Luminescent properties of Ag()/Cu() coordination polymers: crystal structures and high intensity luminescence of a PMMA-doped hybrid material based on a quinoline-2,3-dicarboxylic acid ligand
Three one-dimensional (1D) Ag( i )/Cu( i ) coordination polymers, formulated as [Ag(2,3-Hqldc)] n ( Ag1 ), [Ag(3-qlc)] 2 n ( Ag2 ) and [CuI(3-Hqlc)] n ( Cu1 ) based on the ligand quinoline-2,3-dicarboxylic acid (H 2 qldc), were synthesized through hydrothermal (solvothermal) method and structurally...
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| Veröffentlicht in: | RSC advances 2015-01, Vol.5 (22), p.17343-17353 |
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| creator | Song, Yang Fan, Rui-Qing Zhang, Hui-Jie Liu, Zhi-Wei Wang, Xue-Tao Tan, Cai-Tu Yang, Yu-Lin Wang, Yu-Lei |
| description | Three one-dimensional (1D) Ag(
i
)/Cu(
i
) coordination polymers, formulated as [Ag(2,3-Hqldc)]
n
(
Ag1
), [Ag(3-qlc)]
2
n
(
Ag2
) and [CuI(3-Hqlc)]
n
(
Cu1
) based on the ligand quinoline-2,3-dicarboxylic acid (H
2
qldc), were synthesized through hydrothermal (solvothermal) method and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy and elemental analysis. Molecular structural analysis reveals that
Ag1
was a 1D + 1D → 1D infinite chain synthesized at a relatively low temperature 80 °C, which further forms a three-dimensional (3D) structure by π-π stacking interactions.
Ag2
forms a 1D dimer chain structure and
via
π π packing interactions shows a two-dimensional (2D) supramolecular network. Both
Ag1
and
Ag2
display stable blue luminescent in the solid state and in organic solvents (DMSO, CH
3
CN and CH
3
OH) at 298 K and 77 K. However,
Cu1
possess a 1D ladder chain structure, which further forms a 2D structure by hydrogen bonding interactions.
Cu1
shows tunable luminescence at 298 K and 77 K in the solid state with a large red-shift of 70 nm and the CIE color shifts from bright yellow (0.51, 0.48) to red (0.67, 0.30), indicating thermochromic luminescence for
Cu1
. After doping with poly(methylmethacrylate) (PMMA), not only are the luminescence intensity and lifetimes enhanced, but the thermal stability is also increased in comparison with
Cu1
. After
Cu1
was doped with PMMA (
Cu1
@PMMA), the lifetime of the polymer film material
Cu1
@PMMA increases and reaches a maximum at 1.0% (
τ
= 95.57 μs), which is more than eight times longer than that of
Cu1
(
τ
= 13.78 μs).
Cu1
@PMMA is confirmed as a bright yellow luminescent polymer film material.
Preparation, characterization, crystal structure and different luminescent properties of Ag(
i
)/Cu(
i
) coordination polymers: stable blue emission, thermochromism and PMMA-doped hybrid material. |
| doi_str_mv | 10.1039/c4ra16863a |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_proquest_miscellaneous_1677905812</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1677905812</sourcerecordid><originalsourceid>FETCH-LOGICAL-c378t-108c4268188d2ed87010791019a8631aa5b8bfcf71bb0c79cb40d54d14c1a65f3</originalsourceid><addsrcrecordid>eNp9kUtr3TAQhU1oISHNJvuAsrspdSP5IcvdmUtfcENLaNdmPJJvFGTJkWSIf13_WpXeknRVbSRmvjkHzcmyc0bfM1q211h5YFzwEo6yk4JWPC8ob1_98z7OzkK4p-nwmhWcnWS_dsukrQqobCSzd7PyUatA3Ei6_ebqertsrgg656W2ELWzZHZmnZQPHwj6NUQwJES_YFx8GgMryZ3e3xFto7JBx5WYZwNUT7JAvt_cdLlMVoldB68lmSAqr5PUACFVkwuQh0VbZ9JoXrwrc6kR_OAeV6ORAKYZo_fJ7U32egQT1Nnf-zT7-enjj-2XfPft89dtt8uxbETMGRVYFVwwIWShpGgoo03LKGsh7YsB1IMYRhwbNgwUmxaHisq6kqxCBrwey9Nsc9BNO3pYVIj9pNOfjAGr3BJ6xpumpbVgRULfHlD0LgSvxn72egK_9oz2T0H12-q2-xNUl-CLA-wDPnMvQab-5f_6_SzH8jdE-529</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1677905812</pqid></control><display><type>article</type><title>Luminescent properties of Ag()/Cu() coordination polymers: crystal structures and high intensity luminescence of a PMMA-doped hybrid material based on a quinoline-2,3-dicarboxylic acid ligand</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Song, Yang ; Fan, Rui-Qing ; Zhang, Hui-Jie ; Liu, Zhi-Wei ; Wang, Xue-Tao ; Tan, Cai-Tu ; Yang, Yu-Lin ; Wang, Yu-Lei</creator><creatorcontrib>Song, Yang ; Fan, Rui-Qing ; Zhang, Hui-Jie ; Liu, Zhi-Wei ; Wang, Xue-Tao ; Tan, Cai-Tu ; Yang, Yu-Lin ; Wang, Yu-Lei</creatorcontrib><description>Three one-dimensional (1D) Ag(
i
)/Cu(
i
) coordination polymers, formulated as [Ag(2,3-Hqldc)]
n
(
Ag1
), [Ag(3-qlc)]
2
n
(
Ag2
) and [CuI(3-Hqlc)]
n
(
Cu1
) based on the ligand quinoline-2,3-dicarboxylic acid (H
2
qldc), were synthesized through hydrothermal (solvothermal) method and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy and elemental analysis. Molecular structural analysis reveals that
Ag1
was a 1D + 1D → 1D infinite chain synthesized at a relatively low temperature 80 °C, which further forms a three-dimensional (3D) structure by π-π stacking interactions.
Ag2
forms a 1D dimer chain structure and
via
π π packing interactions shows a two-dimensional (2D) supramolecular network. Both
Ag1
and
Ag2
display stable blue luminescent in the solid state and in organic solvents (DMSO, CH
3
CN and CH
3
OH) at 298 K and 77 K. However,
Cu1
possess a 1D ladder chain structure, which further forms a 2D structure by hydrogen bonding interactions.
Cu1
shows tunable luminescence at 298 K and 77 K in the solid state with a large red-shift of 70 nm and the CIE color shifts from bright yellow (0.51, 0.48) to red (0.67, 0.30), indicating thermochromic luminescence for
Cu1
. After doping with poly(methylmethacrylate) (PMMA), not only are the luminescence intensity and lifetimes enhanced, but the thermal stability is also increased in comparison with
Cu1
. After
Cu1
was doped with PMMA (
Cu1
@PMMA), the lifetime of the polymer film material
Cu1
@PMMA increases and reaches a maximum at 1.0% (
τ
= 95.57 μs), which is more than eight times longer than that of
Cu1
(
τ
= 13.78 μs).
Cu1
@PMMA is confirmed as a bright yellow luminescent polymer film material.
Preparation, characterization, crystal structure and different luminescent properties of Ag(
i
)/Cu(
i
) coordination polymers: stable blue emission, thermochromism and PMMA-doped hybrid material.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c4ra16863a</identifier><language>eng</language><subject>Chains ; Coordination polymers ; Luminescence ; Molecular structure ; Polymethyl methacrylates ; Solid state ; Three dimensional ; Two dimensional</subject><ispartof>RSC advances, 2015-01, Vol.5 (22), p.17343-17353</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c378t-108c4268188d2ed87010791019a8631aa5b8bfcf71bb0c79cb40d54d14c1a65f3</citedby><cites>FETCH-LOGICAL-c378t-108c4268188d2ed87010791019a8631aa5b8bfcf71bb0c79cb40d54d14c1a65f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Song, Yang</creatorcontrib><creatorcontrib>Fan, Rui-Qing</creatorcontrib><creatorcontrib>Zhang, Hui-Jie</creatorcontrib><creatorcontrib>Liu, Zhi-Wei</creatorcontrib><creatorcontrib>Wang, Xue-Tao</creatorcontrib><creatorcontrib>Tan, Cai-Tu</creatorcontrib><creatorcontrib>Yang, Yu-Lin</creatorcontrib><creatorcontrib>Wang, Yu-Lei</creatorcontrib><title>Luminescent properties of Ag()/Cu() coordination polymers: crystal structures and high intensity luminescence of a PMMA-doped hybrid material based on a quinoline-2,3-dicarboxylic acid ligand</title><title>RSC advances</title><description>Three one-dimensional (1D) Ag(
i
)/Cu(
i
) coordination polymers, formulated as [Ag(2,3-Hqldc)]
n
(
Ag1
), [Ag(3-qlc)]
2
n
(
Ag2
) and [CuI(3-Hqlc)]
n
(
Cu1
) based on the ligand quinoline-2,3-dicarboxylic acid (H
2
qldc), were synthesized through hydrothermal (solvothermal) method and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy and elemental analysis. Molecular structural analysis reveals that
Ag1
was a 1D + 1D → 1D infinite chain synthesized at a relatively low temperature 80 °C, which further forms a three-dimensional (3D) structure by π-π stacking interactions.
Ag2
forms a 1D dimer chain structure and
via
π π packing interactions shows a two-dimensional (2D) supramolecular network. Both
Ag1
and
Ag2
display stable blue luminescent in the solid state and in organic solvents (DMSO, CH
3
CN and CH
3
OH) at 298 K and 77 K. However,
Cu1
possess a 1D ladder chain structure, which further forms a 2D structure by hydrogen bonding interactions.
Cu1
shows tunable luminescence at 298 K and 77 K in the solid state with a large red-shift of 70 nm and the CIE color shifts from bright yellow (0.51, 0.48) to red (0.67, 0.30), indicating thermochromic luminescence for
Cu1
. After doping with poly(methylmethacrylate) (PMMA), not only are the luminescence intensity and lifetimes enhanced, but the thermal stability is also increased in comparison with
Cu1
. After
Cu1
was doped with PMMA (
Cu1
@PMMA), the lifetime of the polymer film material
Cu1
@PMMA increases and reaches a maximum at 1.0% (
τ
= 95.57 μs), which is more than eight times longer than that of
Cu1
(
τ
= 13.78 μs).
Cu1
@PMMA is confirmed as a bright yellow luminescent polymer film material.
Preparation, characterization, crystal structure and different luminescent properties of Ag(
i
)/Cu(
i
) coordination polymers: stable blue emission, thermochromism and PMMA-doped hybrid material.</description><subject>Chains</subject><subject>Coordination polymers</subject><subject>Luminescence</subject><subject>Molecular structure</subject><subject>Polymethyl methacrylates</subject><subject>Solid state</subject><subject>Three dimensional</subject><subject>Two dimensional</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kUtr3TAQhU1oISHNJvuAsrspdSP5IcvdmUtfcENLaNdmPJJvFGTJkWSIf13_WpXeknRVbSRmvjkHzcmyc0bfM1q211h5YFzwEo6yk4JWPC8ob1_98z7OzkK4p-nwmhWcnWS_dsukrQqobCSzd7PyUatA3Ei6_ebqertsrgg656W2ELWzZHZmnZQPHwj6NUQwJES_YFx8GgMryZ3e3xFto7JBx5WYZwNUT7JAvt_cdLlMVoldB68lmSAqr5PUACFVkwuQh0VbZ9JoXrwrc6kR_OAeV6ORAKYZo_fJ7U32egQT1Nnf-zT7-enjj-2XfPft89dtt8uxbETMGRVYFVwwIWShpGgoo03LKGsh7YsB1IMYRhwbNgwUmxaHisq6kqxCBrwey9Nsc9BNO3pYVIj9pNOfjAGr3BJ6xpumpbVgRULfHlD0LgSvxn72egK_9oz2T0H12-q2-xNUl-CLA-wDPnMvQab-5f_6_SzH8jdE-529</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Song, Yang</creator><creator>Fan, Rui-Qing</creator><creator>Zhang, Hui-Jie</creator><creator>Liu, Zhi-Wei</creator><creator>Wang, Xue-Tao</creator><creator>Tan, Cai-Tu</creator><creator>Yang, Yu-Lin</creator><creator>Wang, Yu-Lei</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150101</creationdate><title>Luminescent properties of Ag()/Cu() coordination polymers: crystal structures and high intensity luminescence of a PMMA-doped hybrid material based on a quinoline-2,3-dicarboxylic acid ligand</title><author>Song, Yang ; Fan, Rui-Qing ; Zhang, Hui-Jie ; Liu, Zhi-Wei ; Wang, Xue-Tao ; Tan, Cai-Tu ; Yang, Yu-Lin ; Wang, Yu-Lei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c378t-108c4268188d2ed87010791019a8631aa5b8bfcf71bb0c79cb40d54d14c1a65f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Chains</topic><topic>Coordination polymers</topic><topic>Luminescence</topic><topic>Molecular structure</topic><topic>Polymethyl methacrylates</topic><topic>Solid state</topic><topic>Three dimensional</topic><topic>Two dimensional</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Song, Yang</creatorcontrib><creatorcontrib>Fan, Rui-Qing</creatorcontrib><creatorcontrib>Zhang, Hui-Jie</creatorcontrib><creatorcontrib>Liu, Zhi-Wei</creatorcontrib><creatorcontrib>Wang, Xue-Tao</creatorcontrib><creatorcontrib>Tan, Cai-Tu</creatorcontrib><creatorcontrib>Yang, Yu-Lin</creatorcontrib><creatorcontrib>Wang, Yu-Lei</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Song, Yang</au><au>Fan, Rui-Qing</au><au>Zhang, Hui-Jie</au><au>Liu, Zhi-Wei</au><au>Wang, Xue-Tao</au><au>Tan, Cai-Tu</au><au>Yang, Yu-Lin</au><au>Wang, Yu-Lei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Luminescent properties of Ag()/Cu() coordination polymers: crystal structures and high intensity luminescence of a PMMA-doped hybrid material based on a quinoline-2,3-dicarboxylic acid ligand</atitle><jtitle>RSC advances</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>5</volume><issue>22</issue><spage>17343</spage><epage>17353</epage><pages>17343-17353</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Three one-dimensional (1D) Ag(
i
)/Cu(
i
) coordination polymers, formulated as [Ag(2,3-Hqldc)]
n
(
Ag1
), [Ag(3-qlc)]
2
n
(
Ag2
) and [CuI(3-Hqlc)]
n
(
Cu1
) based on the ligand quinoline-2,3-dicarboxylic acid (H
2
qldc), were synthesized through hydrothermal (solvothermal) method and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy and elemental analysis. Molecular structural analysis reveals that
Ag1
was a 1D + 1D → 1D infinite chain synthesized at a relatively low temperature 80 °C, which further forms a three-dimensional (3D) structure by π-π stacking interactions.
Ag2
forms a 1D dimer chain structure and
via
π π packing interactions shows a two-dimensional (2D) supramolecular network. Both
Ag1
and
Ag2
display stable blue luminescent in the solid state and in organic solvents (DMSO, CH
3
CN and CH
3
OH) at 298 K and 77 K. However,
Cu1
possess a 1D ladder chain structure, which further forms a 2D structure by hydrogen bonding interactions.
Cu1
shows tunable luminescence at 298 K and 77 K in the solid state with a large red-shift of 70 nm and the CIE color shifts from bright yellow (0.51, 0.48) to red (0.67, 0.30), indicating thermochromic luminescence for
Cu1
. After doping with poly(methylmethacrylate) (PMMA), not only are the luminescence intensity and lifetimes enhanced, but the thermal stability is also increased in comparison with
Cu1
. After
Cu1
was doped with PMMA (
Cu1
@PMMA), the lifetime of the polymer film material
Cu1
@PMMA increases and reaches a maximum at 1.0% (
τ
= 95.57 μs), which is more than eight times longer than that of
Cu1
(
τ
= 13.78 μs).
Cu1
@PMMA is confirmed as a bright yellow luminescent polymer film material.
Preparation, characterization, crystal structure and different luminescent properties of Ag(
i
)/Cu(
i
) coordination polymers: stable blue emission, thermochromism and PMMA-doped hybrid material.</abstract><doi>10.1039/c4ra16863a</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2015-01, Vol.5 (22), p.17343-17353 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1677905812 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Chains Coordination polymers Luminescence Molecular structure Polymethyl methacrylates Solid state Three dimensional Two dimensional |
| title | Luminescent properties of Ag()/Cu() coordination polymers: crystal structures and high intensity luminescence of a PMMA-doped hybrid material based on a quinoline-2,3-dicarboxylic acid ligand |
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