Investigation of the swelling response and quantitative prediction for hydrogenated nitrile rubber
A much more elegant method using three groups of solvent mixtures was employed to determine the Hansen three-dimensional solubility parameters (HSPs) of hydrogenated nitrile rubber (HNBR). The HSPs obtained by this way are comparable with previous work. The Flory-Rehner relationship was used to inve...
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| Veröffentlicht in: | Polymer testing 2014-04, Vol.34, p.72-77 |
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| container_title | Polymer testing |
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| creator | Liu, Guangyong Hoch, Martin Wrana, Claus Kulbaba, Kevin Liu, Susu Bi, Weina Zhao, Shugao |
| description | A much more elegant method using three groups of solvent mixtures was employed to determine the Hansen three-dimensional solubility parameters (HSPs) of hydrogenated nitrile rubber (HNBR). The HSPs obtained by this way are comparable with previous work. The Flory-Rehner relationship was used to investigate the effects of the crosslink density and the molar volume of solvent on the swelling response of the HNBR matrix. Both of these factors have a significant effect on the swelling volume in high swelling conditions (small Ra and Mc values) while the swelling curves show the characteristic reversed S-shape. The swelling volumes of HNBR (Therban 2568) in solvents and solvent mixtures have been calculated quantitatively by the Flory-Rehner relationship and correlated with the energy difference (Ra). The calculated swelling volumes decrease with increasing Ra values and also show the characteristic reversed S-shape, which correlate well with the experimental values. Therefore, it is expected that the swelling behavior of HNBR based vulcanizates in mixed fluids, taking bio-fuels and bio-based service fluids as examples, may now be predicted quantitatively. |
| doi_str_mv | 10.1016/j.polymertesting.2013.12.013 |
| format | Article |
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The HSPs obtained by this way are comparable with previous work. The Flory-Rehner relationship was used to investigate the effects of the crosslink density and the molar volume of solvent on the swelling response of the HNBR matrix. Both of these factors have a significant effect on the swelling volume in high swelling conditions (small Ra and Mc values) while the swelling curves show the characteristic reversed S-shape. The swelling volumes of HNBR (Therban 2568) in solvents and solvent mixtures have been calculated quantitatively by the Flory-Rehner relationship and correlated with the energy difference (Ra). The calculated swelling volumes decrease with increasing Ra values and also show the characteristic reversed S-shape, which correlate well with the experimental values. Therefore, it is expected that the swelling behavior of HNBR based vulcanizates in mixed fluids, taking bio-fuels and bio-based service fluids as examples, may now be predicted quantitatively.</description><identifier>ISSN: 0142-9418</identifier><identifier>EISSN: 1873-2348</identifier><identifier>DOI: 10.1016/j.polymertesting.2013.12.013</identifier><identifier>CODEN: POTEDZ</identifier><language>eng</language><publisher>Kindlington: Elsevier Ltd</publisher><subject>Applied sciences ; Density ; Energy difference ; Exact sciences and technology ; Flory-Rehner relationship ; Fluid dynamics ; Fluid flow ; Fluids ; Hansen solubility parameter ; Hydrogenated nitrile rubber ; Mathematical analysis ; Nitrile rubber ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization ; Solvents ; Swelling ; Thermal and thermodynamic properties</subject><ispartof>Polymer testing, 2014-04, Vol.34, p.72-77</ispartof><rights>2014 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c463t-38c300552893113aae7bee89657960f1415bbb947b3e34e2cfa20da390457cdb3</citedby><cites>FETCH-LOGICAL-c463t-38c300552893113aae7bee89657960f1415bbb947b3e34e2cfa20da390457cdb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.polymertesting.2013.12.013$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27923,27924,45994</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28339604$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Guangyong</creatorcontrib><creatorcontrib>Hoch, Martin</creatorcontrib><creatorcontrib>Wrana, Claus</creatorcontrib><creatorcontrib>Kulbaba, Kevin</creatorcontrib><creatorcontrib>Liu, Susu</creatorcontrib><creatorcontrib>Bi, Weina</creatorcontrib><creatorcontrib>Zhao, Shugao</creatorcontrib><title>Investigation of the swelling response and quantitative prediction for hydrogenated nitrile rubber</title><title>Polymer testing</title><description>A much more elegant method using three groups of solvent mixtures was employed to determine the Hansen three-dimensional solubility parameters (HSPs) of hydrogenated nitrile rubber (HNBR). The HSPs obtained by this way are comparable with previous work. The Flory-Rehner relationship was used to investigate the effects of the crosslink density and the molar volume of solvent on the swelling response of the HNBR matrix. Both of these factors have a significant effect on the swelling volume in high swelling conditions (small Ra and Mc values) while the swelling curves show the characteristic reversed S-shape. The swelling volumes of HNBR (Therban 2568) in solvents and solvent mixtures have been calculated quantitatively by the Flory-Rehner relationship and correlated with the energy difference (Ra). The calculated swelling volumes decrease with increasing Ra values and also show the characteristic reversed S-shape, which correlate well with the experimental values. Therefore, it is expected that the swelling behavior of HNBR based vulcanizates in mixed fluids, taking bio-fuels and bio-based service fluids as examples, may now be predicted quantitatively.</description><subject>Applied sciences</subject><subject>Density</subject><subject>Energy difference</subject><subject>Exact sciences and technology</subject><subject>Flory-Rehner relationship</subject><subject>Fluid dynamics</subject><subject>Fluid flow</subject><subject>Fluids</subject><subject>Hansen solubility parameter</subject><subject>Hydrogenated nitrile rubber</subject><subject>Mathematical analysis</subject><subject>Nitrile rubber</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Solvents</subject><subject>Swelling</subject><subject>Thermal and thermodynamic properties</subject><issn>0142-9418</issn><issn>1873-2348</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqNkUtrGzEUhUVoIK6T_6BFC93MRK95CLopoXmAoZtmLSTNHUdmLI0l2cX_vnJtCl01q7v5zrn33IPQJ0pqSmh7v6nnMB23EDOk7Py6ZoTymrK6jCu0oH3HK8ZF_wEtCBWskoL2N-hjShtCSFMcFsi8-MNJvNbZBY_DiPMb4PQLpqkY4ghpDj4B1n7Au7322eVCHgDPEQZn_4jGEPHbcYhhDV5nGLB3OboJcNwbA_EWXY96SnB3mUv0-vj958Nztfrx9PLwbVVZ0fJc8d7yclXDeskp5VpDZwB62TadbMlIBW2MMVJ0hgMXwOyoGRk0l0Q0nR0MX6IvZ985ht2-hFJbl2wJoj2EfVK07TrJuOTk_2jTyFa0jDYF_XpGbQwpRRjVHN1Wx6OiRJ1aUBv1bwvq1IKiTJVR5J8vm3Syehqj9talvx6s57ykE4V7PHNQPnRwEFWyDrwtT45gsxqCe9_C3x21qFw</recordid><startdate>20140401</startdate><enddate>20140401</enddate><creator>Liu, Guangyong</creator><creator>Hoch, Martin</creator><creator>Wrana, Claus</creator><creator>Kulbaba, Kevin</creator><creator>Liu, Susu</creator><creator>Bi, Weina</creator><creator>Zhao, Shugao</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20140401</creationdate><title>Investigation of the swelling response and quantitative prediction for hydrogenated nitrile rubber</title><author>Liu, Guangyong ; Hoch, Martin ; Wrana, Claus ; Kulbaba, Kevin ; Liu, Susu ; Bi, Weina ; Zhao, Shugao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c463t-38c300552893113aae7bee89657960f1415bbb947b3e34e2cfa20da390457cdb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Applied sciences</topic><topic>Density</topic><topic>Energy difference</topic><topic>Exact sciences and technology</topic><topic>Flory-Rehner relationship</topic><topic>Fluid dynamics</topic><topic>Fluid flow</topic><topic>Fluids</topic><topic>Hansen solubility parameter</topic><topic>Hydrogenated nitrile rubber</topic><topic>Mathematical analysis</topic><topic>Nitrile rubber</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>Solvents</topic><topic>Swelling</topic><topic>Thermal and thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Guangyong</creatorcontrib><creatorcontrib>Hoch, Martin</creatorcontrib><creatorcontrib>Wrana, Claus</creatorcontrib><creatorcontrib>Kulbaba, Kevin</creatorcontrib><creatorcontrib>Liu, Susu</creatorcontrib><creatorcontrib>Bi, Weina</creatorcontrib><creatorcontrib>Zhao, Shugao</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer testing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Guangyong</au><au>Hoch, Martin</au><au>Wrana, Claus</au><au>Kulbaba, Kevin</au><au>Liu, Susu</au><au>Bi, Weina</au><au>Zhao, Shugao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation of the swelling response and quantitative prediction for hydrogenated nitrile rubber</atitle><jtitle>Polymer testing</jtitle><date>2014-04-01</date><risdate>2014</risdate><volume>34</volume><spage>72</spage><epage>77</epage><pages>72-77</pages><issn>0142-9418</issn><eissn>1873-2348</eissn><coden>POTEDZ</coden><abstract>A much more elegant method using three groups of solvent mixtures was employed to determine the Hansen three-dimensional solubility parameters (HSPs) of hydrogenated nitrile rubber (HNBR). The HSPs obtained by this way are comparable with previous work. The Flory-Rehner relationship was used to investigate the effects of the crosslink density and the molar volume of solvent on the swelling response of the HNBR matrix. Both of these factors have a significant effect on the swelling volume in high swelling conditions (small Ra and Mc values) while the swelling curves show the characteristic reversed S-shape. The swelling volumes of HNBR (Therban 2568) in solvents and solvent mixtures have been calculated quantitatively by the Flory-Rehner relationship and correlated with the energy difference (Ra). The calculated swelling volumes decrease with increasing Ra values and also show the characteristic reversed S-shape, which correlate well with the experimental values. Therefore, it is expected that the swelling behavior of HNBR based vulcanizates in mixed fluids, taking bio-fuels and bio-based service fluids as examples, may now be predicted quantitatively.</abstract><cop>Kindlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymertesting.2013.12.013</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0142-9418 |
| ispartof | Polymer testing, 2014-04, Vol.34, p.72-77 |
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| source | ScienceDirect Freedom Collection (Elsevier); EZB Electronic Journals Library |
| subjects | Applied sciences Density Energy difference Exact sciences and technology Flory-Rehner relationship Fluid dynamics Fluid flow Fluids Hansen solubility parameter Hydrogenated nitrile rubber Mathematical analysis Nitrile rubber Organic polymers Physicochemistry of polymers Properties and characterization Solvents Swelling Thermal and thermodynamic properties |
| title | Investigation of the swelling response and quantitative prediction for hydrogenated nitrile rubber |
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