Fabrication and semiconducting properties of monodisperse n-type phthalocyanine nanograss
Dipotassium-2,3,9,10,16,17,23,24-octacyanophthalocyanine–potassium (K2Pc(CN)8–K) complex nanograss was fabricated on a single KCl crystal. The process was controlled to achieve monodisperse nanograss with individual rod diameters of 60nm and lengths of 250nm. The gaps between the rods were fully cov...
Gespeichert in:
| Veröffentlicht in: | Thin solid films 2013-03, Vol.531, p.513-518 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 518 |
|---|---|
| container_issue | |
| container_start_page | 513 |
| container_title | Thin solid films |
| container_volume | 531 |
| creator | Saeki, Hiroyuki Nishimoto, Mihoko Koshiba, Yasuko Misaki, Masahiro Ishida, Kenji Ueda, Yasukiyo |
| description | Dipotassium-2,3,9,10,16,17,23,24-octacyanophthalocyanine–potassium (K2Pc(CN)8–K) complex nanograss was fabricated on a single KCl crystal. The process was controlled to achieve monodisperse nanograss with individual rod diameters of 60nm and lengths of 250nm. The gaps between the rods were fully covered with K2Pc(CN)8–K complex grains. The film continuity at the interface between the substrate and the nanograss layer allowed measurement of the field-effect-transistor characteristics of the material. The K2Pc(CN)8–K complex film exhibited n-type conduction characteristics, and the energy of the highest occupied molecular orbital was determined to be 5.8eV. Organic photovoltaic cells containing K2Pc(CN)8–K as an n-type semiconductor were also fabricated, and the power-conversion efficiency of a cell containing vertical-aligned-nanograss was approximately four times larger than that of a nanograss dispersed bulk-heterojunction-type cell.
► Octacyanophthalocyanine nanograss was formed by chemical vapor deposition (CVD). ► The distribution of length of nanograss can be controlled by the temperature in CVD. ► The nanograss showed good n-type semiconductor property in photovoltaic cells. |
| doi_str_mv | 10.1016/j.tsf.2013.01.009 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1677920637</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S004060901300059X</els_id><sourcerecordid>1677920637</sourcerecordid><originalsourceid>FETCH-LOGICAL-c426t-aa79bd502a539727643545f39e2295ee8861ccc1c5f97e4d1f0a1dc3b5eb3f4c3</originalsourceid><addsrcrecordid>eNp9kEFr3DAQhUVoIdu0P6A3Xwq92BlJtrWmpxKaJhDopT30JLTjUaLFK7kabWH_fRU29JjTwON7b2aeEB8ldBLkeL3vCvtOgdQdyA5guhAbuTVTq4yWb8QGoId2hAkuxTvmPQBIpfRG_L51uxzQlZBi4-LcMB0CpjgfsYT42Kw5rZRLIG6Sbw4ppjlwVZia2JbTSs36VJ7ckvDkYohVdTE9Zsf8Xrz1bmH68DKvxK_bbz9v7tqHH9_vb74-tNirsbTOmWk3D6DcoCejzNjroR-8nkipaSDabkeJiBIHPxnqZ-nByRn1bqCd9j3qK_H5nFtP_XMkLvYQGGlZXKR0ZCtHYyYFozYVlWcUc2LO5O2aw8Hlk5Vgn2u0e1trtM81WpC21lg9n17iHaNbfHYRA_83KiO3vdG6cl_OHNVf_wbKljFQRJpDJix2TuGVLf8A4P2Jow</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1677920637</pqid></control><display><type>article</type><title>Fabrication and semiconducting properties of monodisperse n-type phthalocyanine nanograss</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Saeki, Hiroyuki ; Nishimoto, Mihoko ; Koshiba, Yasuko ; Misaki, Masahiro ; Ishida, Kenji ; Ueda, Yasukiyo</creator><creatorcontrib>Saeki, Hiroyuki ; Nishimoto, Mihoko ; Koshiba, Yasuko ; Misaki, Masahiro ; Ishida, Kenji ; Ueda, Yasukiyo</creatorcontrib><description>Dipotassium-2,3,9,10,16,17,23,24-octacyanophthalocyanine–potassium (K2Pc(CN)8–K) complex nanograss was fabricated on a single KCl crystal. The process was controlled to achieve monodisperse nanograss with individual rod diameters of 60nm and lengths of 250nm. The gaps between the rods were fully covered with K2Pc(CN)8–K complex grains. The film continuity at the interface between the substrate and the nanograss layer allowed measurement of the field-effect-transistor characteristics of the material. The K2Pc(CN)8–K complex film exhibited n-type conduction characteristics, and the energy of the highest occupied molecular orbital was determined to be 5.8eV. Organic photovoltaic cells containing K2Pc(CN)8–K as an n-type semiconductor were also fabricated, and the power-conversion efficiency of a cell containing vertical-aligned-nanograss was approximately four times larger than that of a nanograss dispersed bulk-heterojunction-type cell.
► Octacyanophthalocyanine nanograss was formed by chemical vapor deposition (CVD). ► The distribution of length of nanograss can be controlled by the temperature in CVD. ► The nanograss showed good n-type semiconductor property in photovoltaic cells.</description><identifier>ISSN: 0040-6090</identifier><identifier>EISSN: 1879-2731</identifier><identifier>DOI: 10.1016/j.tsf.2013.01.009</identifier><identifier>CODEN: THSFAP</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Continuity ; Crystals ; Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures ; Electronics ; Energy ; Exact sciences and technology ; Molecular orbitals ; N-type semiconductors ; Nanograss ; Nanostructure ; Natural energy ; Octacyanophthalocyanine ; Organic photovoltaic cells ; Organic semiconductor ; Photovoltaic cells ; Photovoltaic conversion ; Physics ; Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices ; Solar cells ; Solar cells. Photoelectrochemical cells ; Solar energy ; Surface and interface electron states ; Thin films ; Transistors</subject><ispartof>Thin solid films, 2013-03, Vol.531, p.513-518</ispartof><rights>2013 Elsevier B.V.</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c426t-aa79bd502a539727643545f39e2295ee8861ccc1c5f97e4d1f0a1dc3b5eb3f4c3</citedby><cites>FETCH-LOGICAL-c426t-aa79bd502a539727643545f39e2295ee8861ccc1c5f97e4d1f0a1dc3b5eb3f4c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S004060901300059X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27184733$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Saeki, Hiroyuki</creatorcontrib><creatorcontrib>Nishimoto, Mihoko</creatorcontrib><creatorcontrib>Koshiba, Yasuko</creatorcontrib><creatorcontrib>Misaki, Masahiro</creatorcontrib><creatorcontrib>Ishida, Kenji</creatorcontrib><creatorcontrib>Ueda, Yasukiyo</creatorcontrib><title>Fabrication and semiconducting properties of monodisperse n-type phthalocyanine nanograss</title><title>Thin solid films</title><description>Dipotassium-2,3,9,10,16,17,23,24-octacyanophthalocyanine–potassium (K2Pc(CN)8–K) complex nanograss was fabricated on a single KCl crystal. The process was controlled to achieve monodisperse nanograss with individual rod diameters of 60nm and lengths of 250nm. The gaps between the rods were fully covered with K2Pc(CN)8–K complex grains. The film continuity at the interface between the substrate and the nanograss layer allowed measurement of the field-effect-transistor characteristics of the material. The K2Pc(CN)8–K complex film exhibited n-type conduction characteristics, and the energy of the highest occupied molecular orbital was determined to be 5.8eV. Organic photovoltaic cells containing K2Pc(CN)8–K as an n-type semiconductor were also fabricated, and the power-conversion efficiency of a cell containing vertical-aligned-nanograss was approximately four times larger than that of a nanograss dispersed bulk-heterojunction-type cell.
► Octacyanophthalocyanine nanograss was formed by chemical vapor deposition (CVD). ► The distribution of length of nanograss can be controlled by the temperature in CVD. ► The nanograss showed good n-type semiconductor property in photovoltaic cells.</description><subject>Applied sciences</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Continuity</subject><subject>Crystals</subject><subject>Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures</subject><subject>Electronics</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Molecular orbitals</subject><subject>N-type semiconductors</subject><subject>Nanograss</subject><subject>Nanostructure</subject><subject>Natural energy</subject><subject>Octacyanophthalocyanine</subject><subject>Organic photovoltaic cells</subject><subject>Organic semiconductor</subject><subject>Photovoltaic cells</subject><subject>Photovoltaic conversion</subject><subject>Physics</subject><subject>Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices</subject><subject>Solar cells</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>Solar energy</subject><subject>Surface and interface electron states</subject><subject>Thin films</subject><subject>Transistors</subject><issn>0040-6090</issn><issn>1879-2731</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kEFr3DAQhUVoIdu0P6A3Xwq92BlJtrWmpxKaJhDopT30JLTjUaLFK7kabWH_fRU29JjTwON7b2aeEB8ldBLkeL3vCvtOgdQdyA5guhAbuTVTq4yWb8QGoId2hAkuxTvmPQBIpfRG_L51uxzQlZBi4-LcMB0CpjgfsYT42Kw5rZRLIG6Sbw4ppjlwVZia2JbTSs36VJ7ckvDkYohVdTE9Zsf8Xrz1bmH68DKvxK_bbz9v7tqHH9_vb74-tNirsbTOmWk3D6DcoCejzNjroR-8nkipaSDabkeJiBIHPxnqZ-nByRn1bqCd9j3qK_H5nFtP_XMkLvYQGGlZXKR0ZCtHYyYFozYVlWcUc2LO5O2aw8Hlk5Vgn2u0e1trtM81WpC21lg9n17iHaNbfHYRA_83KiO3vdG6cl_OHNVf_wbKljFQRJpDJix2TuGVLf8A4P2Jow</recordid><startdate>20130301</startdate><enddate>20130301</enddate><creator>Saeki, Hiroyuki</creator><creator>Nishimoto, Mihoko</creator><creator>Koshiba, Yasuko</creator><creator>Misaki, Masahiro</creator><creator>Ishida, Kenji</creator><creator>Ueda, Yasukiyo</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20130301</creationdate><title>Fabrication and semiconducting properties of monodisperse n-type phthalocyanine nanograss</title><author>Saeki, Hiroyuki ; Nishimoto, Mihoko ; Koshiba, Yasuko ; Misaki, Masahiro ; Ishida, Kenji ; Ueda, Yasukiyo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c426t-aa79bd502a539727643545f39e2295ee8861ccc1c5f97e4d1f0a1dc3b5eb3f4c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Applied sciences</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Continuity</topic><topic>Crystals</topic><topic>Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures</topic><topic>Electronics</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Molecular orbitals</topic><topic>N-type semiconductors</topic><topic>Nanograss</topic><topic>Nanostructure</topic><topic>Natural energy</topic><topic>Octacyanophthalocyanine</topic><topic>Organic photovoltaic cells</topic><topic>Organic semiconductor</topic><topic>Photovoltaic cells</topic><topic>Photovoltaic conversion</topic><topic>Physics</topic><topic>Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices</topic><topic>Solar cells</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>Solar energy</topic><topic>Surface and interface electron states</topic><topic>Thin films</topic><topic>Transistors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Saeki, Hiroyuki</creatorcontrib><creatorcontrib>Nishimoto, Mihoko</creatorcontrib><creatorcontrib>Koshiba, Yasuko</creatorcontrib><creatorcontrib>Misaki, Masahiro</creatorcontrib><creatorcontrib>Ishida, Kenji</creatorcontrib><creatorcontrib>Ueda, Yasukiyo</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Thin solid films</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saeki, Hiroyuki</au><au>Nishimoto, Mihoko</au><au>Koshiba, Yasuko</au><au>Misaki, Masahiro</au><au>Ishida, Kenji</au><au>Ueda, Yasukiyo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication and semiconducting properties of monodisperse n-type phthalocyanine nanograss</atitle><jtitle>Thin solid films</jtitle><date>2013-03-01</date><risdate>2013</risdate><volume>531</volume><spage>513</spage><epage>518</epage><pages>513-518</pages><issn>0040-6090</issn><eissn>1879-2731</eissn><coden>THSFAP</coden><abstract>Dipotassium-2,3,9,10,16,17,23,24-octacyanophthalocyanine–potassium (K2Pc(CN)8–K) complex nanograss was fabricated on a single KCl crystal. The process was controlled to achieve monodisperse nanograss with individual rod diameters of 60nm and lengths of 250nm. The gaps between the rods were fully covered with K2Pc(CN)8–K complex grains. The film continuity at the interface between the substrate and the nanograss layer allowed measurement of the field-effect-transistor characteristics of the material. The K2Pc(CN)8–K complex film exhibited n-type conduction characteristics, and the energy of the highest occupied molecular orbital was determined to be 5.8eV. Organic photovoltaic cells containing K2Pc(CN)8–K as an n-type semiconductor were also fabricated, and the power-conversion efficiency of a cell containing vertical-aligned-nanograss was approximately four times larger than that of a nanograss dispersed bulk-heterojunction-type cell.
► Octacyanophthalocyanine nanograss was formed by chemical vapor deposition (CVD). ► The distribution of length of nanograss can be controlled by the temperature in CVD. ► The nanograss showed good n-type semiconductor property in photovoltaic cells.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.tsf.2013.01.009</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0040-6090 |
| ispartof | Thin solid films, 2013-03, Vol.531, p.513-518 |
| issn | 0040-6090 1879-2731 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1677920637 |
| source | Elsevier ScienceDirect Journals Complete |
| subjects | Applied sciences Condensed matter: electronic structure, electrical, magnetic, and optical properties Continuity Crystals Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures Electronics Energy Exact sciences and technology Molecular orbitals N-type semiconductors Nanograss Nanostructure Natural energy Octacyanophthalocyanine Organic photovoltaic cells Organic semiconductor Photovoltaic cells Photovoltaic conversion Physics Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices Solar cells Solar cells. Photoelectrochemical cells Solar energy Surface and interface electron states Thin films Transistors |
| title | Fabrication and semiconducting properties of monodisperse n-type phthalocyanine nanograss |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T20%3A03%3A50IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fabrication%20and%20semiconducting%20properties%20of%20monodisperse%20n-type%20phthalocyanine%20nanograss&rft.jtitle=Thin%20solid%20films&rft.au=Saeki,%20Hiroyuki&rft.date=2013-03-01&rft.volume=531&rft.spage=513&rft.epage=518&rft.pages=513-518&rft.issn=0040-6090&rft.eissn=1879-2731&rft.coden=THSFAP&rft_id=info:doi/10.1016/j.tsf.2013.01.009&rft_dat=%3Cproquest_cross%3E1677920637%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1677920637&rft_id=info:pmid/&rft_els_id=S004060901300059X&rfr_iscdi=true |