hydrochar prepared by hydrothermal carbonization of lanthanum pretreated rice straw</title><title>Bioresource technology</title><addtitle>Bioresour Technol</addtitle><description>•Lanthanum doped hydrochar was prepared by one-pot hydrothermal carbonization.•The adsorbents was highly effective in P adsorption in a wide range of pH.•The competing anions showed little negative effects on P adsorption on the adsorbent.
Engineered hydrochar composites (EHC) were synthesized by hydrothermal carbonization (HTC) of lanthanum pretreated rice straw. The as-prepared composite with about 30% lanthanum content showed greater P removal potential than La(OH)3, indicating the synergistic effect of hydrochar and lanthanum in P removal. The adsorption results showed that EHC showed great P adsorption capacities (>50mgPg−1) in the pH range of 2.5–10.5, and the presence of competing anions had little negative effects on P adsorption on EHC. The equilibrium time for P adsorption on EHC was considerably reduced under acid condition (12h) compared to alkaline condition (48h). The maximum adsorption capacity was 61.57mgPg−1 according to Langmuir isotherms. These results suggested that EHC was highly effective in P adsorption in a wide range of pH and the presence of competing anions, thus EHC could be a promising adsorbent for phosphorus removal/recovery from wastewater.</description><subject>Adsorption</subject><subject>Anions</subject><subject>Biological and medical sciences</subject><subject>Carbonization</subject><subject>Charcoal - chemistry</subject><subject>Food industries</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Hydrochar composite</subject><subject>Hydrothermal carbonization</subject><subject>Kinetics</subject><subject>Lanthanum</subject><subject>Lanthanum - chemistry</subject><subject>Microscopy, Electron, Scanning</subject><subject>Oryza - chemistry</subject><subject>Oryza sativa</subject><subject>Phosphorus - isolation & purification</subject><subject>Phosphorus recovery</subject><subject>Phosphorus removal</subject><subject>Rice</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Straw</subject><subject>Thermodynamics</subject><subject>Use and upgrading of agricultural and food by-products. Biotechnology</subject><subject>Waste water</subject><subject>X-Ray Diffraction</subject><issn>0960-8524</issn><issn>1873-2976</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkc1uEzEURkcIRNPCK1SzQWKT1P_2sAJVhSJFYgNry_HcYRzNjIdrJyg8Dw-Ko6RFrMrCsmSd7_jaX1VdU7KihKqb7WoTImbw_YoRKlaEr4hRz6oFNZovWaPV82pBGkWWRjJxUV2mtCWEcKrZy-qCCc00l3JR_b6bvocJAKGt-0OL0fcOax_HOaaQIdVdxHruYyoLd6lGGOPeDTcIPu4BD-_qtZty76bdWLdx_scyI8zuKN4cTqe5BxzdUHuHmziFXy6HONWxq4dHR8lkBJdLCoOHOmV0P19VLzo3JHh93q-qbx_vvt7eL9dfPn2-_bBeeqFEXmomiNRcOMV021LuPci2PLQRUsqOC-6MMQ0lXG9UY4SishGU-dZLx6TUhF9Vb0_eGeOPHaRsx5A8DGU8iLtkqdK6UbIIn0YlF4Yq8z_WUhDVynBdUHVCPcaUEDo7YxgdHiwl9ti73dqH3u2xd0u4Lb2X4PX5jt1mhPYx9lB0Ad6cAZe8Gzp0kw_pL2cKSNhR9P7EQfnnfQC0yQeYPLShVJ5tG8NTs_wBU_HR7w</recordid><startdate>20140601</startdate><enddate>20140601</enddate><creator>Dai, Lichun</creator><creator>Wu, Bo</creator><creator>Tan, Furong</creator><creator>He, Mingxiong</creator><creator>Wang, Wenguo</creator><creator>Qin, Han</creator><creator>Tang, Xiaoyu</creator><creator>Zhu, Qili</creator><creator>Pan, Ke</creator><creator>Hu, Qichun</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7QH</scope><scope>7QO</scope><scope>7UA</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>FR3</scope><scope>H97</scope><scope>L.G</scope><scope>P64</scope><scope>7SR</scope><scope>7SU</scope><scope>7TB</scope><scope>JG9</scope><scope>KR7</scope></search><sort><creationdate>20140601</creationdate><title>Engineered hydrochar composites for phosphorus removal/recovery: Lanthanum doped hydrochar prepared by hydrothermal carbonization of lanthanum pretreated rice straw</title><author>Dai, Lichun ; Wu, Bo ; Tan, Furong ; He, Mingxiong ; Wang, Wenguo ; Qin, Han ; Tang, Xiaoyu ; Zhu, Qili ; Pan, Ke ; Hu, Qichun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c464t-72405734a627dd13cce5d72794555f343a88891037b69846159412cdc5a255703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Adsorption</topic><topic>Anions</topic><topic>Biological and medical sciences</topic><topic>Carbonization</topic><topic>Charcoal - chemistry</topic><topic>Food industries</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Hydrochar composite</topic><topic>Hydrothermal carbonization</topic><topic>Kinetics</topic><topic>Lanthanum</topic><topic>Lanthanum - chemistry</topic><topic>Microscopy, Electron, Scanning</topic><topic>Oryza - chemistry</topic><topic>Oryza sativa</topic><topic>Phosphorus - isolation & purification</topic><topic>Phosphorus recovery</topic><topic>Phosphorus removal</topic><topic>Rice</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Straw</topic><topic>Thermodynamics</topic><topic>Use and upgrading of agricultural and food by-products. Biotechnology</topic><topic>Waste water</topic><topic>X-Ray Diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dai, Lichun</creatorcontrib><creatorcontrib>Wu, Bo</creatorcontrib><creatorcontrib>Tan, Furong</creatorcontrib><creatorcontrib>He, Mingxiong</creatorcontrib><creatorcontrib>Wang, Wenguo</creatorcontrib><creatorcontrib>Qin, Han</creatorcontrib><creatorcontrib>Tang, Xiaoyu</creatorcontrib><creatorcontrib>Zhu, Qili</creatorcontrib><creatorcontrib>Pan, Ke</creatorcontrib><creatorcontrib>Hu, Qichun</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Aqualine</collection><collection>Biotechnology Research Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Engineering Research Database</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>Bioresource technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dai, Lichun</au><au>Wu, Bo</au><au>Tan, Furong</au><au>He, Mingxiong</au><au>Wang, Wenguo</au><au>Qin, Han</au><au>Tang, Xiaoyu</au><au>Zhu, Qili</au><au>Pan, Ke</au><au>Hu, Qichun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Engineered hydrochar composites for phosphorus removal/recovery: Lanthanum doped hydrochar prepared by hydrothermal carbonization of lanthanum pretreated rice straw</atitle><jtitle>Bioresource technology</jtitle><addtitle>Bioresour Technol</addtitle><date>2014-06-01</date><risdate>2014</risdate><volume>161</volume><spage>327</spage><epage>332</epage><pages>327-332</pages><issn>0960-8524</issn><eissn>1873-2976</eissn><abstract>•Lanthanum doped hydrochar was prepared by one-pot hydrothermal carbonization.•The adsorbents was highly effective in P adsorption in a wide range of pH.•The competing anions showed little negative effects on P adsorption on the adsorbent.
Engineered hydrochar composites (EHC) were synthesized by hydrothermal carbonization (HTC) of lanthanum pretreated rice straw. The as-prepared composite with about 30% lanthanum content showed greater P removal potential than La(OH)3, indicating the synergistic effect of hydrochar and lanthanum in P removal. The adsorption results showed that EHC showed great P adsorption capacities (>50mgPg−1) in the pH range of 2.5–10.5, and the presence of competing anions had little negative effects on P adsorption on EHC. The equilibrium time for P adsorption on EHC was considerably reduced under acid condition (12h) compared to alkaline condition (48h). The maximum adsorption capacity was 61.57mgPg−1 according to Langmuir isotherms. These results suggested that EHC was highly effective in P adsorption in a wide range of pH and the presence of competing anions, thus EHC could be a promising adsorbent for phosphorus removal/recovery from wastewater.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><pmid>24727355</pmid><doi>10.1016/j.biortech.2014.03.086</doi><tpages>6</tpages></addata></record> |
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subjects | Adsorption Anions Biological and medical sciences Carbonization Charcoal - chemistry Food industries Fundamental and applied biological sciences. Psychology Hydrochar composite Hydrothermal carbonization Kinetics Lanthanum Lanthanum - chemistry Microscopy, Electron, Scanning Oryza - chemistry Oryza sativa Phosphorus - isolation & purification Phosphorus recovery Phosphorus removal Rice Spectroscopy, Fourier Transform Infrared Straw Thermodynamics Use and upgrading of agricultural and food by-products. Biotechnology Waste water X-Ray Diffraction |
title | Engineered hydrochar composites for phosphorus removal/recovery: Lanthanum doped hydrochar prepared by hydrothermal carbonization of lanthanum pretreated rice straw |
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