Reactive and unreactive pathways in a photochemical ring opening reaction from 2D femtosecond stimulated Raman

Two-dimensional femtosecond stimulated Raman spectroscopy (2D-FSRS) is used to probe the structural evolution of a modified cyclohexadiene as it undergoes a photoinduced ring opening reaction. Analysis of the excited state stimulated Raman vibrational data reveals oscillations of the center frequenc...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2015-04, Vol.17 (14), p.9231-9240
Hauptverfasser: Valley, David T, Hoffman, David P, Mathies, Richard A
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Sprache:eng
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