Impact of titanium and silica/titanium fumed oxide nanofillers on the elastic properties and thermal decomposition of a polyester resin
ABSTRACT The impact of nanoparticles of titanium (rutile) and silica–titanium fumed oxide (STO) on both the acoustic properties and thermal decomposition of a styrene‐crosslinked unsaturated polyester resin were studied with the methods of ultrasonic probing and thermal decomposition mass spectromet...
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| Veröffentlicht in: | Journal of applied polymer science 2015-06, Vol.132 (22), p.np-n/a |
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| container_title | Journal of applied polymer science |
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| creator | Gorelov, Borys Gorb, Alla Korotchenkov, Oleg Nadtochiy, Andriy Polovina, Oleksiy Sigareva, Nadia |
| description | ABSTRACT
The impact of nanoparticles of titanium (rutile) and silica–titanium fumed oxide (STO) on both the acoustic properties and thermal decomposition of a styrene‐crosslinked unsaturated polyester resin were studied with the methods of ultrasonic probing and thermal decomposition mass spectrometry at filler loadings ranging from 0.5 to 5.0%. It was shown that the elastic modulus, Poisson's ratio, and thermal resistivity in the titanium‐filled nanocomposites increased at small loadings of about 0.5%, whereas in the STO‐filled nanoparticles, the decreases in the parameters at loadings of up to 1.5% was replaced by some increases at higher loadings of up to 5.0%. Distinctions in the concentration dependences of the elastic parameters and the thermal decomposition intensity for both fillers could be explained by the features of the polymer–particle interactions because of the differences in both the number of active sites located on the particle's surface and the polymer structure within interface regions. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42010. |
| doi_str_mv | 10.1002/app.42010 |
| format | Article |
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The impact of nanoparticles of titanium (rutile) and silica–titanium fumed oxide (STO) on both the acoustic properties and thermal decomposition of a styrene‐crosslinked unsaturated polyester resin were studied with the methods of ultrasonic probing and thermal decomposition mass spectrometry at filler loadings ranging from 0.5 to 5.0%. It was shown that the elastic modulus, Poisson's ratio, and thermal resistivity in the titanium‐filled nanocomposites increased at small loadings of about 0.5%, whereas in the STO‐filled nanoparticles, the decreases in the parameters at loadings of up to 1.5% was replaced by some increases at higher loadings of up to 5.0%. Distinctions in the concentration dependences of the elastic parameters and the thermal decomposition intensity for both fillers could be explained by the features of the polymer–particle interactions because of the differences in both the number of active sites located on the particle's surface and the polymer structure within interface regions. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42010.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.42010</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Blackwell Publishing Ltd</publisher><subject>composites ; Fillers ; Materials science ; mechanical properties ; Nanoparticles ; Nanostructure ; nanowires and nanocrystals ; Oxides ; Polyester resins ; Polymers ; resins ; Rutile ; Thermal conductivity ; Thermal decomposition ; thermal properties ; Titanium</subject><ispartof>Journal of applied polymer science, 2015-06, Vol.132 (22), p.np-n/a</ispartof><rights>2015 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3680-fc991ee18e19a42acc98a46a692b870e0aaf10e00956e1cd5043405b64c8499e3</citedby><cites>FETCH-LOGICAL-c3680-fc991ee18e19a42acc98a46a692b870e0aaf10e00956e1cd5043405b64c8499e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.42010$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.42010$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27928,27929,45578,45579</link.rule.ids></links><search><creatorcontrib>Gorelov, Borys</creatorcontrib><creatorcontrib>Gorb, Alla</creatorcontrib><creatorcontrib>Korotchenkov, Oleg</creatorcontrib><creatorcontrib>Nadtochiy, Andriy</creatorcontrib><creatorcontrib>Polovina, Oleksiy</creatorcontrib><creatorcontrib>Sigareva, Nadia</creatorcontrib><title>Impact of titanium and silica/titanium fumed oxide nanofillers on the elastic properties and thermal decomposition of a polyester resin</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>ABSTRACT
The impact of nanoparticles of titanium (rutile) and silica–titanium fumed oxide (STO) on both the acoustic properties and thermal decomposition of a styrene‐crosslinked unsaturated polyester resin were studied with the methods of ultrasonic probing and thermal decomposition mass spectrometry at filler loadings ranging from 0.5 to 5.0%. It was shown that the elastic modulus, Poisson's ratio, and thermal resistivity in the titanium‐filled nanocomposites increased at small loadings of about 0.5%, whereas in the STO‐filled nanoparticles, the decreases in the parameters at loadings of up to 1.5% was replaced by some increases at higher loadings of up to 5.0%. Distinctions in the concentration dependences of the elastic parameters and the thermal decomposition intensity for both fillers could be explained by the features of the polymer–particle interactions because of the differences in both the number of active sites located on the particle's surface and the polymer structure within interface regions. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42010.</description><subject>composites</subject><subject>Fillers</subject><subject>Materials science</subject><subject>mechanical properties</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>nanowires and nanocrystals</subject><subject>Oxides</subject><subject>Polyester resins</subject><subject>Polymers</subject><subject>resins</subject><subject>Rutile</subject><subject>Thermal conductivity</subject><subject>Thermal decomposition</subject><subject>thermal properties</subject><subject>Titanium</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp1kc9u1DAQxi1UJLaFA29gqRc4pOtJHCc-llXZtqqgB_4crakzEW6dONiJ6D4Br43bpT0gcRiNNPP7xp_8MfYWxAkIUa5xmk5kKUC8YCsQuimkKtsDtso7KFqt61fsMKVbIQBqoVbs98UwoZ156PnsZhzdMnAcO56cdxbXz7N-Gajj4d51xEccQ--8p5h4GPn8gzh5TLOzfIphojg7So9X8ioO6HlHNgxTSG52WZDfQj4Fv6M0U-SRkhtfs5c9-kRv_vYj9vXj2ZfNeXH1eXuxOb0qbKVaUfRWayCClkCjLNFa3aJUqHR50zaCBGIPuQldKwLb1UJWUtQ3StpWak3VEXu3v5ud_lyyATO4ZMl7HCksyYBqGl3lgowe_4PehiWO2V2mFNSVakSdqfd7ysaQUqTeTNENGHcGhHmIxORIzGMkmV3v2V_O0-7_oDm9vn5SFHuFy191_6zAeGdUUzW1-f5pa759qOTltgWzqf4Ai_Od7g</recordid><startdate>20150610</startdate><enddate>20150610</enddate><creator>Gorelov, Borys</creator><creator>Gorb, Alla</creator><creator>Korotchenkov, Oleg</creator><creator>Nadtochiy, Andriy</creator><creator>Polovina, Oleksiy</creator><creator>Sigareva, Nadia</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>7U5</scope><scope>L7M</scope></search><sort><creationdate>20150610</creationdate><title>Impact of titanium and silica/titanium fumed oxide nanofillers on the elastic properties and thermal decomposition of a polyester resin</title><author>Gorelov, Borys ; Gorb, Alla ; Korotchenkov, Oleg ; Nadtochiy, Andriy ; Polovina, Oleksiy ; Sigareva, Nadia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3680-fc991ee18e19a42acc98a46a692b870e0aaf10e00956e1cd5043405b64c8499e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>composites</topic><topic>Fillers</topic><topic>Materials science</topic><topic>mechanical properties</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>nanowires and nanocrystals</topic><topic>Oxides</topic><topic>Polyester resins</topic><topic>Polymers</topic><topic>resins</topic><topic>Rutile</topic><topic>Thermal conductivity</topic><topic>Thermal decomposition</topic><topic>thermal properties</topic><topic>Titanium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gorelov, Borys</creatorcontrib><creatorcontrib>Gorb, Alla</creatorcontrib><creatorcontrib>Korotchenkov, Oleg</creatorcontrib><creatorcontrib>Nadtochiy, Andriy</creatorcontrib><creatorcontrib>Polovina, Oleksiy</creatorcontrib><creatorcontrib>Sigareva, Nadia</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gorelov, Borys</au><au>Gorb, Alla</au><au>Korotchenkov, Oleg</au><au>Nadtochiy, Andriy</au><au>Polovina, Oleksiy</au><au>Sigareva, Nadia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Impact of titanium and silica/titanium fumed oxide nanofillers on the elastic properties and thermal decomposition of a polyester resin</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2015-06-10</date><risdate>2015</risdate><volume>132</volume><issue>22</issue><spage>np</spage><epage>n/a</epage><pages>np-n/a</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>ABSTRACT
The impact of nanoparticles of titanium (rutile) and silica–titanium fumed oxide (STO) on both the acoustic properties and thermal decomposition of a styrene‐crosslinked unsaturated polyester resin were studied with the methods of ultrasonic probing and thermal decomposition mass spectrometry at filler loadings ranging from 0.5 to 5.0%. It was shown that the elastic modulus, Poisson's ratio, and thermal resistivity in the titanium‐filled nanocomposites increased at small loadings of about 0.5%, whereas in the STO‐filled nanoparticles, the decreases in the parameters at loadings of up to 1.5% was replaced by some increases at higher loadings of up to 5.0%. Distinctions in the concentration dependences of the elastic parameters and the thermal decomposition intensity for both fillers could be explained by the features of the polymer–particle interactions because of the differences in both the number of active sites located on the particle's surface and the polymer structure within interface regions. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42010.</abstract><cop>Hoboken</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.42010</doi><tpages>10</tpages></addata></record> |
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| subjects | composites Fillers Materials science mechanical properties Nanoparticles Nanostructure nanowires and nanocrystals Oxides Polyester resins Polymers resins Rutile Thermal conductivity Thermal decomposition thermal properties Titanium |
| title | Impact of titanium and silica/titanium fumed oxide nanofillers on the elastic properties and thermal decomposition of a polyester resin |
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