Seed-assisted growth of high-quality multi-crystalline silicon in directional solidification

An approach to grain control using seed-assisted growth in directional solidification (DS) is reported in this paper. Proper multi-crystalline silicon seeds at the bottom of the crucible provided numerous fine nucleation points for the controlled grain growth in an optimized hot-zone. Low dislocatio...

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Veröffentlicht in:Journal of crystal growth 2014-01, Vol.386, p.52-56
Hauptverfasser: Zhu, Didi, Ming, Liang, Huang, Meiling, Zhang, Zhaoyu, Huang, Xinming
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container_title Journal of crystal growth
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Ming, Liang
Huang, Meiling
Zhang, Zhaoyu
Huang, Xinming
description An approach to grain control using seed-assisted growth in directional solidification (DS) is reported in this paper. Proper multi-crystalline silicon seeds at the bottom of the crucible provided numerous fine nucleation points for the controlled grain growth in an optimized hot-zone. Low dislocation density was observed with large numbers of uniform small grains in the silicon ingot, although the grain size increased with crystal growth. Crystals produced using seed-assisted growth showed a higher and more uniform minority carrier lifetime with a much lower dislocation multiplication rate. A higher average solar cell conversion efficiency of about 0.5% in absolute value was obtained in the seed-assisted grown silicon in comparison with that in the seedless silicon under the same cell fabrication process. •Multi-crystalline silicon seeds for externally seeded growth process were performed.•We carried out a study in an optimized hot-zone for seed-assisted growth.•Uniform grains sizes with low dislocation density and propagation rate was obtained.•Minority carrier lifetime with high values and uniform distribution can be achieved.•The solar cells with high conversion efficiency were achieved in the seeded ingot.
doi_str_mv 10.1016/j.jcrysgro.2013.09.051
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A higher average solar cell conversion efficiency of about 0.5% in absolute value was obtained in the seed-assisted grown silicon in comparison with that in the seedless silicon under the same cell fabrication process. •Multi-crystalline silicon seeds for externally seeded growth process were performed.•We carried out a study in an optimized hot-zone for seed-assisted growth.•Uniform grains sizes with low dislocation density and propagation rate was obtained.•Minority carrier lifetime with high values and uniform distribution can be achieved.•The solar cells with high conversion efficiency were achieved in the seeded ingot.</description><identifier>ISSN: 0022-0248</identifier><identifier>EISSN: 1873-5002</identifier><identifier>DOI: 10.1016/j.jcrysgro.2013.09.051</identifier><identifier>CODEN: JCRGAE</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>A1. Directional solidification ; A1. Dislocation ; A2. Seed-assisted ; A3. 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Proper multi-crystalline silicon seeds at the bottom of the crucible provided numerous fine nucleation points for the controlled grain growth in an optimized hot-zone. Low dislocation density was observed with large numbers of uniform small grains in the silicon ingot, although the grain size increased with crystal growth. Crystals produced using seed-assisted growth showed a higher and more uniform minority carrier lifetime with a much lower dislocation multiplication rate. 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subjects A1. Directional solidification
A1. Dislocation
A2. Seed-assisted
A3. Uniform grain sizes
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Crucibles
Crystal growth
Directional solidification
Dislocations
Equations of state, phase equilibria, and phase transitions
Exact sciences and technology
General studies of phase transitions
Grains
Growth from melts
zone melting and refining
Materials science
Methods of crystal growth
physics of crystal growth
Minority carriers
Nucleation
Phase diagrams and microstructures developed by solidification and solid-solid phase transformations
Physics
Silicon
Solidification
Theory and models of crystal growth
physics of crystal growth, crystal morphology and orientation
title Seed-assisted growth of high-quality multi-crystalline silicon in directional solidification
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