Experimental Method to Discriminate RAFT Models between Intermediate Termination and Slow Fragmentation via Comparison of Rates of Miniemulsion and Bulk Polymerization

A simple model discrimination method for RAFT polymerization mechanism, proposed on a theoretical basis, is applied to the polystyryl dithiobenzoate‐mediated styrene polymerization. It is confirmed that the intermediate termination (IT) is the major reason for the rate retardation. The method utiliz...

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Veröffentlicht in:	Macromolecular theory and simulations 2014-03, Vol.23 (3), p.136-146
Hauptverfasser:	Suzuki, Kiyoshi, Kanematsu, Yuta, Miura, Takashi, Minami, Masayuki, Satoh, Shuzaemon, Tobita, Hidetaka
Format:	Artikel
Sprache:	eng
Schlagworte:	Bulk polymerization Discrimination Droplets emulsion polymerization Fragmentation intermediate termination kinetics (polym.) Mathematical models modeling and theory Polymerization Rafts reversible addition fragmentation chain transfer (RAFT) Styrenes Termination (polymerization)
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