Room temperature ferromagnetic Cr–Ni codoped ZnO diluted magnetic semiconductors synthesized by hydrothermal method under high pulsed magnetic field

Pulse magnetic field-assisted hydrothermal method was used for the preparation of Cr–Ni codoped ZnO diluted magnetic semiconductors. XRD analysis reveals that all the samples have hexagonal wurtzite structure. HRTEM, EDS measurements and XPS results ensure that the divalent Cr and Ni ions have incor...

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Veröffentlicht in:Ceramics international 2015-01, Vol.41 (1), p.451-457
Hauptverfasser: Zhong, Min, Wang, Shiwei, Li, Ying, Hu, Yemin, Zhu, Mingyuan, Jin, Hongmin, Li, Yibing, Zhang, Haimin, Zhao, Huijun
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container_end_page 457
container_issue 1
container_start_page 451
container_title Ceramics international
container_volume 41
creator Zhong, Min
Wang, Shiwei
Li, Ying
Hu, Yemin
Zhu, Mingyuan
Jin, Hongmin
Li, Yibing
Zhang, Haimin
Zhao, Huijun
description Pulse magnetic field-assisted hydrothermal method was used for the preparation of Cr–Ni codoped ZnO diluted magnetic semiconductors. XRD analysis reveals that all the samples have hexagonal wurtzite structure. HRTEM, EDS measurements and XPS results ensure that the divalent Cr and Ni ions have incorporated in the wurtzite host matrix without any detectable impurity phase formed. M–H and ZFC/FC curves of the samples reveal the enhancement of ferromagnetism resulted from the magnetic field processing. XPS measurement and Raman scattering spectra indicate that the content of oxygen vacancies in the sample increases with pulse magnetic field processing. According to the bound magnetic polaron model, this may be the reason for the sample with magnetic field processing having better ferromagnetism than that without field processing.
doi_str_mv 10.1016/j.ceramint.2014.08.091
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subjects Ceramics
Chromium
Diluted magnetic semiconductor
Dilution
Ferromagnetism
Hydrothermal method
Magnetic fields
Magnetic semiconductors
Pulsed magnetic field
Wurtzite
X-ray photoelectron spectroscopy
Zinc oxide
ZnO
title Room temperature ferromagnetic Cr–Ni codoped ZnO diluted magnetic semiconductors synthesized by hydrothermal method under high pulsed magnetic field
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