Engineered hydrochar composites for phosphorus removal/recovery: Lanthanum doped hydrochar prepared by hydrothermal carbonization of lanthanum pretreated rice straw

•Lanthanum doped hydrochar was prepared by one-pot hydrothermal carbonization.•The adsorbents was highly effective in P adsorption in a wide range of pH.•The competing anions showed little negative effects on P adsorption on the adsorbent. Engineered hydrochar composites (EHC) were synthesized by hy...

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Veröffentlicht in:Bioresource technology 2014-06, Vol.161, p.327-332
Hauptverfasser: Dai, Lichun, Wu, Bo, Tan, Furong, He, Mingxiong, Wang, Wenguo, Qin, Han, Tang, Xiaoyu, Zhu, Qili, Pan, Ke, Hu, Qichun
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container_end_page 332
container_issue
container_start_page 327
container_title Bioresource technology
container_volume 161
creator Dai, Lichun
Wu, Bo
Tan, Furong
He, Mingxiong
Wang, Wenguo
Qin, Han
Tang, Xiaoyu
Zhu, Qili
Pan, Ke
Hu, Qichun
description •Lanthanum doped hydrochar was prepared by one-pot hydrothermal carbonization.•The adsorbents was highly effective in P adsorption in a wide range of pH.•The competing anions showed little negative effects on P adsorption on the adsorbent. Engineered hydrochar composites (EHC) were synthesized by hydrothermal carbonization (HTC) of lanthanum pretreated rice straw. The as-prepared composite with about 30% lanthanum content showed greater P removal potential than La(OH)3, indicating the synergistic effect of hydrochar and lanthanum in P removal. The adsorption results showed that EHC showed great P adsorption capacities (>50mgPg−1) in the pH range of 2.5–10.5, and the presence of competing anions had little negative effects on P adsorption on EHC. The equilibrium time for P adsorption on EHC was considerably reduced under acid condition (12h) compared to alkaline condition (48h). The maximum adsorption capacity was 61.57mgPg−1 according to Langmuir isotherms. These results suggested that EHC was highly effective in P adsorption in a wide range of pH and the presence of competing anions, thus EHC could be a promising adsorbent for phosphorus removal/recovery from wastewater.
doi_str_mv 10.1016/j.biortech.2014.03.086
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Engineered hydrochar composites (EHC) were synthesized by hydrothermal carbonization (HTC) of lanthanum pretreated rice straw. The as-prepared composite with about 30% lanthanum content showed greater P removal potential than La(OH)3, indicating the synergistic effect of hydrochar and lanthanum in P removal. The adsorption results showed that EHC showed great P adsorption capacities (&gt;50mgPg−1) in the pH range of 2.5–10.5, and the presence of competing anions had little negative effects on P adsorption on EHC. The equilibrium time for P adsorption on EHC was considerably reduced under acid condition (12h) compared to alkaline condition (48h). The maximum adsorption capacity was 61.57mgPg−1 according to Langmuir isotherms. 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These results suggested that EHC was highly effective in P adsorption in a wide range of pH and the presence of competing anions, thus EHC could be a promising adsorbent for phosphorus removal/recovery from wastewater.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><pmid>24727355</pmid><doi>10.1016/j.biortech.2014.03.086</doi><tpages>6</tpages></addata></record>
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subjects Adsorption
Anions
Biological and medical sciences
Carbonization
Charcoal - chemistry
Food industries
Fundamental and applied biological sciences. Psychology
Hydrochar composite
Hydrothermal carbonization
Kinetics
Lanthanum
Lanthanum - chemistry
Microscopy, Electron, Scanning
Oryza - chemistry
Oryza sativa
Phosphorus - isolation & purification
Phosphorus recovery
Phosphorus removal
Rice
Spectroscopy, Fourier Transform Infrared
Straw
Thermodynamics
Use and upgrading of agricultural and food by-products. Biotechnology
Waste water
X-Ray Diffraction
title Engineered hydrochar composites for phosphorus removal/recovery: Lanthanum doped hydrochar prepared by hydrothermal carbonization of lanthanum pretreated rice straw
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