Stereospecific Styrene Polymerization by Methylalumoxane-Activated Ti (IV) N-Trimethylsilylamido Complexes Bearing the N-Biphenyl or N-(6-(2-(Diethylboryl)phenyl)-Pyrid-2-yl) Motif

Cp'TiCl2(N‐(6‐(2‐(diethylboryl)phenyl)pyrid‐2‐yl)SiMe3), [Cp' = C5H5 (3), C5(CH3)5 (4)], and the aminoborane‐free half‐titanocene analogs with the general formula: Cp'TiCl2(N‐(biphenyl‐3‐yl)SiMe3); [Cp' = C5H5 (7), C5(CH3)5 (8)] are synthesized and used in the polymerization of s...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Macromolecular chemistry and physics 2014-10, Vol.215 (20), p.2007-2013
Hauptverfasser:	Narayana, Gurram Venkata, Xu, Guangjuan, Wang, Dongren, Speiser, Maria, Frey, Wolfgang, Buchmeiser, Michael R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Analogs Bearing Catalysts Chemical synthesis Molecular weight Polymerization Polystyrene resins Styrene Styrenes syndiotactic polymers Syndiotacticity Synthesis Titanium Titanium chlorides
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!