Room temperature ferromagnetic Cr–Ni codoped ZnO diluted magnetic semiconductors synthesized by hydrothermal method under high pulsed magnetic field
Pulse magnetic field-assisted hydrothermal method was used for the preparation of Cr–Ni codoped ZnO diluted magnetic semiconductors. XRD analysis reveals that all the samples have hexagonal wurtzite structure. HRTEM, EDS measurements and XPS results ensure that the divalent Cr and Ni ions have incor...
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Veröffentlicht in: | Ceramics international 2015-01, Vol.41 (1), p.451-457 |
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creator | Zhong, Min Wang, Shiwei Li, Ying Hu, Yemin Zhu, Mingyuan Jin, Hongmin Li, Yibing Zhang, Haimin Zhao, Huijun |
description | Pulse magnetic field-assisted hydrothermal method was used for the preparation of Cr–Ni codoped ZnO diluted magnetic semiconductors. XRD analysis reveals that all the samples have hexagonal wurtzite structure. HRTEM, EDS measurements and XPS results ensure that the divalent Cr and Ni ions have incorporated in the wurtzite host matrix without any detectable impurity phase formed. M–H and ZFC/FC curves of the samples reveal the enhancement of ferromagnetism resulted from the magnetic field processing. XPS measurement and Raman scattering spectra indicate that the content of oxygen vacancies in the sample increases with pulse magnetic field processing. According to the bound magnetic polaron model, this may be the reason for the sample with magnetic field processing having better ferromagnetism than that without field processing. |
doi_str_mv | 10.1016/j.ceramint.2014.08.091 |
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XRD analysis reveals that all the samples have hexagonal wurtzite structure. HRTEM, EDS measurements and XPS results ensure that the divalent Cr and Ni ions have incorporated in the wurtzite host matrix without any detectable impurity phase formed. M–H and ZFC/FC curves of the samples reveal the enhancement of ferromagnetism resulted from the magnetic field processing. XPS measurement and Raman scattering spectra indicate that the content of oxygen vacancies in the sample increases with pulse magnetic field processing. According to the bound magnetic polaron model, this may be the reason for the sample with magnetic field processing having better ferromagnetism than that without field processing.</description><subject>Ceramics</subject><subject>Chromium</subject><subject>Diluted magnetic semiconductor</subject><subject>Dilution</subject><subject>Ferromagnetism</subject><subject>Hydrothermal method</subject><subject>Magnetic fields</subject><subject>Magnetic semiconductors</subject><subject>Pulsed magnetic field</subject><subject>Wurtzite</subject><subject>X-ray photoelectron spectroscopy</subject><subject>Zinc oxide</subject><subject>ZnO</subject><issn>0272-8842</issn><issn>1873-3956</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkcFqFTEYhYNY8Nr2FSRLNzMmM5NMslMuWgvFgnTVTZhJ_nRymUzGJCPcrnwHwQf0SUy5Ku5c5efwnQ_CQegVJTUllL851Bri4N2S64bQriaiJpI-Qzsq-rZqJePP0Y40fVMJ0TUv0MuUDqQUZUd26MfnEDzO4NfiyFsEbCHG4IeHBbLTeB9_fvv-yWEdTFjB4PvlFhs3b7ncf6EE3umwmE3nEBNOxyVPkNxjYcYjno4mhhJEP8zYQ56CwdtiIOLJPUx43eb0r8w6mM0FOrNDyS9_v-fo7sP7u_3H6ub26nr_7qbSbcdyxdjIDbVCCiMY48xKK4WmjI6j4GOJjG6k7aGzI29621lttaaN0cRS1vD2HL0-adcYvmyQsvIuaZjnYYGwJUV538tWtn1fUH5CdQwpRbBqjc4P8agoUU87qIP6s4N62kERocoOpfj2VITyj68OokrawaLBuAg6KxPc_xS_ALXamtk</recordid><startdate>201501</startdate><enddate>201501</enddate><creator>Zhong, Min</creator><creator>Wang, Shiwei</creator><creator>Li, Ying</creator><creator>Hu, Yemin</creator><creator>Zhu, Mingyuan</creator><creator>Jin, Hongmin</creator><creator>Li, Yibing</creator><creator>Zhang, Haimin</creator><creator>Zhao, Huijun</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>201501</creationdate><title>Room temperature ferromagnetic Cr–Ni codoped ZnO diluted magnetic semiconductors synthesized by hydrothermal method under high pulsed magnetic field</title><author>Zhong, Min ; Wang, Shiwei ; Li, Ying ; Hu, Yemin ; Zhu, Mingyuan ; Jin, Hongmin ; Li, Yibing ; Zhang, Haimin ; Zhao, Huijun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c345t-55b6d1f898d85565f9f98c151bb86b855dc29f7e4fb627f4fcfcc12dc0f15263</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Ceramics</topic><topic>Chromium</topic><topic>Diluted magnetic semiconductor</topic><topic>Dilution</topic><topic>Ferromagnetism</topic><topic>Hydrothermal method</topic><topic>Magnetic fields</topic><topic>Magnetic semiconductors</topic><topic>Pulsed magnetic field</topic><topic>Wurtzite</topic><topic>X-ray photoelectron spectroscopy</topic><topic>Zinc oxide</topic><topic>ZnO</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhong, Min</creatorcontrib><creatorcontrib>Wang, Shiwei</creatorcontrib><creatorcontrib>Li, Ying</creatorcontrib><creatorcontrib>Hu, Yemin</creatorcontrib><creatorcontrib>Zhu, Mingyuan</creatorcontrib><creatorcontrib>Jin, Hongmin</creatorcontrib><creatorcontrib>Li, Yibing</creatorcontrib><creatorcontrib>Zhang, Haimin</creatorcontrib><creatorcontrib>Zhao, Huijun</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Ceramics international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhong, Min</au><au>Wang, Shiwei</au><au>Li, Ying</au><au>Hu, Yemin</au><au>Zhu, Mingyuan</au><au>Jin, Hongmin</au><au>Li, Yibing</au><au>Zhang, Haimin</au><au>Zhao, Huijun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Room temperature ferromagnetic Cr–Ni codoped ZnO diluted magnetic semiconductors synthesized by hydrothermal method under high pulsed magnetic field</atitle><jtitle>Ceramics international</jtitle><date>2015-01</date><risdate>2015</risdate><volume>41</volume><issue>1</issue><spage>451</spage><epage>457</epage><pages>451-457</pages><issn>0272-8842</issn><eissn>1873-3956</eissn><abstract>Pulse magnetic field-assisted hydrothermal method was used for the preparation of Cr–Ni codoped ZnO diluted magnetic semiconductors. XRD analysis reveals that all the samples have hexagonal wurtzite structure. HRTEM, EDS measurements and XPS results ensure that the divalent Cr and Ni ions have incorporated in the wurtzite host matrix without any detectable impurity phase formed. M–H and ZFC/FC curves of the samples reveal the enhancement of ferromagnetism resulted from the magnetic field processing. XPS measurement and Raman scattering spectra indicate that the content of oxygen vacancies in the sample increases with pulse magnetic field processing. According to the bound magnetic polaron model, this may be the reason for the sample with magnetic field processing having better ferromagnetism than that without field processing.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.ceramint.2014.08.091</doi><tpages>7</tpages></addata></record> |
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subjects | Ceramics Chromium Diluted magnetic semiconductor Dilution Ferromagnetism Hydrothermal method Magnetic fields Magnetic semiconductors Pulsed magnetic field Wurtzite X-ray photoelectron spectroscopy Zinc oxide ZnO |
title | Room temperature ferromagnetic Cr–Ni codoped ZnO diluted magnetic semiconductors synthesized by hydrothermal method under high pulsed magnetic field |
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