Donor–acceptor rod–coil block copolymers comprising poly[2,7‐(9,9‐dihexylfluorene)‐alt‐bithiophene] and fullerene as compatibilizers for organic photovoltaic devices
The successful synthesis is described for a donor–acceptor rod–coil block copolymer comprising blocks of poly[2,7‐(9,9‐dihexylfluorene)‐alt‐bithiophene] (F6T2) and polystyrene functionalized with fullerene (PS(C₆₀)) (F6T2‐b‐PS(C₆₀)). This new material was obtained by combining Suzuki polycondensatio...
Gespeichert in:
| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2015-04, Vol.53 (7), p.888-903 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 903 |
|---|---|
| container_issue | 7 |
| container_start_page | 888 |
| container_title | Journal of polymer science. Part A, Polymer chemistry |
| container_volume | 53 |
| creator | Bicciocchi, Erika Haeussler, Matthias Rizzardo, Ezio Scully, Andrew D Ghiggino, Kenneth P |
| description | The successful synthesis is described for a donor–acceptor rod–coil block copolymer comprising blocks of poly[2,7‐(9,9‐dihexylfluorene)‐alt‐bithiophene] (F6T2) and polystyrene functionalized with fullerene (PS(C₆₀)) (F6T2‐b‐PS(C₆₀)). This new material was obtained by combining Suzuki polycondensation with radical addition fragmentation chain transfer. The block copolymer was characterized by nuclear magnetic resonance, gel permeation chromatography, and optical spectroscopy methods. Photophysical data for (F6T2‐b‐PS(C₆₀)) and a related block copolymer (F6T2‐b‐PS(PCBM)) (PCBM, phenyl‐C61‐butyric acid methyl ester) are reported and their performance as compatibilizers in bulk heterojunction organic solar cells is assessed. It is demonstrated that the addition of the rod–coil block copolymers to the active layer extends the operational stability of organic photovoltaic devices. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 888–903 |
| doi_str_mv | 10.1002/pola.27514 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1677929818</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3602523301</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5364-b1e3564b37f0f583b5e479e59b142cde5986452277c4e4548d0bccb2c60f08743</originalsourceid><addsrcrecordid>eNp9ks1u1DAQxyMEEkvhwgsQiUuLmmI7duwc-wEFadWu1FZFQshyHGfXrTcOdlK6nPoISDwJr9QnYUKAAwcu8-XfjEf-O0meY7SHESKvO-_UHuEM0wfJDKOyzBDD4mEyQ0LwrCD0w-PkSYxXCMEZE7Pkx5Fvfbi_-660Nl3vQxp8Dan21qWV8_o61R6mbtYmRAjXXbDRtst0rH0ku_z-7tt2uVuCq-3K3G5c4wYfTGt2oKRcD7ay_cr6bgXFT6lq67QZnDMjk6pppuptZZ39Ot7RwA4-LFVrddqtfO9vvOsVJLW5sdrEp8mjRrlonv32W8nF2zfnh--y-enx-8P9eaZZXtCswiZnBa1y3qCGibxihvLSsLLClOgaAlFQRgjnmhrKqKhRpXVFdIEaJDjNt5LtaW4X_OfBxF6ubdTGOdUaP0SJC85LUgosAH35D3rlh9DCdkAxznhR5OPAVxOlg48xmEbCW65V2EiM5KieHNWTv9QDGE_wF-vM5j-kXJzO9__0ZFOPjb25_dujwrUseM6ZvDw5licHi8X50cGlPAP-xcQ3yku1BGHlxRlBuIDfkTMG5id8n765</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1657576634</pqid></control><display><type>article</type><title>Donor–acceptor rod–coil block copolymers comprising poly[2,7‐(9,9‐dihexylfluorene)‐alt‐bithiophene] and fullerene as compatibilizers for organic photovoltaic devices</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Bicciocchi, Erika ; Haeussler, Matthias ; Rizzardo, Ezio ; Scully, Andrew D ; Ghiggino, Kenneth P</creator><creatorcontrib>Bicciocchi, Erika ; Haeussler, Matthias ; Rizzardo, Ezio ; Scully, Andrew D ; Ghiggino, Kenneth P</creatorcontrib><description>The successful synthesis is described for a donor–acceptor rod–coil block copolymer comprising blocks of poly[2,7‐(9,9‐dihexylfluorene)‐alt‐bithiophene] (F6T2) and polystyrene functionalized with fullerene (PS(C₆₀)) (F6T2‐b‐PS(C₆₀)). This new material was obtained by combining Suzuki polycondensation with radical addition fragmentation chain transfer. The block copolymer was characterized by nuclear magnetic resonance, gel permeation chromatography, and optical spectroscopy methods. Photophysical data for (F6T2‐b‐PS(C₆₀)) and a related block copolymer (F6T2‐b‐PS(PCBM)) (PCBM, phenyl‐C61‐butyric acid methyl ester) are reported and their performance as compatibilizers in bulk heterojunction organic solar cells is assessed. It is demonstrated that the addition of the rod–coil block copolymers to the active layer extends the operational stability of organic photovoltaic devices. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 888–903</description><identifier>ISSN: 0887-624X</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/pola.27514</identifier><identifier>CODEN: JPACEC</identifier><language>eng</language><publisher>Hoboken: Wiley</publisher><subject>Active control ; block copolymer ; Block copolymers ; Buckminsterfullerene ; Chain transfer ; compatibilizer ; Compatibilizers ; composite polymers ; conjugated polymers ; donor-acceptor rod-coil block copolymer ; fullerene ; Fullerenes ; gel chromatography ; nuclear magnetic resonance spectroscopy ; organic photovoltaic ; photophysics ; Photovoltaic cells ; polystyrenes ; RAFT ; Solar cells ; Stability ; thermal stability ; transient absorption spectroscopy</subject><ispartof>Journal of polymer science. Part A, Polymer chemistry, 2015-04, Vol.53 (7), p.888-903</ispartof><rights>2015 Wiley Periodicals, Inc.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5364-b1e3564b37f0f583b5e479e59b142cde5986452277c4e4548d0bccb2c60f08743</citedby><cites>FETCH-LOGICAL-c5364-b1e3564b37f0f583b5e479e59b142cde5986452277c4e4548d0bccb2c60f08743</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpola.27514$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpola.27514$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Bicciocchi, Erika</creatorcontrib><creatorcontrib>Haeussler, Matthias</creatorcontrib><creatorcontrib>Rizzardo, Ezio</creatorcontrib><creatorcontrib>Scully, Andrew D</creatorcontrib><creatorcontrib>Ghiggino, Kenneth P</creatorcontrib><title>Donor–acceptor rod–coil block copolymers comprising poly[2,7‐(9,9‐dihexylfluorene)‐alt‐bithiophene] and fullerene as compatibilizers for organic photovoltaic devices</title><title>Journal of polymer science. Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. Part A: Polym. Chem</addtitle><description>The successful synthesis is described for a donor–acceptor rod–coil block copolymer comprising blocks of poly[2,7‐(9,9‐dihexylfluorene)‐alt‐bithiophene] (F6T2) and polystyrene functionalized with fullerene (PS(C₆₀)) (F6T2‐b‐PS(C₆₀)). This new material was obtained by combining Suzuki polycondensation with radical addition fragmentation chain transfer. The block copolymer was characterized by nuclear magnetic resonance, gel permeation chromatography, and optical spectroscopy methods. Photophysical data for (F6T2‐b‐PS(C₆₀)) and a related block copolymer (F6T2‐b‐PS(PCBM)) (PCBM, phenyl‐C61‐butyric acid methyl ester) are reported and their performance as compatibilizers in bulk heterojunction organic solar cells is assessed. It is demonstrated that the addition of the rod–coil block copolymers to the active layer extends the operational stability of organic photovoltaic devices. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 888–903</description><subject>Active control</subject><subject>block copolymer</subject><subject>Block copolymers</subject><subject>Buckminsterfullerene</subject><subject>Chain transfer</subject><subject>compatibilizer</subject><subject>Compatibilizers</subject><subject>composite polymers</subject><subject>conjugated polymers</subject><subject>donor-acceptor rod-coil block copolymer</subject><subject>fullerene</subject><subject>Fullerenes</subject><subject>gel chromatography</subject><subject>nuclear magnetic resonance spectroscopy</subject><subject>organic photovoltaic</subject><subject>photophysics</subject><subject>Photovoltaic cells</subject><subject>polystyrenes</subject><subject>RAFT</subject><subject>Solar cells</subject><subject>Stability</subject><subject>thermal stability</subject><subject>transient absorption spectroscopy</subject><issn>0887-624X</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9ks1u1DAQxyMEEkvhwgsQiUuLmmI7duwc-wEFadWu1FZFQshyHGfXrTcOdlK6nPoISDwJr9QnYUKAAwcu8-XfjEf-O0meY7SHESKvO-_UHuEM0wfJDKOyzBDD4mEyQ0LwrCD0w-PkSYxXCMEZE7Pkx5Fvfbi_-660Nl3vQxp8Dan21qWV8_o61R6mbtYmRAjXXbDRtst0rH0ku_z-7tt2uVuCq-3K3G5c4wYfTGt2oKRcD7ay_cr6bgXFT6lq67QZnDMjk6pppuptZZ39Ot7RwA4-LFVrddqtfO9vvOsVJLW5sdrEp8mjRrlonv32W8nF2zfnh--y-enx-8P9eaZZXtCswiZnBa1y3qCGibxihvLSsLLClOgaAlFQRgjnmhrKqKhRpXVFdIEaJDjNt5LtaW4X_OfBxF6ubdTGOdUaP0SJC85LUgosAH35D3rlh9DCdkAxznhR5OPAVxOlg48xmEbCW65V2EiM5KieHNWTv9QDGE_wF-vM5j-kXJzO9__0ZFOPjb25_dujwrUseM6ZvDw5licHi8X50cGlPAP-xcQ3yku1BGHlxRlBuIDfkTMG5id8n765</recordid><startdate>20150401</startdate><enddate>20150401</enddate><creator>Bicciocchi, Erika</creator><creator>Haeussler, Matthias</creator><creator>Rizzardo, Ezio</creator><creator>Scully, Andrew D</creator><creator>Ghiggino, Kenneth P</creator><general>Wiley</general><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>FBQ</scope><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>7SP</scope><scope>7TB</scope><scope>FR3</scope><scope>L7M</scope></search><sort><creationdate>20150401</creationdate><title>Donor–acceptor rod–coil block copolymers comprising poly[2,7‐(9,9‐dihexylfluorene)‐alt‐bithiophene] and fullerene as compatibilizers for organic photovoltaic devices</title><author>Bicciocchi, Erika ; Haeussler, Matthias ; Rizzardo, Ezio ; Scully, Andrew D ; Ghiggino, Kenneth P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5364-b1e3564b37f0f583b5e479e59b142cde5986452277c4e4548d0bccb2c60f08743</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Active control</topic><topic>block copolymer</topic><topic>Block copolymers</topic><topic>Buckminsterfullerene</topic><topic>Chain transfer</topic><topic>compatibilizer</topic><topic>Compatibilizers</topic><topic>composite polymers</topic><topic>conjugated polymers</topic><topic>donor-acceptor rod-coil block copolymer</topic><topic>fullerene</topic><topic>Fullerenes</topic><topic>gel chromatography</topic><topic>nuclear magnetic resonance spectroscopy</topic><topic>organic photovoltaic</topic><topic>photophysics</topic><topic>Photovoltaic cells</topic><topic>polystyrenes</topic><topic>RAFT</topic><topic>Solar cells</topic><topic>Stability</topic><topic>thermal stability</topic><topic>transient absorption spectroscopy</topic><toplevel>online_resources</toplevel><creatorcontrib>Bicciocchi, Erika</creatorcontrib><creatorcontrib>Haeussler, Matthias</creatorcontrib><creatorcontrib>Rizzardo, Ezio</creatorcontrib><creatorcontrib>Scully, Andrew D</creatorcontrib><creatorcontrib>Ghiggino, Kenneth P</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bicciocchi, Erika</au><au>Haeussler, Matthias</au><au>Rizzardo, Ezio</au><au>Scully, Andrew D</au><au>Ghiggino, Kenneth P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Donor–acceptor rod–coil block copolymers comprising poly[2,7‐(9,9‐dihexylfluorene)‐alt‐bithiophene] and fullerene as compatibilizers for organic photovoltaic devices</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. Part A: Polym. Chem</addtitle><date>2015-04-01</date><risdate>2015</risdate><volume>53</volume><issue>7</issue><spage>888</spage><epage>903</epage><pages>888-903</pages><issn>0887-624X</issn><eissn>1099-0518</eissn><coden>JPACEC</coden><abstract>The successful synthesis is described for a donor–acceptor rod–coil block copolymer comprising blocks of poly[2,7‐(9,9‐dihexylfluorene)‐alt‐bithiophene] (F6T2) and polystyrene functionalized with fullerene (PS(C₆₀)) (F6T2‐b‐PS(C₆₀)). This new material was obtained by combining Suzuki polycondensation with radical addition fragmentation chain transfer. The block copolymer was characterized by nuclear magnetic resonance, gel permeation chromatography, and optical spectroscopy methods. Photophysical data for (F6T2‐b‐PS(C₆₀)) and a related block copolymer (F6T2‐b‐PS(PCBM)) (PCBM, phenyl‐C61‐butyric acid methyl ester) are reported and their performance as compatibilizers in bulk heterojunction organic solar cells is assessed. It is demonstrated that the addition of the rod–coil block copolymers to the active layer extends the operational stability of organic photovoltaic devices. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 888–903</abstract><cop>Hoboken</cop><pub>Wiley</pub><doi>10.1002/pola.27514</doi><tpages>16</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0887-624X |
| ispartof | Journal of polymer science. Part A, Polymer chemistry, 2015-04, Vol.53 (7), p.888-903 |
| issn | 0887-624X 1099-0518 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1677929818 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Active control block copolymer Block copolymers Buckminsterfullerene Chain transfer compatibilizer Compatibilizers composite polymers conjugated polymers donor-acceptor rod-coil block copolymer fullerene Fullerenes gel chromatography nuclear magnetic resonance spectroscopy organic photovoltaic photophysics Photovoltaic cells polystyrenes RAFT Solar cells Stability thermal stability transient absorption spectroscopy |
| title | Donor–acceptor rod–coil block copolymers comprising poly[2,7‐(9,9‐dihexylfluorene)‐alt‐bithiophene] and fullerene as compatibilizers for organic photovoltaic devices |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T16%3A14%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Donor%E2%80%93acceptor%20rod%E2%80%93coil%20block%20copolymers%20comprising%20poly%5B2,7%E2%80%90(9,9%E2%80%90dihexylfluorene)%E2%80%90alt%E2%80%90bithiophene%5D%20and%20fullerene%20as%20compatibilizers%20for%20organic%20photovoltaic%20devices&rft.jtitle=Journal%20of%20polymer%20science.%20Part%20A,%20Polymer%20chemistry&rft.au=Bicciocchi,%20Erika&rft.date=2015-04-01&rft.volume=53&rft.issue=7&rft.spage=888&rft.epage=903&rft.pages=888-903&rft.issn=0887-624X&rft.eissn=1099-0518&rft.coden=JPACEC&rft_id=info:doi/10.1002/pola.27514&rft_dat=%3Cproquest_cross%3E3602523301%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1657576634&rft_id=info:pmid/&rfr_iscdi=true |